ML-13G

Rochester Midland Corporation

Revision date : 2016-10-11

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

31075-24-8

Name of the chemical

N,N,N',N'-Tetramethylethylenediaminebis(2-chloroethyl)ether copolymer

Concentration

100%

Listed in

General Information

Version

3

Revision date

2016-10-11

Product name

ML-13G

Product Synonyms

NONE

CAS No.

31075-24-8

1.2.1 Relevant identified uses

Algicide. Fungicide. Disinfectant

Emergency telephone

1-800-535-5053, +1-352-323-3500

Icons in SDS

Company Information

company name

Rochester Midland Corporation

GHS Information

Signal word

WARNING

Section 2

SECTION 2: Hazards identification

2.2 Label elements

Emergency Overview WARNING

Hazard statements

Causes eye irritation Appearance Clear Amber Physical state Liquid Odor Mild Odor

Prevention

Wash face, hands and any exposed skin thoroughly after handling

Response

Call a POISON CENTER or doctor/physician if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention

2.3 Other hazards

No information available

Further information

Harmful to aquatic life with long lasting effects. * Toxic to aquatic life. CAS No. TRADE SECRET Poly [oxyethylene (dimethyliminio) ethylene 31075-24-8 15 (dimethyliminio) ethylene dichloride] *The exact percentage (concentration) of composition has been withheld as a trade secret. First aid measures General advice Call a POISON CENTER or doctor/physician if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN: Wash with soap and water. Inhalation IF INHALED: Remove to fresh air. Ingestion IF SWALLOWED: Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact NONE. Sensitivity to Static Discharge NONE. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Personal precautions, protective equipment and emergency procedures Personal precautions Wear adequate personal protective equipment, see Section 8, Exposure Controls/Personal Protection. Environmental precautions Keep out of drains, sewers, streams, or other bodies of water. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Dike to contain. Pick up with absorbant material. Put in suitable container for disposal. Methods for cleaning up Pick up and transfer to properly labeled containers. Precautions for safe handling Advice on safe handling Do not breathe mist or vapors. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Softening point No information available VOC (EPA METH.24) (GIL): 0 Density 8.62 Ibs/gal Bulk density No information available REACTIVITY No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. CONDITIONS TO AVOID Extremes of temperature and direct sunlight. Incompatible materials None known based on information supplied. Hazardous Decomposition Products If evaporated to dryness, as in a fire, material may burn, releasing:. Carbon Monoxide. Information on likely routes of exposure Product Information No data available. Inhalation May cause irritation of respiratory tract. Page 4o0f7 Eye contact Irritating to eyes. Skin contact Prolonged contact may lead to irritation and dermatitis. Ingestion Large amounts may cause irritation, nausea, diarrhea. PRODUCT COMPOSITION Oral LD50 Dermal LD50 Inhalation LC50 Poly [foxyethylene (dimethyliminio) ethylene = 1850 mg/kg ( Rat ) - (dimethyliminio) ethylene dichloride] 31075-24-8 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 12333 mg/kg ATEmix (inhalation-dust/mist) 19.3 mg/l Ecotoxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects. 0% of the mixture consists of components(s) of unknown hazards to the aquatic environment PRODUCT COMPOSITION Algae/aquatic plants Fish Crustacea Poly [oxyethylene (dimethyliminio) ethylene - > 600.0: 96 h Sheepshead | 13.0: 96 h Mysidopsis Bahia (dimethyliminio) ethylene dichloride] minnow mg/L LC50 mg/L LC50 31075-24-8 Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects No information available Waste treatment methods Disposal of wastes Permits may be required for discharges containing this pesticide into lakes, streams, ponds, or public water. Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. Page 5of7 EPA Reg. No.: 1448-212-527 DEPT, OF TRANSPORTATION Proper shipping name Not Regulated by DOT TDG Not Regulated International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not Comply ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories ACUTE HEALTH HAZARD YES CHRONIC HEALTH HAZARD No FIRE HAZARD No Sudden release of pressure hazard No REACTIVE HAZARD No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Page 6 of 7 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide Registration Number 1448-212-527 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label Caution. moderate eye irritation. Harmful if swallowed. This pesticide is toxic to fish, aquatic organisms and clams. NFPA Health hazards 1 Flammability 0 Instability 0

Storage

Conditions Do not contaminate water, food, or feed. Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials None known based on information supplied. Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls ENGINEERING CONTROLS Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Safety glasses are recommended to minimize eye contact. Skin and body protection Chemical resistant gloves are recommended to minimize skin contact. It is the responsibility of the end user of this product to determine level of PPE required that is consistent with safe use of this product. RESPIRATORY PROTECTION __ If exposure limits are exceeded or irritation is experienced, NOOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties Physical state Liquid

Appearance/Odor

Clear Amber Mild Odor Color Amber Odor threshold No information available

Remarks

* Method Melting point/freezing point No information available Boiling point / boiling range 100 / 212 Flash point None to boiling. Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Specific gravity 1.024 - 1.044 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available

SDS Library

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