Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
25-50%
General Information
Revision date
2024-10-02
Product name
- Iso
1.2.1 Relevant identified uses
only outdoors
Manufacturer Name
Rainbow Technology Corporation
Emergency telephone
1-800-255-3924
Icons in SDS
Company Information
company name
Rainbow Technology Corporation
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H319
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
of the substance or mixture GHSO7 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation.
2.2 Label elements
elements The vroduct is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHSO7 Signal word Warning
Hazard statements
Causes skin irritation. Causes serious eye irritation.
Precautionary statements
Wear protective gloves. Wear eye protection / face protection. Wash thoroughly after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this lapel). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with volenty of water. Take off contaminated clothing and wash it pefore reuse. protective equipment and emergency procedures Wear protective equioment. Keep unprotected versons away. Ensure adequate ventilation Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of contaminated material as waste in accordance with federal state and local regulations. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and for safe handling Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Wash thoroughly after handling. Information about protection against explosions and fires: No special measures required. Conditions for safe
Classifications
system
NFPA Ratings
(scale 0 - 4) 1 0 Health = 1 Fire = 1 Reactivity = 0
HMIS® ratings
(scale 0 - 4) HEALTH FIRE PHYSICAL HAZARD |0| HEALTH FIRE
Physical hazards
J 0 Health = 1 Fire = 1 = 0
2.3 Other hazards
Results of
PBT Substances
and vPvB assessment Not applicable. and vPvB assessment Not applicable. Persistent, Bioaccumulative and Toxic
vPvB Substances
Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture Hazardous components: 102-60-3 1,1',1'',1'''-ethylenedinitrilotetrapropan-2-ol 5-20% 280-57-9 Triethylenediamine £ 2.5% 556-67-2 octamethylcyclotetrasiloxane £ 0.5% 4 First-aid measures Description of first aid measures After inhalation: Overexposure, remove to fresh air and seek medical attention. After skin contact: Immediately wash with water and soap and rinse thoroughly. If sxin becomes irritated seek medical attention. After eye contact: Rinse ovened eye for 20 minutes under running water. If eye pecomes irritated, obtain medical treatment. After swallowing: Rinse out mouth with water. Drinx 1 - 2 glasses of water but DO NOT induce vomiting. Do not give liquids to a drowsy, convulsing or unconscious person. If vomiting occurs spontaneously, xeeo head below hips to vrevent aspiration. Seek medical treatment. Information for doctor: Most important symotoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No Not applicaple. very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety
Further information
relevant available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards arising from the substance or mixture No relevant available. Trade name: Ez-Pak Poly Advice for firefighters Protective equipment: Protective clothing and respiratory protective device. 6 Accidental release measures Personal about relevant available. 8 Exposure controls/personal protection No further relevant information available. 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possipility of hazardous reactions No dangerous reactions xnown. Conditions to avoid Moisture Exposure to high temperatures. Incompatible materials: Strong oxidizers, acids, and bases. reacts with nitrates. Reacts with alcohols. Hazardous decomposition products: Carbon monoxide and carbon dioxide Nitrogen oxides * 11 relevant available. Persistence and degradapility No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Although the information and recommendations set forth in this SDS are presented in good faith and are believed to be correct as of Revision of this SDS, Canbond Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it will maxe their own determination as to the suitability for their purwvose prior to use. In no event will Canbond Inc. or any affiliate thereof pe responsible for damages of any nature whatsoever resulting from the use or reliance on the information set forth in the SDS. Department issuing SDS: Environment protection department. Creation Date 11/28/2022 Revision of prevaration / last Revision 09/28/2024 / - Aboreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Devartment of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Supostances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA)
Storage
Handling: including any incompatibilities Requirements to be met by storerooms and receptacles: Store in a cool location away from direct heat. Information about in one common facility: Store away from oxidizing agents. conditions: Protect from humidity and water. Keer receptacle tightly sealed. Specific end use(s) No
Additional information
about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workvolace: 556-67-2 octamethylcyclotetrasiloxane WEEL Long-term value: 10* ppm *OARS WEEL The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment (see listings below) General worotective and hygienic measures: Wash hands before breaxs and at the end of work. Breathing equivment: Not necessary if room is well-ventilated. Protection of hands: Protective gloves The glove material has to be imeermeabdle and resistant to the product/ the substance/ the preparation. Material of gloves Nitrile rubber, NBR The selection of the suitable gloves does not only depend on the material, out also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact preak through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Safety glasses with side shields. Body vrotection: Protective work clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Apvearance: Form: Liquid Color: Beige Odor: Characteristic Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point: Undetermined. Boiling point: Flash point: > 93 °C (> 199 °F) Flammaoility (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. ‘ Auto igniting: Product is not selfigniting. Danger of explosion: Product does not vresent an explosion hazard. Vapor pressure: Not determined. Specific gravity at 20 °C (68 °F): 0.96 g/cmN (8.011 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Slightly soluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent toxicological Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 ecological General notes: At present there are no ecotoxicological assessments. Results of
Contains
Organic solvents: 0.0 % Solids not available
TOXICOLOGICAL INFORMATION
‘ Information on toxicological effects Acute toxicity: Primary irritant effect: on the sxin: Sxin irritant. on the eye: Irritating effect. Sensitization: No sensitizing effects known.
ECOLOGICAL INFORMATION
Toxicity Aquatic toxicity: No
Other hazards
No further relevant information available. 13
Disposal
considerations Waste treatment methods Recommendation: Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information
UN Number
DOT, ADR, ADN, IMDG, IATA not regulated UN proper shipving name DOT, ADR, ADN, IMDG, IATA not regulated Transvort
SECTION 2: Hazards identification
class(es DOT, ADR, ADN, IMDG, IATA Class not regulated Packing group DOT, ADR, IMDG, IATA not regulated
Environmental hazards
Not applicaple. Special vrecautions for user Not applicable. Transvort in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation": not regulated 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely
Hazardous Ingredients
None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements. Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. (DSL) Canada Dosmestic Substance List All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL requirements. New Jersey Right-to-Know List: None of the ingredients is listed. New Jersey Special Hazardous Substance List: None of the ingredients is listed. Pennsylvania Right-to-Know List: 8001-22-7 soybean oil Pennsylvania Special Hazardous Substance List: None of the ingredients is listed. Cancerogenity categories EPA (Environmental Protection Agency} None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients listed. MAK (German Maximum Worxplace Concentration) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. National regulations: Water
Hazard categories
Water 1 (Self-assessment): slightly hazardous for water. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 2 Eye Irrit. 2A: Serious eye damage/eye irritation, 2A