known. Reproductive

Hazard statements (CLP)

H303, H315, H333

Code

Statements

H303

May be harmful if swallowed

SECTION 2: Hazards identification

OSHA Hazards Identification * * *

2.2 Label elements

Sym

Hazard pictograms

1ói:. Ëxciaination Exclamation Point

Signal word

Word: WARNING!

Hazard statements

May be harmful if swallowed. Causee Causes eye irritation irritation. Causes Causes skin irçitation: irritation. Harmful if if inhaled:: inhaled. Do Do not eat. at drink, dtink, or or use-tobacco use tobacco when when using this product. Useorily Use only än in a well- ventilated area.: area. Do: Do not breathe dust. Wash, Wash thoroughly after after handling: handling. * * Section Section 3 - Composition i information * ** 1 Information oh on Ingredients * * OSHA ACGIH HAZARDÖUStINGREDIE_ HAZARDOUS INGREDIENT NT CAS # PEL(mgim3) PEL(mg /m3) TLV(mg/m3) ALUMINUM FLUORIDE' FLUORIDE 7784 -18 -1 -1 2.5 (as F) F) 2.5 (as F) 'OSHA OSHA -PEL and ACGIH -TLV are are O 9 -Hour TWA unless otherwise otherwise noted, toted. , per CFR 29, Part 1910.1200: 1910.1200; ngrcdients ingredients listed only ifdeemed if deemed hazardous and comprise comprtte 'I% 1°A or greater or of the compositor)

