HL225D/NC

Robnor ResinLab Ltd

Revision date : 2022-10-01

SDS Library

Move your SDS library online today

Check Icon
Setup – Easy setup with our database of 16 million+ SDSs
Check Icon
Up-to-date – Your SDS get updated to latest versions.
Check Icon
Employee access – Tablets, Smartphones, or link from Corporate Intranet
Check Icon
Safety – One-click access to first aid information.
Check Icon
Labels – Generate Secondary Container Labels with just one click.
GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

≥50

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

≥25

General Information

Version

3.0

Revision date

2022-10-01

Product name

HL225D/NC

1.2.1 Relevant identified uses

Professional use Industrial/Professional use spec

Manufacturer Name

Robnor ResinLab Ltd

Emergency telephone

+44(0) 1793 823741, +44 20 7188 7188

Icons in SDS

GHS07 GHS08 M004 M009 M010 M017

Company Information

company name

Robnor ResinLab Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

eusds@robnor.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled

Hazard pictograms

GHS07 GHS08 GHS07 GHS08

Signal word

Danger : Danger

Hazardous Ingredients

Polymer of 4,4'-diisocyanatodiphenylmethane, 4,4'-diisocyanatodiphenylmethane : Polymer of 4,4'-diisocyanatodiphenylmethane, 4,4'-diisocyanatodiphenylmethane

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer (if inhaled). H373 - May cause damage to organs (respiratory system) through prolonged or repeated exposure (if inhaled). : H317 - May cause an allergic skin reaction. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351 - Suspected of causing cancer (if inhaled).

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P284 - Wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTRE or doctor if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label). P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P284 - Wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P321 - Specific treatment (see supplemental first aid instruction on this label). P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P362+P364 - Take off contaminated clothing and wash it before reuse. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Supplemental label elements

EUH204 - Contains isocyanates. May produce an allergic reaction. : EUH204 - Contains isocyanates. May produce an allergic reaction.

Additional information

Persons already sensitised to diisocyanates may develop allergic reactions when using this product. As from 24 August 2023 adequate training is required before industrial or professional use. Labelling according to: exemption for packages of a capacity of 125ml or less : Persons already sensitised to diisocyanates may develop allergic reactions when using this product. As from 24 August 2023 adequate training is required before industrial or professional use.

2.3 Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity — Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity — Repeated exposure, Category 2 H373 Contains isocyanates. May produce an allergic reaction. EUH204 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

SDS Library

Move your SDS library online today

Check Icon
Setup – Easy setup with our database of 16 million+ SDSs
Check Icon
Up-to-date – Your SDS get updated to latest versions.
Check Icon
Employee access – Tablets, Smartphones, or link from Corporate Intranet
Check Icon
Safety – One-click access to first aid information.
Check Icon
Labels – Generate Secondary Container Labels with just one click.