CLP

Hazard statements (CLP)

H225, H226, H304, H317, H319, H336, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

and BGR uses properties vPvB of assessment equipment (including personal the N-butyl-N-[(triethoxysilyl)methyl]butan-1-amine May criteria of 1000 substance Industrial cause for this an Materials-7, or allergic mixture not protective class skin 1989 available equipment referred to under Section 8 of the safety data sheet) to prevent and reaction. uses Edition advised against 14.7. - IFA Maritime SECTION 4. First aid measures AGW H336 GESTIS transport website DEU in bulk according Distillates May 380 cause (petroleum), to drowsiness IMO 200 instruments hydrotreated or dizziness. 1520 light 800 any Initial contamination boiling point of skin, eyes and personal clothing. not These available indications apply for both processing staff and those involved in emergency 10.6. Intended 4.1. procedures. CARCINOGENICITY On - ECHA Flammability Description of first aid measures Hazardous MAK EUH066 the basis website use of decomposition available DEU data, the products N-(3-(trimethoxysilyl)propyl)ethylenediamine Repeated 380 product exposure does not 200 contain may Permanent not available cause any skin

PBT Substances

surface 1520 dryness or vPvB protection or in percentage cracking. 800 varnish ≥ than 0,1%. Information - Database Lower explosive limit TLV of not SDS relevant models GRC for chemicals Trimethoxyvinylsilane 1900 - Ministry 1000 of Health and ISS (Istituto Superiore di Sanità) - Italy not available 1.3. 12.6. In Does In Send Upper Details the case away Endocrine TLV not event of meet the explosive of doubt individuals of disrupting thermal the supplier or limit in the who presence classification ROU decomposition of properties are not of suitably the criteria safety 1900 or data symptoms for fire, this sheet equipped gases hazard contact 1000 and class not Use a available vapours that 9500 doctor explosion-proof and show equipment are potentially 5000 him this document dangerous to health may be released Eliminate all sources of ignition (cigarettes, flames, LEGEND In sparks, Flash case point ПДК of etc.) more from severe the leakage RUS symptoms, site. ask for immediate 23 medical 1000 T ≤ aid 60 2000 SECTION Name REPRODUCTIVE Based ADR: WEL on European the available Regulatory information Agreement TOXICITY GBR data, concerning the product 1920 the does carriage not 1000 contain DRUCKFARBEN of Dangerous substances goods listed HELLAS by in Road the SA main European lists of potential or suspected endocrine Toxicological information EYES Auto-ignition Remove, temperature if present, contact lenses if the situation not available allows you to do so easily. Wash immediately with plenty of water for at least 15 Full minutes, disruptors Note Decomposition ATE Other Environmental TLV-ACGIH address for Acute hazards users opening temperature with Toxicity environmental the precautions Estimate effects under evaluation. MEGARIDOS AVENUE eyelids fully. Get medical advice/attention not available 1884 1000 District Does The CAS information not Chemical and meet Country the contained Abstract classification Service in the criteria present Number for sheet this hazard are based 19300 class on our own ASPROPYRGOS knowledge on the date of the last version. (ATTIKI) SKIN Users must verify the pH In the Safety, Take absence health off immediately of experimental and environmental all contaminated data for regulations/legislation the product clothing itself, not Wash available health immediately specific hazards for and are the evaluated thoroughly substance according with or running mixture Reason to the water properties for missing and soap of data:substance/mixture the if possible) substances Get it is 12.7. On suitability medical The contains, CE50 Other the basis product Effective advice/attention adverse using must the not and of thoroughness available concentration effects data, criteria penetrate Avoid specified of provided the further required into in the contact product the sewer information to does applicable induce not a according with system contaminated contain 50% effect) regulation or come into any to PBT for clothing each GREECE classification contact with surface water or non-soluble or specific vPvB in use percentage of the product than 0,1% ground water in water) STOT This INGESTION Kinematic It Seveso CE: document is therefore Identifier SINGLE in must Category viscosity Do necessary EXPOSURE not ESIS not (European Directive induce be regarded to take vomiting 2012/18/EU into account Hydrocarbons, archive as a of guarantee unless explicitly existing C9-C11, the concentration Tel substances) 1040 on any n-alkanes, authorised mm2/s specific +30 of by the a individual product doctor isoalkanes, 210 5519500 P5c Do hazardous property. cyclics, <2% aromatics not give anything substances Method:Converting by mouth indicated to an in unconscious section Formula 3, from to person evaluate Dynamic Get the medical The Threshold Information CLP: product toxicological Methods use Regulation advice/attention of Limit this and not does effects available product material Value not EC) contain of exposure