2.1 Classification of the substance or mixture

Classification: Skin Irritation, Category 2 2 Eye :lrr Irritation, taiion, Category 2 2 Labeling; Labeling: Sym Symbol: 1ói:. Ëxciaination Exclamation Point Signal Word; Word: WARNING! Hazard Statements, Statements: May be harmful if swallowed. Causee Causes eye irritation irritation. Causes Causes skin irçitation: irritation. Harmful if if inhaled:: inhaled. Precautionary Statements; Statements: Do Do not eat. at drink, dtink, or or use-tobacco use tobacco when when using this product. Useorily Use only än in a well- ventilated area.: area. Do: Do not breathe dust. Wash, Wash thoroughly after after handling: handling. * * Section Section 3 - Composition i information * ** 1 Information oh on Ingredients * * OSHA ACGIH HAZARDÖUStINGREDIE_ HAZARDOUS INGREDIENT NT CAS # PEL(mgim3) PEL(mg /m3) TLV(mg/m3) ALUMINUM FLUORIDE' FLUORIDE 7784 -18 -1 -1 2.5 (as F) F) 2.5 (as F) 'OSHA OSHA -PEL and ACGIH -TLV are are O 9 -Hour TWA unless otherwise otherwise noted, toted. , per CFR 29, Part 1910.1200: 1910.1200; ngrcdients ingredients listed only ifdeemed if deemed hazardous and comprise comprtte 'I% 1°A or greater or of the compositor) composition 0:1% (0 1% or greater for for carcinogens)._ carcinogens). cOn Component ptànent.Related Related Regulatory Information Information: This product may be regulated, have exposure limits limits or other information identified: identified. Measures * * * * * * Section 4 - First Aid Measures*** FIRST FIRST AID: INHALATION: Move Move victimytä victim to fresh air.. air. if If not breathing, give artificial t'espIitation,.if respiration. If breathing is difficult, give oxygen. Get medical medical attention. attention. EYES: EYES: Hold eyelids . eyelids apart and flush with running water for at at least- least 15 minutes, minutes. Get medical attention. SKIN: Wash affected area with soap and and water. water. Remove, Remove contaminated clothing. clothing. If irritation or burns are present, get medical attention. INGESTION: If If tbnsc.ious, conscious, give plenty plenty-of of water._ water. Do not induce vomiting. vomiting. Get Get immediate immediate medical medical attention: attention. Speöiál Special Treatment/Notes to to Physician:. Physician: None` None rage Page Ï i of of Revision sion Date: 10 J29110 /29 /10 Rëv3. Rev3 3) ALU BRAZE ADDITIVE AF Safety Data Data Sheet Sheet Proddct Product Trade Name: ALU-BRAZE ALU -BRAZE ADDITIVE AF ID: ALBRAZAAF Respiratory PrOtectitin: Protection: If ventilation ventilation is not sufficient sufficient to toeffectively effectively prevent buildup buildup of dust. dust .Misis mists or Vabtirs, vapors, provide appropriate :NIOSH/MSHA NIOSH /MSHA respiratory protection. protectiOn. Persdnal Personal Protective Protective Equipment: Provide eyewash fountains fountains in n areas areas where where there there is is any possibility pcissibilitythat that workers could be be' exposed totite, to the substance: substance; this is irreSpective irrespective of the the recommendation recommendation involving the wearing wearing of of eye Oeotectidn: protection. Provide facilities facilities for quickly drenching the body body within the immediate immediate work area area for emergency use where where there is a a possibility of exposure. Depending on the specific circumstances, a deluge shower, shower, a sink or ' hose hose cOuld could