Note: Ingredients listed on restricted chemical lists
EC/CAS
205-500-4/141-78-6
Name of the chemical
acetic acid, ethyl ester
Concentration
<85
EC/CAS
618-498-9/9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
<30
General Information
Version
1.9
Revision date
2026-07-28
Product name
TIP TOP HARDENER ER-42
1.2.1 Relevant identified uses
Hardener
Manufacturer Name
REMA TIP TOP AG
Emergency telephone
+49 (0) 6132 - 84463, +353 (0) 1 809 2166
Icons in SDS
Company Information
company name
REMA TIP TOP AG
e-mail address of the competent person responsible for the Safety Data Sheet
info@tiptop.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H315, H317, H319, H334, H335, H336, H351, H373
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture
Adverse physicochemical, human health and environmental effects
Flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer May cause damage to organs through prolonged or repeated exposure. Repeated exposure may cause skin dryness or cracking
Hazard pictograms
GHS02 GHS07 GHS08
Signal word
Danger
Contains
Diphenylmethanediisocyanate, isomers and homologues; 4-isocyanatosulphonyltoluene; Aromatic polyisocyanate; Ethyl acetate
Hazard statements
H225 - Highly flammable liquid and vapour. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 - Obtain special instructions before use. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P260 - Do not breathe vapours. P280 - Wear protective gloves, protective clothing/eye protection/face protection. P308+P313 - IF exposed or concerned: Get medical advice/attention.
Supplemental label elements
EUH204 - Contains isocyanates. May produce an allergic reaction.
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
Other hazards which do not result in classification
Vapours may form explosive mixture with air. Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII. The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity – Single exposure, Category 3, H336 Narcosis Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Repeated exposure may cause skin dryness or cracking.