UN Number

CEILING Predicted at 12. ground Flam. the Liq or Ecological no INHAL ID number effect = Inhalable level and, if information

Environmental hazards

H226, Asp concentration ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges are given Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction Tox. 1 in H304, sections STOT 11 and SE 3 12 H336, of this EUH066, sheet. Classification DELAYED Interactive Substances effects When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous stirring EFFECTS subject to Based exportation on the reporting information pursuant currently to Regulation available, note according EU) there 649/2012 are to no Annex known VI cases to the of delayed CLP Regulation effects following exposure to this Hazard VND REACH EC product Use None this classification hazard product 919-857-5 Regulation

Hazard categories

shower (German). see section 10 for details. with face and eye wash station. EC Workers exposed 265-149-8 to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks HAND PROTECTION CAS Hydrocarbons, related to labelling Trimethoxyvinylsilane the workers' C9-C11, 64742-47-8 pursuant health n-alkanes, to EC and Regulation safety isoalkanes,

Hazard pictograms

LD50 Crustacea

Hazard statements

Liq. 2 may form in containers (see (EU) standard 2017/776 Deutschland EN (X 14387). Flammable Atp. CLP) Forschungsgemeinschaft MAK- und BAT-Werte-Liste 2022 Ständige Senatskommission zur exposed liquid, to category fire at a 2 risk of explosion. Do not breathe combustion products. EC Ethanol LD50 (Dermal): Ethanol Flam. Liq. 3 200-578-6 Flammable liquid, category 3 Eye > 5000 Irrit. mg/kg 2 H319: Rabbit ≥ 50% If ADR 14. the / substance CAS Solubility H226 Regulation (EU) 2018/669 (XI Flammable RID, IMDG, considered LD50 in water (Oral): 64-17-5 IATA: is odourless Atp. CLP) Prüfung III or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an liquid and gesundheitsschädlicher vapour. 1000 > 5000 - 10000 mg/kg mg/l Rat Arbeitsstoffe Mitteilung 58 5.3. Advice GRC emergency, 15. Risk Acute of for Regulation (EU) 2019/521 (XII Tox. explosion wear open-circuit firefighters 4 Ελλάδα compressed air on contact with: Acute alkaline Atp. toxicity, metals,alkaline Π.Δ. breathing category 4 26/2020 apparatus (ΦΕΚ 50/Α` (in 6.3.2020) oxides,calcium hypochlorite,sulphur monofluoride,acetic compliance Εναρμόνιση with standard της ελληνικής EN 137) or νομοθεσίας external air-intake προς τις breathing διατάξεις των REACH Rapidly H304 anhydride,acids,concentrated Asp. Tox. 1 LC50 degradable Reg. (Inhalation 01-2119457610-43 vapours): May Aspiration hydrogen hazard, 01-2120767055-53 be CLP) fatal if swallowed and > enters peroxide,perchlorates,perchloric category 1 20 mg/l/4h airways. Rat acid,perchloronitrile,mercury nitrate,nitric acid,silver,silver apparatus 16. H317 Delegated (in compliance Regulation with (UE) standard 2018/1480 May cause EN (XIII οδηγιών an 138). allergic Atp. For CLP) 2017/2398/EΕ, a skin correct reaction. choice 2019/130/ΕΕ of respiratory και protection 2019/983/ΕΕ device, «για see την standard τροποποίηση EN 529. της οδηγίας ... / >> H336 May cause drowsiness or dizziness. EUH066 Repeated exposure may cause skin dryness or cracking.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P331 Do NOT induce vomiting. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P301+P310 IF SWALLOWED: immediately call a POISON CENTER or a doctor P370+P378 In case of fire: use alcohol resistant foam to extinguish. P261 Avoid breathing dust / fume / gas / mist / vapours / spray.