be cOnSidered considered adequate. adequate. * * * * Section 9 - Physical Physical & & Chemical Pebberties Properties * * * PhysiCal Physical State: Solid Appearance Appearance/Odor: /Odor: odorless, white powder.. powder. pH: pH; N.A. Boiling Point: 'N.A. N.A. SpecifioGravity: Specific Gravity: N.E. Melting Point: 190()-- 1900'F ,Evaporation Evaporation Rate: N N.A. A. Flash Point: Point:: None. Solubility Water: Water:, complete. Auto-ignitiOn Auto- ignition Temperature N,E. N.E. Vapor Density: N.A. Decomposition Point: Point: N.E. Vapor Pressure: Pressure: NA N.A. Flammability Limits -Low: - Low: N.A. OctanOlMater Octanol -Water Coefficient Coefficient: N.I. N.E. Hi: N N.A. * * * * Section Section 10 - - Chemical Stability & Reactivity Information information * ** * Chemical Stability; Stability: STABLE ' Conditions Cgriditions to Avoid: 'None, None. incompatibility: Incompatibility: strong strong aPidS. acids. Decomposition ProdUCts: Products: hydrogen fluoride under thermal decomposition decomposition in in the presence of of mbisture. moisture. Hazardous PelVmerization: Polymerization: Will WII not occur. * * * * Section 11 - - Toxicological Information * * * EtnetgencY OVefvieW: Emergency Overview: - Contains FLUORIDES: FLUORIDES. May cause seière.eye,- severe eye, skin and respiratory tract irritation. May May cause eye and Skirt skin burns. burns. Hartplul Harmful if inhaled. Harmful and may be fatal if swallowed. swallowed. Chronic Chronic exposure to to Fluoride-Ion Fluoride -Ion has been reported to to result result in tooth mottling, ...bone bone fluorosis and,osteosolero,siS and osteoscierosis in in huinari's. humans. Avoid contact with with eyes, skin skin or ,ciothing. clothing. Avoid inhalation of of dust dust. RouteS Routes of Exposuré: Exposure: eye/skin eye /skin Contatt contact, inhalatibrt inhalation, ingestión;_ ingestion. ACute Acute ToxiCitY; Toxicity: A:'Generei A: General Product information Information Eyg Eye Cgn Contact: tact: Causes eye4critation:i. eye irritation. :Skin Skin Coritatt: Contact: May pause cause Skin-irritatiOn; skin irritation. Page Page 3 of Revision Date: 10129/1U.Kev3 10/29/10 Rev3 3) ALU BRAZE BRAZE ADDITIVE ADDITIVE AF AF Safety Safety Data Data Sheet Product Trade Name: ALU-BRAZE ALU -BRAZE ADDITIVE' ADDITIVE AF JD. ID: ALBRAZAAF * * * * Section Section 14 14 - - Transportation Transportation Information ** * * * US US DOT DOT Information ALUMINUM FLUORIDE FLUORIDE MIXTURE MIXTURE HEAT HEAT TRANSFER OR BRAZINGSALTS: I3RAZINGSALTS, NON D.O.T. DA. T. REGULATED Marine Pollutant: Pollutant: Not Not classified as a,madne a marine pollulant pollutant, WOG IMDG Classification Not Not determined: determined. lATA IATA Classification Nokietermined Not determined ** * * * Section Section 15 - Regulatory Regulatory Information Information **-* * * * US US Fgclditl Federal REfgUlations Regulations A: General Product Infärmation Information No additional information available: available, B: domponent Component Analysis Analysis This This material may contain chetnicali,-requiring chemicals, requiring Identificationpnder identification under SARA Section 302 (40 CFR 355 355 Appendix,A), Appendix A), SARA Section 313 (40 gFER CFR 372.6). 372.65), or or CERCLA CERCLA (40 CFR 302.4), 302.4). HAZARDOUS: HAZARDOUS CERCLA SECT 302 302 SECT SECT 313* COMFONENt COMPONENT RQ LBS. LBS, TPQ LBS. TOXIC % °Lo by Wt; Wt. No CERCLA or er SARA 313 components N.A. NA, N.A. fki9 No k, SARA 311/312 3111312 HAZARDS, HAZARDS: . : Irninediate immediate (Acute)_ True Chronic* Chronic' ...... :..,..,.......,......._True True - 'Fire Fire False Sudden Release-of-Pressure.. Release -of- Pressure False Reactive Reactive . ... ; False . State Regu Regulations iatiOrit A: A: General General Product ProduCt Information No infOrmation information aVailable: available. Other Regulations Regulations. A: General General Prodtitt Product InfOrMatiOn Information ,All All components are are on the U.S. EPA TSCA inventóry Inventory List, ,B: B: Component-Analysis Component Analysis -inventory- - Invento ry CAS it # Component I TSCA TSOA DSL EINECS 7784 7784;18-1 -18 -1 ALUMINUM FLUORIDE FLUORIDE YES ' ** * * * Section 16 - Other Information Information * HMIS Ratings; Ratings: Health: 2 2 Fire: 0 6 Reactivity: 0 0 Personal Personal Protection: Protection: X X lia4ard Hazard Scale.;. Scale: O 0 =MmnimaJ = Minimal 1 = = Slighl Slight 2= 2 = Moderate 3 = Serious Seriou. 4 = Severe Sev0e- = Chronic Chrontobazárd hazard NIS:DS MSDS Change Chanoe History: History: 2/1 2/1E3102 8/02 Rev2 Rev2 1'0/29/10 10/29/10 Rev3 Format update update (all sections) Information update (all (all sections) ?tg Page e 5 5 of Of 6 6 Revision Revision Date: Daw10/29/10 10/29/10 ReV3 Rev3 * t313) (313) 895-7215 895 -7215 lHI1:HLti -17 -11 r-sis,1111:1,14111-,..111 rl1,1111111,1111 'APIR*26. APR .. 26. 2000 2000 .,a,..,.,,, V g: 9 2SAM 29AM : HErHIBHIH *it*#t****#'k#dE***;F*}ritit*kiF**9r***;E*iF*(P*#-****ßF*ìbßba614ßf3b*##,gi8*3F({ k**#96;(#Ya+4****4h1f***84*ar.a;.* hNieNTEp. T MATEFIAL AL SrAIF-ETV A F-RT. "410 PAVT DATA 0HEET PARk PARK METALLURGICAL METALLURGICAL CORPORATION 8074 8074 Military Avenue Detroit, Detroit, Michigan 46204 48204 _ SECTION 1 1 Product Product Nabe: an :ALUMINUM ALUMINUM 1RAZING BRAIIN6 SALT 06o 1ALI MA Rav.01 formlita Formula Anpberl Number: ALIRAISB69 ALIIRA1 860 Date: 40; 11/03117. 11/03/97 * ...a -4,4,:>4:-^ 4-- .44,447,44 .. _..-... ..n_..+..r..9+..-..yi.."w-.I.strw.wr9rrslYU+ti.+v....rw-.+w.+,r+w . SECTION SEGTIDN 2 2 - HAZARDOUS HAZARDOU$ INGREDIENTS SMIPIIII0 TIN ow.. 10. 4,45.,,, * Vb., row 31* :- rls ÿAS Registry)10.. Registry No IngyedInt Ingredient TLV E0thet) (Other) UDIUM SODIUM FLUORIDE -MU! -49 -4 7581-49-4 1;5 7.5 A/kg mg/kg (F) (F) AlUNINUN FLUORIDE ,r-N7784 -7784-19-1 -15-1 2.5 mg/ky mg/kg JF) IF) a.. s ,.!' - SEPTTPN. SECTION 3 - PHYSICAL-DATA PHYSICAL DATA -06rcentVplatilel Poi cent Volatile: NA Dni Boiling I A.g: Poi nt: , Point: 'AA, NA: Pressure: NA - tvapurativn-F4tel EVapuration Rate: NA Vapor -Pressure: APPREC. Water War SolubllitY; Solubility; ,APPREC, pH: NA 11,0 SpeWit Specific Gravity; 5ravityt AppeatancOt Appearance: 41)WDEP PONDER ._.____. _ IAA - ___.___. sgcTioN, SECTION 4 4 - __- __., F. F RE AND EXPLOSION HAZARD FIRE .,. HAZARD. DATA .4e._ mot . 1 F.-lah FIash Point: NA tiomably F13eaaple -Limits; Limits; NA :Extingasl)ing Extinguishing Media: !AA NA Special Rte Fire FightIng Fighting Pracedurest Procedures: NA - t44.115441 15ual -47jr Fire And and ExIlosinn Explosion Hazardst Hazards: AA NA APR . r.- E6 9;;;3114--fr- 9 3EIFrtr--°RitH : . 