URETHANE 51606-MV PART A

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~  GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure d ~  GHS07 Acute Tox. 4 H332 Harmful if inhaled Skin Irrit. 2 H315 Causes skin irritation Eye Irrit. 2A H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction STOT SE 3 H335 May cause respiratory irritation Classification according to Directive 67/548/EEC or Directive 1999/45/EC @ G Harmful Harmful by inhalation. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation @ G Irritant Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact Information concerning particular hazards for human and environment The product has to be labeled due to the calculation procedure of international guidelines Classification system The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data

2.2 Label elements

· Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. (Contd. on page 2) US (Contd. of page 1) · Code letter and hazard designation of product: ? @ G Harmful

Hazardous Ingredients

4,4'-methylenediphenyl diisocyanate methylenediphenyl diisocyanate

Hazard statements

Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by inhalation and skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Precautionary statements

Keep locked up and out of the reach of children. Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Dispose of this material and its container to hazardous or special waste collection point. In case of accident by inhalation: remove casualty to fresh air and keep at rest.

Special rules for supplemental label elements for certain mixtures

Contains isocyanates. See information supplied by the manufacturer.

Classification system

· NFPA ratings (scale 0 - 4) Health = 1 1 Fire = 1 1 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *1 Health = *1 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.1 Classification of the substance or mixture

d ~  GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. d ~  GHS07 Acute Tox. 4 H332 Harmful if inhaled. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC ? @ G Harmful Harmful by inhalation. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. ? @ G Irritant Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact. · Information concerning particular hazards for human and environment: The product has to be labeled due to the calculation procedure of international guidelines. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data.