ISD Sample Pretreatment

Roche Diagnostics Limited

Revision date : 2024-08-28

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GHS02 GHS06 GHS08 GHS05 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=70-<90 603-001- >=10% 3-<10% 3-<10%

EC/CAS

203-473-3/107-21-1

Name of the chemical

Ethane-1,2-diol

Concentration

>=10-<20

General Information

Revision date

2024-08-28

Product name

ISD Sample Pretreatment

1.2.1 Relevant identified uses

Laboratory chemicals, Refer to product literature for further details

Emergency telephone

+44 (0)808 100 1920, +44 344 892 0111, +44 845 4647

Icons in SDS

GHS02 GHS05 GHS06 GHS08 GHS09 M004 M009 M010 M011 M013 M017

Company Information

company name

Roche Diagnostics Limited

e-mail address of the competent person responsible for the Safety Data Sheet

burgesshill.customerservice@roche.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H318, H331, H370, H373, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H318 Causes serious eye damage. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist or vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.

Storage

ISD Sample Pretreatment 4 P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Hazardous Ingredients

Methanol Ethylene glycol Zinc sulphate hepta hydrate

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) as amended by GB-CLP Regulation, UK SI 2019/720, and UK SI 2020/1567) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 3 H301: Toxic if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Serious eye damage, Category 1 H318: Causes serious eye damage. ISD Sample Pretreatment 3 Specific target organ toxicity - single H370: Causes damage to organs. exposure, Category 1 Specific target organ toxicity - repeated H373: May cause damage to organs through exposure, Category 2 prolonged or repeated exposure. Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting effects. Category 2 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) as amended by GB-CLP Regulation, UK SI 2019/720, and UK SI 2020/1567) Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H318 Causes serious eye damage. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist or vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. Response: P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage. Storage: ISD Sample Pretreatment 4 P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Hazardous components which must be listed on the label: Methanol Ethylene glycol Zinc sulphate hepta hydrate 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Components Chemical name CAS-No. Classification Concentration EC-No. (% w/w) Index-No. Registration number Methanol 67-56-1 Flam. Liq. 2; H225 >= 70 - < 90 200-659-6

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