20:a@ 1 i Lf.1 ;I iiH tH,I hi SECTION 5 -- HEALTH HEALTH HAZARD HAZARD DATA DATA a a tam ; 4.; 4titeatt 411,:f 4.0 .74;;;?1,7,:va.i....4..a..14..... mr Ihruhold Thmhold Lipit:Valme: Unit Value: SEE SCI SCT XI II Effects of OvereAposure: Overezposure: SKIN SKIT' - - CONTACT MAY CAUSE rORMATION FORMATION Or OF LARGE,. LARGE, OPEN OPEC, BOILAIKE $OIL -LIKE tORES SORES ESPECIALLY ESPECIALLY IN IA OE THE -PRESENCE PRESENCE OrMOISTORE4 OF %STORE, "ALATION .!ALATION - MAY MAY PRODUCE CHRONIC CHRONIC POiSONTRG., POISONING. E/E2- EYES - -MODERATELY MODERATELY IRRITATING. IRRITATING. Erlergency Emergency and and First first Aid Aid Procedures Procedures: : SKIN SKIN AND EYES' EYES 'FLUSH --FLUSH WITH LARGE AMOUNTS tF OF DATER. WATER. OBTAIN MEDICAL MEDICAL ATTENTIOL ATTENTION. INHALATION:--REMOVE_ INHALATION - RENOVE PERSON PERSON FROM FRON CONTAMINATED AREA, AREA, IF IF IYMPTONSAF SYMPTOMS OF RESPIRATORY RESPIRATORY DIsconFoglpstsT,00TAIN DISCOMFORT PERSIST OUTAIN muIpAL MEDICAL ATTENTION ATTENTION -IMMEDIATELY.. IMMEDIATELY, a_ a at a W _....,,.. . ........ a. a 4,44 atia ....._............a a...a,. a at ...__..._.__... SECTION 6 fi - REACTIVITY REACTIVITY DATA ATA ..» .._.,....._.».............,. ataa a a at, iiett)t.4 . _ 444: $,Stabitity! Stability: ''YES YES Iticopatability: Incaapatability. -NONE NONE KNOWN Yaudous Hazardous Docoppostipp Oacqepo5tion Products: Produttsi HF FIF 844rdous Hazardous Polymerization: PoIllterI241iue: NO a a...a.; a- a. a - $ECTION 7 ", SECTION - SPILL DR OR LEAK LEAK PROCEDURES 1'74' ........ -.4,-. a a 4, a a a 44.a...a a. ApiLl -Spill Informationt !Volution: SWEEP UP-AND UP AND RETURN RETURN TO 'DRUM DRUM FOR REUSE IF SALT HAFROT-BECOME NM NOT BECOME WET. 1L VAstp,DispósaAi Taste Disposal: THIS MATERIAL IS IS CLASSIFIED AS A HUN-HWROOUS NON -HAZARDOUS WASTE ORDER UNDER THE REEDURCE, RESOURCE OONSERVATION CONSERVATION Alp AND RECOVER/ RECOVERY ACT'.. ACT. aaa a..."...,H....,'",01:!...a>,,.. SECT! SECTION ON 8- SPECIAL SPECIAL. PROTECT' PROTECTION ON INFORMATION I NFORMAT I ON Rispiratdry Respiratory Protection: NTOSH APPROVED DUST 'MASK MASK IS-RECONNENDED IS RECOMMENDED FOR1AOLINO FOR HANDLING DRY DRY PRODUCT,IDR-IF PRODUCT DR IF FUMES FUME$ "MomE BECOME Ex_cOpy;:- EXCESSIVE. Mentila #ion; MHANICAOENTKATION MECHANICAL VENTILATION IS IS RECOMMENDED RECOMMENDED TO .COMPLY COMPLY WITH WITH THRESHOLD THRESHOLD LIMIT UNIT VALUE STATED IN SECTION Y. P'TotKiive Protective SI4v0s1 aloes: THERMAL THERMAL.PROTECTIOWRECOMMENDEIL PROTECTION RECDMIlENDED, tys Eye Protection; Protection: SAFETY SAFETY GOGGLES DOODLES RECOMMENDED, RECOiiAENOED, Oth.pr Other Prntectiye Protective Equipment.; Egaippertt. JNERMAL THERMAL PROTECTION RECOMMENDED. RECOMMENDED, . ,...;+, - eratapy we. SECTI SECT/ON ON 9 9 -- ,SPEC SPECIAL I AL PRECAUTIONS PRECAUT IONS . Handling Handling and 464,5t04ge Storage Precaptionl: Precautions: sToRE STORE IN XtOSED CLOSED tONTAINERS'TOAVOTO CONTAINERS TO AV D MOISTURE PICK URi UP, Other Merfreta0005i -Precautions: ,DO DO NOT NOT ADD WET WET SALT SALT TU MOLTEN tipLTEm SAP SALT BATH. BATH, 5) 5) Ammo Arnmonium nìúmBitluórake aifluoridéfiake- Spaa Spec, (BR-1). (BR-1) ..Cade.. Coglel 10303 1003 -:1)attic .04-22-89 04--32-89 . INuvTR 3Z:r SA.TY' 172V1**.r1,. 5318s; nD i'rodtxct: :A.t449# Bk-13.1 AMMONIUM ';lity*.T,CAR.:1DE HIFLUC:RIDE FLARE FLAKE BPEC sPEc 404 104 R,,; " :s'.0 1:-: 0 r-' C a 6111 4' m ... w_ .., .. e Ccittimon Coiazncn Name Name. : :___A,MMÓtiTUM -,--41240111/11-1ACTD ACÌD='Fr,UcìATnE Oitaidii1 CYäe4ca1 -,10.44.:i'.:,''A1n#44014:13.1.-Fiitf.004-;'--.'