MS R0 iAED1

Hazard statements (CLP)

H226, H302+H312+H332, H319, H361, H370, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids Category 3 Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 4 Acute toxicity (Dermal) Category 4 Serious eye damage/eye irritation Category 2 Reproductive toxicity Category 2 Specific target organ toxicity - Category 1 (Eyes) single exposure Specific target organ toxicity - Category 1 MS R0 iAED1 repeated exposure

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H370 Causes damage to organs (Eyes). H372 Causes damage to organs through prolonged or repeated exposure.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON MS R0 iAED1 4 CENTER/ doctor. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 4 Serious eye damage/eye : Category 2 irritation Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 1 (Eyes) single exposure Specific target organ toxicity - : Category 1 MS R0 iAED1 3 repeated exposure GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H226 Flammable liquid and vapour. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H370 Causes damage to organs (Eyes). H372 Causes damage to organs through prolonged or repeated exposure. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON MS R0 iAED1 4 CENTER/ doctor. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification None known. Section 3: Composition/information on ingredients Substance / Mixture : Mixture Components Chemical name CAS-No. Concentration (% w/w) Methanol 67-56-1 >= 10 - < 20 Section 4: First-aid measures General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : Move to fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact