Note: Ingredients listed on restricted chemical lists
EC/CAS
141-78-6
Name of the chemical
acetic acid, ethyl ester
Concentration
<85
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
<30
General Information
Version
1.9
Revision date
2026-07-27
Product name
TIP TOP HARDENER ER-42
1.2.1 Relevant identified uses
Hardener
Manufacturer Name
REMA TIP TOP AG
Emergency telephone
+61-280735031
Icons in SDS
Company Information
company name
REMA TIP TOP AG
e-mail address of the competent person responsible for the Safety Data Sheet
info@tiptop.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H336, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Classification according to the model Work Health and Safety Regulations (WHS Regulations) Classification of the hazardous chemical
Hazard pictograms
Exclamation Health hazard mark
Signal word
Danger
Contains
Diphenylmethanediisocyanate, isomers and homologues (< 30 %); 4- isocyanatosulphonyltoluene (< 0,5 %); Aromatic polyisocyanate (< 10 %)
Hazard statements
H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements
P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a POISON CENTER, a doctor if you feel unwell. P333+P313 - If skin irritation or rash occurs: Get medical attention. P337+P313 - If eye irritation persists: Get medical attention. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER, a doctor. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Other hazards which do not result in classification
Vapours may form explosive mixture with air.
2.1 Classification of the substance or mixture
Classification according to the model Work Health and Safety Regulations (WHS Regulations) Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2A H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373