. , Name :'AMMONIUM 3TFLÜOtIÄÉf: ormúle1. : ' NH4 FHF; P rodrié t CAS # 1341-=49-7 $upp3 iex: : MÑG.ELHARD CoRPóRÁTZòta, CoRPP:M.' ------:.:: s- _ 'ztTGINZERED. ENGINEERED MATERIALS Mugi 11IVISION, DIVTS ION -Address ADVANCED PINISFï_TNC .TEC'r;PdoL:OGZEs GROUP : Z9_ó01 SOFl3 `'RÓÁD:_:. e v : Stj Zip : SdL03r', ai 44133 P$Öne Phone , . . :.:--i.,.-.04¡2!2.49i.po : . 215=292-9200 , ' ti*ROMP4 EMERGENCY PRONE . PHONE .#: 216-292 9204 . ..... - _ .. ................... ;-.r1.1: TAZA.13P0..Pi :XX .GREDIZITZ:Z$79Rlaritg.t. :1.::!;;;i1.4.-.1 INGREDIENT 1.11W.I.EDI.ENT ., % Wt.' .PEIr-0SHA *fr.OSHA TLV6ACG7.R 1.0..ACGTE . 71,1$07:114 AlcbNZUM 131 nu4RI-IE CAS fit 1341-49-7 98 . 9 2: 5 zt:g¡3It3 as E -m1' as 2,_5 2.5 Agim2 gl:r,= as as F F - 35 35ppm :. as NK . ppm as NI13 2 25 ppm E?pm art Nii, ,as NH3 sTEL , = - .STEL' . INGREDIENx, xxercgp.mm, HAzARD 114.13.9 twipmiT STATEMÉNT, causes Causes eye eye and and skin skin 'cairns. 'pùrxis; Causes Causes skin skin :àn4 and ..reePiratory respiratory tract irritation. tract i.rrä.tatián. ót and atótaS dust (p4rticu10es (particu,látes önly) only) A1I, ACGITi AP.Pik TL3Ts. TVITs lia? Harmful nttí1 if ssiialitived.- if swä,l,ówad.' uíi:ess tjii1+04, Ott terwfise. noted/ all value s reported herwise riateá,, all values áxe Are Yeported as 8-4011r as 8-hour, 'Time-Weighted Time-Weighted Averages AverAiges' OWAs) (TWAs) arid stottl -duet PELe refer refer to to 29 29 -FR -C111 Part Part ° refer 'ix refer to -th® the 1988-$9 Standads. 1988-89 standeres,' 741 QSHA. All OSHA. PELs 1910 Air ontamikAnts: 1910 Áix . Coìitamxriätits: Firiäl 'Rule/ Rule, January January 19, 19/ 1989. 1989. 'SECTION IITY L.P.4.01CAVORztEM,41 'PHYSXGgLZCfMEECAt. CHAVAGTËRIS cgn4c1.14a6Tr . Boiling B0,04.:±ig -Point: 239.5°C 239'..5*C ,Speoltip Specific Gravity (H=Q.*l) 1.$03 1.503 : Melting Point: MitliOJW Poiñt: 12ä.2°C 126,2°C 44) ITot applicable Vapor 7itsi#:04: rapar : pressuz'e (mm Hg) a Not ZvapOrat*iitirt vra P,. orätiçn Rate at púty1 Aeètates1): Vapor A.cetAte=.1.):aot applicable. Deti4ff (D4) Not applicable ( Air=1.) : N4t applicable ot eri;p1itib1e 5t solubility/water: 8o1.4-i1itWvIeter: 58.3 4,166 -4 water 58.3 q/100 g Tao.* y . : - rrjrpóriiiiYfC:Bifluoride Flake Speç_(BR=1) : transludent translucent flakes 74)44.* Whit4= flake0':?,`,:Oni-iii.oil: `:.4 OYYïäC odor odor Flash Flash `'Point: Point; Not Not available' ayail.dbf,é. >-, IkUtO#Zgnition: Áùtó.Igrii.tiórn: tiot:':avarablë. Not available LEL: LEL;Not Not ,available ávai,lakalle UELs''>N0t UZL; :.iivtiaabIe ,:, ...::..:::... .. iglA ÄSARD NIPPA`b2ARD,CLASSIFICATION : CF.A88IFICAT;IUN Health: 3.; F].aabl.é; a. Reaetivitys rositiv.ity.t o HMIs MOM CLASSIFICA3'ION.: Bias HaAllb clawFic.A, v9,N, Aealtht Realtlas .3* 3* rlambables FZables o 0 Heactivity:. 0 RsaCtivity! -.:.;.... ,_ .,_:.:.-...: E3ÇIH3iiING EXTTIOCrigHXNG 2ïSb2:A. MTh. Uss carbOin-diogidA.Or 17e0 :::carbott di.oxide or OheTlfical Chemical föam. foam- 4 SPECIAL SPECIAL FIRE FIGATING FIGHTING P.ROCEDU'REB PROCEDURES Waar Wear ,poskitiirs-pressure,selt-qontained posi.ivs-essuze: sel-roontairißd breathing breathing apparatus. apparatus. 1017VS74L FIRE. Intro74 P;rtz M'fl AND ExPliosX0H :HAZARDS ;EXPIßSI411 -114;ARDS Not A. Not A firo,Pr sx140sion hazard - .Howevert in a t.re fixe. or expl,o04.