RF 11

2.1 Classification of the substance or mixture

EYE DAMAGE/IRRITATION - Category 1 FLAMMABLE LIQUIDS - Category 3 HAZARDOUS TO THE AQUATIC ENVIRONMENT - A - Category 3 SENSITIZATION - SKIN - Category 1 SKIN CORROSION/IRRITATION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (Single E - Category 3

Signal word

Danger

Hazard statements

Causes serious eye damage Causes severe skin burns and eye damage Flammable liquid and vapor Harmful if swallowed Harmful to aquatic life May cause an allergic skin reaction May cause respiratory irritation Toxic in contact with skin

Response

Call a poison center or doctor immediately if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If on skin: Wash with plenty of soap and water for a minimum of 15 minutes If skin irritation or rash occurs: Get medical advice/attention. If swallowed: Call a poison center/doctor/ ... / if you feel unwell. If swallowed: Rinse mouth. Do NOT induce vomiting. In case of fire: Use ... to extinguish. Rinse mouth. Specific treatment (see instructions on this label) Take off immediately all contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse.

Prevention

Avoid release to the environment Contaminated work clothing must not be allowed out of the workplace. Do not breathe dust/fume/gas/mist/ vapors/spray. Do not eat, drink or smoke when using this product. Ground/bond container and receiving equipment. Keep away from heat. Keep container tightly closed. Take precautionary measures against static discharge. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Wash ...thoroughly after handling. Wear eye protection/face protection. Wear protective Butyl Gloves, Face Shield, Eye Bath and Safety Shower. Wear protective gloves. Wear protective gloves/eye protection/face protection Wear protective gloves/protective clothing/eye protection/face protection.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

Disposal

Dispose of contents/container should be in accordance with federal, state and local laws. Ingredients of unknown 0% toxicity

2.3 Other hazards

Page 2 of 11 EMERGENCY OVERVIEW DANGER: COMBUSTIBLE. CORROSIVE LIQUID. MAY BE HARMFUL IF SWALLOWED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CAUSES EYE BURNS. CAUSES SKIN BURNS. MAY CAUSE RESPIRATORY TRACT IRRITATION. INGESTION MAY CAUSE GASTRIC DISTURBANCES. Avoid contact with the skin, eyes and clothing. Avoid inhalation of mists/vapors. Use with local exhaust ventilation. Wear a NIOSH-certified (or equivalent) organic vapor/particulate respirator. Wear NIOSH-certified chemical goggles. Wear full face shield if slashing hazard exists. Wear chemical resistant protective gloves. Wear protective clothing. Eye wash fountains and safety showers must be easily accessible.

Principle Routes of Exposure

Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Route of entry for gases include inhalation and eye contact. Shin contact may be a route for liquefied gases.

Medical Conditions Generally Aggravated by Exposure

Data available do not indicate that there are medical conditions that are generally recognized as being aggravated by exposure to this substance/product. See MSDS section 11 – Toxicological information. Section 3. Ingredients CAS Ingredient Name Weight % 104-78-9 1,3-Propanediamine, N,N-diethyl- 100 % Occupational exposure limits, if available, are listed in Section 8.