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SECTION 2: Hazards identification

1272/2008 Protect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to 5. Firefighting measures. 10.4. Conditions to avoid. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. preparations should be checked before use, as it can be unpredictable. Gloves' limit depends on the duration of exposure.

2.1 Classification of the substance or mixture

SKIN PROTECTION Avoid overheating, electrostatic discharge and all sources of ignition. 5.1. Extinguishing media. Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with Seveso category. None. 10.5. Incompatible materials. SUITABLE EXTINGUISHING MEDIA The extinction equipment should be of the conventional kind: carbon dioxide, soap and water after removing overalls. The product is not classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC foam, powder and nebulised water. AMMONIA: silver, lead, zinc and their salts; hydrochloric acid, nitric acid, oleum, halogens, acrolein, nitromethane and acrylic acid. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). However, since the product contains hazardous substances in RESPIRATORY PROTECTION If the threshold value for one or more of the substances present in the preparation for daily exposure in EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS POLYETHYLENGLYCOL: avoid contact with oxidising agents and concentrated inorganic acids. None. concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to EC None in particular. the workplace or to a fraction established by the company's prevention and protection service is exceeded, wear a mask with an A or universal Regulation 1907/2006 and subsequent amendments. filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141). 10.6. Hazardous decomposition products. 5.2. Special hazards arising from the substance or mixture. The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of Substances in Candidate List (Art. 59 REACH).

2.2 Label elements

In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Do not breathe technical measures limiting worker exposure. The protection provided by masks is in any case limited. None. combustion products (carbon oxide, toxic pyrolysis products, etc). AMMONIA: nitric oxides. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or This product is not subject to hazard labeling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements. when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, 1,2-PROPANEDIOL: carbon oxides. supplements. 5.3. Advice for firefighters. open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half Substances subject to authorisarion (Annex XIV REACH).

TOXICOLOGICAL INFORMATION

GENERAL INFORMATION mask or mouthpiece (ref. standard EN 138). None. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Warning symbols: None. EYE PROTECTION Warning symbols: None. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Use of protective airtight goggles (ref. standard EN 166) recommended. According to currently available data, this product has not yet produced health damages. Anyway, it must be handled carefully according to contaminated water used for extinction and the remains of the fire according to applicable regulations. Healthcare controls. Hazard sentences (R): None. good industrial practices. This product may have slight health effects on sensitive people, by inhalation and/or cutaneous absorption and/or Hazard sentences (R): None. contact with eyes and/or ingestion. Information not available. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps 9. Caution recommendations (S): None. Physical and chemical properties. around arms, legs and waist), work gloves (fireproof, cut proof and dielectric), a depressurised mask with facemask covering the whole of the 9.1. Information on basic physical and chemical properties. 15.2. Chemical safety assessment. 11.1. Information on toxicological effects. operator's face or a self-respirator (self-protector) in the event of large quantities of fume. Appearance AMMONIA liquid Safety data sheet available upon request for professional users. Colour LD50 (Oral): No chemical safety assessment has been processed for the mixture and the substances it contains. Safety data sheet available upon request for professional users. 350 mg/kg Rat Not available. 1,2-PROPANEDIOL 6. Odour Accidental release amine measures.

Further information

LD50 (Oral): 20800 mg/kg Rat 6.1. Personal precautions, protective equipment and emergency procedures. Odour threshold. Not available.

2.3 Other hazards

pH. LD50 (Dermal): 20800 mg/kg Rat 11 Text of hazard (H) indications mentioned in section 2-3 of the sheet: Melting or freezing point. Not available. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. If there are no contraindications, spray solid products

ECOLOGICAL INFORMATION

Information not available. with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there is Boiling point. Information not available. > 100 °C. Skin Corr. 1B Skin corrosion, category 1B no hazard. Do not handle damaged containers or the leaked product before donning appropriate protective gear. For information on risks for Distillation range. Specific target organ toxicity - single exposure, category 3 Not available. STOT SE 3 the environmental and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this sheet. Flash point. No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil, sewers > 100 °C.