BUFFER-RAL 555

Hazard statements (CLP)

H317, H412

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

May cause an allergic skin reaction. Harmful to aquatic life with long lasting effects

Hazard pictograms

GHS07

Signal word

Warning

Contains

A mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one [EC No 247-500-7] and 2- methyl-2H-isothiazol-3-one [EC No 220-239-6] (3:1)

Hazard statements

H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves, protective clothing, eye protection. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse.

2.3 Other hazards

No additional information available

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment — Chronic Hazard, H412 Category 3 Full text of H and EUH statements: see section 16 Adverse physicochemical, human health and environmental effects May cause an allergic skin reaction. Harmful to aquatic life with long lasting effects. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 Signal word (CLP) : Warning Contains : A mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one [EC No 247-500-7] and 2- methyl-2H-isothiazol-3-one [EC No 220-239-6] (3:1) Hazard statements (CLP) : H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects. Precautionary statements (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves, protective clothing, eye protection. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Disodic phosphate CAS-No.: 7558-79-4 ≤ 5 Eye Irrit. 2, H319 EC-No.: 231-448-7 REACH-no: 01- 2119489797-11 A mixture of: 5-chloro-2-methyl-2H-isothiazol-3- CAS-No.: 55965-84-9 ≤ 0.005 Acute Tox. 3 (Oral), H301 one [EC No 247-500-7] and 2-methyl-2H- EC Index-No.: 613-167- Acute Tox. 3 (Dermal), H311 isothiazol-3-one [EC No 220-239-6] (3:1) 00-5 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1, H314 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=100) Aquatic Chronic 1, H410 (M=100) Specific concentration limits: Name Product identifier Specific concentration limits A mixture of: 5-chloro-2-methyl-2H-isothiazol-3- CAS-No.: 55965-84-9 ( 0.0015 ≤C ≤ 100) Skin Sens. 1A, H317 one [EC No 247-500-7] and 2-methyl-2H- EC Index-No.: 613-167- ( 0.06 ≤C < 0.6) Eye Irrit. 2, H319 isothiazol-3-one [EC No 220-239-6] (3:1) 00-5 ( 0.06 ≤C < 0.6) Skin Irrit. 2, H315 ( 0.6 ≤C ≤ 100) Eye Dam. 1, H318 ( 0.6 ≤C ≤ 100) Skin Corr. 1C, H314 Full text of H and EUH statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse eyes with water as a precaution. First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact : May cause an allergic skin reaction. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case : Toxic fumes may be released.