TIP TOP HARDENER ER-42

REMA TIP TOP AG

Revision date : 2026-07-28

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

205-500-4/141-78-6

Name of the chemical

acetic acid, ethyl ester

Concentration

<85

EC/CAS

618-498-9/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

<30

General Information

Version

1.9

Revision date

2026-07-28

Product name

TIP TOP HARDENER ER-42

1.2.1 Relevant identified uses

Hardener

Manufacturer Name

REMA TIP TOP AG

Emergency telephone

+49 (0) 6132 - 84463, +353 (0) 1 809 2166

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M011 M017 T017

Company Information

company name

REMA TIP TOP AG

e-mail address of the competent person responsible for the Safety Data Sheet

info@tiptop.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H315, H317, H319, H334, H335, H336, H351, H373

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer May cause damage to organs through prolonged or repeated exposure. Repeated exposure may cause skin dryness or cracking

Hazard pictograms

GHS02 GHS07 GHS08

Signal word

Danger

Contains

Diphenylmethanediisocyanate, isomers and homologues; 4-isocyanatosulphonyltoluene; Aromatic polyisocyanate; Ethyl acetate

Hazard statements

H225 - Highly flammable liquid and vapour. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P201 - Obtain special instructions before use. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P260 - Do not breathe vapours. P280 - Wear protective gloves, protective clothing/eye protection/face protection. P308+P313 - IF exposed or concerned: Get medical advice/attention.

Supplemental label elements

EUH204 - Contains isocyanates. May produce an allergic reaction.

Additional information

As from 24 August 2023 adequate training is required before industrial or professional use.

Other hazards which do not result in classification

Vapours may form explosive mixture with air. Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII. The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity – Single exposure, Category 3, H336 Narcosis Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Repeated exposure may cause skin dryness or cracking.

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