Contains

Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics Polydimethylsiloxane with reactive groups N-butyl-N-[(triethoxysilyl)methyl]butan-1-amine Distillates (petroleum), hydrotreated light N-(3-(trimethoxysilyl)propyl)ethylenediamine Trimethoxyvinylsilane Identification x = Conc. %

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures

2.1 Classification of the substance or mixture

decomposition of properties are not of suitably the criteria safety 1900 or data symptoms for fire, this sheet equipped. gases hazard contact 1000 and class not Use a available vapours that 9500 doctor explosion-proof and show equipment. are potentially 5000 him this document. dangerous to health may be released. Eliminate all sources of ignition (cigarettes, flames, LEGEND: In sparks, Flash case point ПДК of etc.) more from severe the leakage RUS symptoms, site. ask for immediate 23 medical 1000 ≤ T ≤ aid. 60 2000 °C SECTION Name REPRODUCTIVE Based - ADR: WEL on European the available 15. Regulatory information п Agreement TOXICITY GBR data, concerning the product 1920 the does carriage not 1000 contain DRUCKFARBEN of Dangerous substances goods listed HELLAS by in Road the SA main European lists of potential or suspected endocrine SECTION 11. Toxicological information EYES: Auto-ignition Remove, temperature if present, contact lenses if the situation not available allows you to do so easily. Wash immediately with plenty of water for at least 15 2.3. Full 6.2. minutes, disruptors - Note Decomposition ATE: Other Environmental TLV-ACGIH address for Acute hazards users: opening temperature with Toxicity environmental the precautions Estimate effects under evaluation. MEGARIDOS AVENUE eyelids fully. Get medical advice/attention. not available 1884 1000 District Does - The CAS: information not Chemical and meet Country the contained Abstract classification Service in the criteria present Number for sheet this hazard are based 19300 class on our own ASPROPYRGOS knowledge on the date of the last version. (ATTIKI) 15.1. SKIN: Users must verify the pH In the Safety, Take absence health off immediately of experimental and environmental all contaminated data for regulations/legislation the product clothing. itself, not Wash available health immediately specific hazards for and are the evaluated thoroughly substance according with or running mixture Reason to the water properties for missing (and soap of data:substance/mixture the if possible). substances Get it is 12.7. On - suitability medical The contains, CE50: Other the basis product Effective advice/attention. adverse using must the not and of thoroughness available concentration effects data, criteria penetrate Avoid specified of provided the further (required into in the contact product the sewer information to does applicable induce not a according with system contaminated contain 50% effect) regulation or come into any to PBT for clothing. each GREECE classification. contact with surface water or non-soluble or specific vPvB in use percentage of the product. ≥ than 0,1%. ground water. (in water) STOT - This INGESTION: Kinematic It Seveso CE: document is therefore Identifier - SINGLE in must Category viscosity Do necessary EXPOSURE not ESIS not (European - Directive induce be regarded to take vomiting 2012/18/EU: into account Hydrocarbons, archive as a of guarantee unless explicitly existing C9-C11, the concentration Tel. substances) 1040 on any n-alkanes, authorised mm2/s specific +30 of by the a individual product doctor. isoalkanes, 210 5519500 P5c Do hazardous property. cyclics, <2% aromatics not give anything substances Method:Converting by mouth indicated to an in unconscious section Formula 3, from to person. evaluate Dynamic Get the 6.3. medical The Threshold Information - CLP: product toxicological Methods use Regulation advice/attention. of Limit this and not does effects available product material Value not (EC) contain of exposure 1272/2008 is not subject for containment substances to the product. to our with and cleaning up direct endocrine