án hazä;'d. prcduct product wilZ thì will a/4t emit töxië toxic gásás: HoWov4x, %n gases-. Contact Contact With e. fire. situation this with .water water will wi,ll form fflrm: corrosive corrosive : 15u10x'.4,ç sultiliic àçid. acid. ' ßECTION.:g 4i'v tiiC DATA. ,:,, ' =s : .: Stability: StabilitY: Gensrally GenerallY -c.an0:dereçï st:áb3,e. considered stable. A"vài$i Avoids Tempartüres Temperatures ab.óv above :400°F. 4009f. IRCOMPA2.IBILITY (Materials niCMPATIBILITY (materials to Avoid) to Avoid) Strong acids, acids, alkalies; alkalies, chlorine, cyanides, cyanides, sultidee.' sulfide, (Th 7- '7 " kZARDlUS nECO*SITION - ï+ QR `,fl3L-:äRdi3K3'.TS s .. s_ es 4 Y S a .3 ~ r , S .x.:.. ':^ '.::; , ry;:_Jl,l.,'i; , ,' 4 W! . .~;' h ,rä *:i 63 A+rFüiïra ífluoiçli.läke Sìgv; f SR 1) - . ,.. 40:054444'f hÿdrógé xçrd4. c' ' wríñt" rgluoxi nt with :*#¡5-h4 ac4.s::; st1î lies. Poi; 3zaticni poiyme#izátiári 4s: nòt,.:e4e4ed to oceur.' 4010 lt.ért applicable; _ .... a:r -,a..äSAtf:!!s; YS: : 'v a'`t .îts" _s: :,.T. _: r. .- ,.;:; i,;-' .ü' ;:il ir .LJ..c;y, a 'rï si: i'.:£r¿.. s: .cs.m. i,.,; E r asm ! " !V ::ir:y!r s :nn:u' :S'..'i%ii;!'F1F."il. y s 7` CA,t3ÇÏ3,';:i2PïtPi:.,:Y_ .:, , ä.u,,Z;A. ., ...'.* t::o.::vr,csi.l: , ::s_:_ !..: ;w-_'.'.,', : ROUTES s 'or OF ENTRY ENTRY 0 OF 0****?OSi3*E OVOEXPOSVRE - /nhalation? Irútál.átá.vn? XEs YES In/astion? YES Eyes? YES .. Ski? ,.:. , YE . 700CTP MEOTS BYE E$ COÑXACT. :Cii.0:es dONTACI °valises burns. 3Surits .: , : CONTACT causes c severe irritation and fiiorxde-like ,irritation and fluoride-iike burns which 111áy , s which may ' SXIN SXá. g401WZr itu0s sevsre ."x_ : hot b4 imm44iateLy'evident- üämdiat±OW*Yiieüt. irritation to to the this upper upper respiratory respiratáry. tract. tract. INHALAT=QN causes IVEMATION causes severe vsre irritation 4rr#ati.on of of tile the gastrointegtihal gastró.i..ht'eztinal tr40t;: 00004, Zr104:49N 0044s0 irritation I$GESTXON Ca4ses tract, nausea, voitim vçmitzg Itnd diarrhea. ad ; áiärr2ïèd. c04NOGgrs;911r CARCINOGENICITY /Th, NU? N01 o ' IARc? xAIW NO ,'21d ßSïïA? N4 OSHA? NO CßItgtilC cHikaac HBAtfiH HOARDS mum nA2ARD6 .Exposure Expósizre. tc to :FLÜßRIfiËS FLUORIDES 'over over years years 'ánaÿ may produce produce embrittlement enibritt3emèrit;end end çîeça:lcif ication of of bones, ).:iones.- and and inCreáS.eci increased ca1cifi.cat.i.On calcification of ligaments of ligaments and . and vertebrae restatingtin spinal vertebrae ree4ting in aepalcilication spi:xíà1 -stiffness stiffness {:£Iuoresis} (fluorosis). MEDICAL MEDICAL CONDITIONS GENERALLY GERAILY ACGRAvATEO 2 AGGRAVATED BXPöSITRE BY EXPOSURE . May May aggravate aggravate existing existing respiratory respiratory and/or and/or akin skin ailments. ailments, .,. . . Et.0`1toE;kICY 1ND FIRSM EMERONCY Mt IRS[' AID PROC'EDTES PROCEDURES EYES EMI s. IM1I%044telY .. Immediäte3:ÿ flugh-with .... .. plenty of Water for plenty ó;f water for atiegst-P t', ].egst minutes. 0 ULutes. D.o Do "ÑO3: NO use 'use tephiran Chloride solutions 40p;Piïrari s41,ut:icns on 4-Ye Oy.gi,eien. SKINS Immediately flush Plune0,ate1Y tltish. -with cold water for least Minutes, . w.t çöI á..watex zor at least. 15 tf,nutès, vse . at 15 Use 00040e aDCa4re eop soap i avni-läbX. ava.iabie. _U I..f irritation 6Ciars, irritáticin öcçür"s, kitud4r$AIihd:soak 1411terie;ariä:= sáák akzEicted AÉfectëd .á*;izîa ar4t, kn 0,1,3% .(1-750) iced, aqUeoue .n 4.0* -4i7$0) f .i.çéd; agiieoue zephirat.Chipride Zephzran Ch3.oricia soiution solution . r' .. : , .t)iñ . = '+lp,: . , .. (BR 1) Sc '2! .: e Flake ., .