30279 / cis-1,2-Dichloroethene Standard

SECTION 2: Hazards identification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Emergency Overview:

Hazard pictograms

GHS Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 1

2.1 Classification of the substance or mixture

Flammable Liquid Category 2 Acute Toxicity - Inhalation Dust / Mist Category 3 Acute Toxicity - Dermal Category 3 Acute Toxicity - Oral Category 3 This chemical is considered hazardous by the

Signal word

Danger Danger

Hazard statements

Highly flammable liquid and vapour. Toxic if swallowed, in contact with skin or if inhaled. Causes damage to organs. GHS Highly flammable liquid and vapor Harmful if swallowed Harmful if inhaled ______________________________________________________________________________________________

Precautionary statements

Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilation and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. First Aid IF SWALLOWED: Immediately call a POISON CENTER/doctor/.... Measures: IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed: Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment see section 4. Rinse mouth. Take off immediately all contaminated clothing and wash it before reuse. In case of fire: Use extinguishing media in section 5 for extinction.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Technical Measures and Conditions Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep away from sources of ignition 8. EXPOSURE CONTROLS / PERSONAL PROTECTION United States: Chemical Name CAS No. IDLH ACGIH STEL ACGIH TLV-TWA Store in a well-ventilated place. Keep cool

Disposal

Dispose of contents/container according to section 13 of the SDS. Single No data available. Exposure Target Organs: Repeated No data available. Exposure Target Organs: 3. COMPOSITION / INFORMATION ON INGREDIENT Chemical Name CAS # EINEC # % Composition methanol 67-56-1 200-659-6 99.800000 cis-1,2-dichloroethylene 156-59-2 205-859-7 0.200000 4. FIRST-AID MEASURES Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Eyes: Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. Ingestion: Do not induce vomiting and seek medical attention immediately. Drink two glasses of water or milk to dilute. Provide medical care provider with this SDS. 5. FIRE- FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water may be ineffective but water spray can be used extinguish a fire if swept across the base of the flames. Water can absorb heat and keep exposed material from being damaged by fire. Fire and/or Explosion Hazards: Vapors may be ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a fire (Class B). Vapors are heavier than air and may travel to a source of ignition and flash back. Fire Fighting Methods and Protection: Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Hazardous Combustion Products: Carbon dioxide, Carbon monoxide 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Methods for Clean-up: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 7. HANDLING AND STORAGE Handling Technical Measures and Precautions: Toxic or severely irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Use spark-proof tools and explosion-proof equipment Methods Dispose of by incineration following Federal, State, Local, or Provincial regulations. Waste Disposal of Packaging: Comply with all Local, State, Federal, and Provincial Environmental Regulations. 14. TRANSPORTATION INFORMATION United States: DOT Proper Shipping Name: Methanol Dispose of contents/container to an approved waste disposal plant

TOXICOLOGICAL INFORMATION

Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: Eyes, Central nervous system stimulation, Skin, GI Tract, Respiratory Tract Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Inhalatioe Toxicity: Degradability: Biodegrades slowly. Ecological Toxicity Data: No data available. 13. DISPOSAL CONSIDERATIONS Waste Description of Spent Product: Spent or discarded material is a hazardous waste.

UN Number

UN1230 UN1230

Hazard categories

3 Packing Group: II International: IATA Proper Shipping Name: Methanol 3(6.1) Packing Group: II Marine Pollutant: No Chemical Name CAS# Marine Pollutant Severe Marine Pollutant No data available. 15. REGULATORY INFORMATION United States: Chemical Name CAS#

Further information

Prior Version Date: 07/22/14 Any changes to the SDS compared to previous versions are marked by a vertical line in front of the concerned paragraph. References: No data available. Disclaimer: Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a particular purpose, are made regarding prodcuts described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk. Creation Date 16-Sep-2014 Revision Date: 30-May-2017 Revision Number 2 1. Identification Product Name trans-1,2-Dichloroethylene, stabilized Cat No. : AC406840000; AC406840250; AC406842500 Synonyms trans-Acetylene dichloride Recommended Use Laboratory chemicals. Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific Acros Organics One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Emergency Telephone Number For information US call 001-800-ACROS-01 / Europe call +32 14 57 52 11 Emergency Number US 001-201-796-7100 / Europe +32 14 57 52 99 CHEMTREC Tel. No.US 001-800-424-9300 / Europe 001-703-527-3887

Prevention

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Ingestion Rinse mouth IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Fire In case of fire: Use CO2, dry chemical, or foam for extinction Explosion risk in case of fire Fight fire with normal precautions from a reasonable distance Evacuate area

2.3 Other hazards

Harmful to aquatic life with long lasting effects