control; Fax disrupting therefore, +30 properties users 210 must, 5519501 in concentration under their own ≥ 0.1%. Viscosity responsibility, comply with the current health & Density e-mail May - and DNEL: Type safety cause address Derived laws drowsiness of and No the Effect regulations. Country competent or dizziness Level The person TWA/8h producer is relieved from any liability STEL/15min arising from improper Remarks uses. / Observations INHALATION: Restrictions relating Remove to the victim product to fresh or contained air, away from substances the accident pursuant scene. to Annex In the XVII event to of EC respiratory Regulation Temperature: symptoms 1907/2006 25 (coughing, responsible - Provide °C EmS: Emergency appointed wheezing, for the staff Safety Schedule with Data adequate Sheet mg/m3 training on how ppm psafety@druckfarben.gr to use chemical mg/m3 products. ppm 11.1. breathing SECTION 3. 13. Composition/information Collect Dynamic Product Information the viscosity difficulty, leaked on product Disposal considerations on ingredients asthma) hazard into classes keep a suitable the as victim defined container. in a in comfortable Regulation Evaluate 83 KU position the (EC) compatibility No for 1272/2008 breathing. of the If container necessary to administer Method:ASTM be used, by oxygen. checking D 562-05 If the section subject 10. stops Absorb the STOT - GHS: breathing, remainder TLV - Globally Point REPEATED administer with inert absorbent Harmonized EXPOSURE GRC artificial 3 - respiration. System 1200 40 material. Get medical advice/attention. of classification and labeling of chemicals Temperature: 25 °C 1.4. Health 3.2. 13.1. Make - CALCULATION Solubility Metabolism, IATA Emergency Mixtures Contained Waste sure treatment DGR: - Derived the toxicokinetics, International substance telephone leakage methods METHODS no-effect number site mechanism Air FOR is well aired. of Contaminated level Transport CLASSIFICATION - DNEL Association action and not / DMEL Dangerous Goods Regulation other material available information should be disposed of in compliance with the provisions set forth in point 13. Does - Chemical Rescuer Partition IC50: not Immobilization Point protection coefficient: n-octanol/water meet and physical the classification Concentration hazards: Effects 75 criteria Product on 50% consumers for classification this hazard class not available derives from criteria established Effects by the on CLP workers Regulation, Annex I, Part 2. The data for For - evaluation IMDG: Route urgent International of inquiries of exposure chemical-physical refer Maritime to Acute Code properties for dangerous Acute are reported goods 0030-210-7793777 in section Chronic 9. Chronic Acute local Acute 6.4. Contains: Vapour Information Reuse, Reference Chronic pressure when not to possible. available other sections Chronic Product residues should be considered not available special hazardous waste. The hazard level of waste containing this product ASPIRATION - Health It Density should Regulation IMO: International is good be and/or hazards: HAZARD practice evaluated (EU) relative Product 2019/1148 for according Maritime rescuers density classification local - on lending Organization to the applicable marketing is systemic support based on calculation regulations. and to a use person 0,92 of explosives local methods as systemic who g/cm3 has been precursors exposed to a chemical Method:ISO per Annex I of CLP, Part 3, unless substance or 2811 systemic determined to a mixture to wear personal local otherwise systemic in Section - 11. INDEX: Identification protective Any Information Disposal not applicable Oral information must Identifier in Annex VI of CLP equipment. on performed personal routes The nature protection through exposure of such x an = and Conc. authorised protection disposal % waste is depends given management VND in Classification on sections the hazard SECTION 8 firm, 300 and level (EC) in 13. compliance on 2. likely 1272/2008 of the substance be Hazards with (CLP) of identification