Note: Ingredients listed on restricted chemical lists
EC/CAS
141-78-6
Name of the chemical
acetic acid, ethyl ester
Concentration
<85
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
<30
General Information
Version
1.9
Revision date
2026-07-27
Product name
TIP TOP HARDENER ER-42
1.2.1 Relevant identified uses
Hardener
supplier name
REMA TIP TOP / North America Inc
Emergency telephone
+49 - (0) 6132 - 84463, 1 800 535 5053, (001) 352 323 3500
Icons in SDS
Company Information
company name
REMA TIP TOP / North America Inc
e-mail address of the competent person responsible for the Safety Data Sheet
sds@gbk-ingelheim.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H315, H317, H319, H334, H335, H336, H351, H373
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Classification (GHS CA) Classification of the substance or mixture Classification (GHS CA) Flammable liquids, Category 2 Skin irritation, Category 2 Eye irritation, Category 2 Respiratory sensitization, Category 1 H225 Highly flammable liquid and vapor H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin sensitization, Category 1 H317 May cause an allergic skin reaction. Carcinogenicity, Category 2 H351 Suspected of causing cancer. Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation. Respiratory tract irritation Specific target organ toxicity, Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure Full text of H statements : see section 16
2.2 Label elements
GHS CA labeling
Signal word
Danger
Hazard statements
H225 - Highly flammable liquid and vapor H315 - Causes skin irritation H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements
P201 - Obtain special instructions before use. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P260 - Do not breathe vapors. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P308+P313 - IF exposed or concerned: Get medical attention, Get medical advice.
Other hazards which do not result in classification
vapors may form explosive mixture with air.
2.1 Classification of the substance or mixture
Classification (GHS CA) Flammable liquids, Category 2 H225 Highly flammable liquid and vapor. Skin irritation, Category 2 H315 Causes skin irritation. Eye irritation, Category 2 H319 Causes serious eye irritation. Respiratory sensitization, Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitization, Category 1 H317 May cause an allergic skin reaction. Carcinogenicity, Category 2 H351 Suspected of causing cancer. Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation. Respiratory tract irritation Specific target organ toxicity, Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure. Full text of H statements : see section 16