Propylene oxide

Hazard statements (CLP)

H224, H302, H312, H315, H319, H332, H335, H340, H350, H402

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

2.1.1 Classification according to Regulation (EC) No 1272/2008 (CLP/GHS) Classification of the substance or mixture Classification and labeling in Annex of Directive 67/548/EEC Endpoints Classification Reason for no classification Explosiveness conclusive but not sufficient for classification Oxidizing properties conclusive but not sufficient for classification Flammability F+; R12 Thermal stability conclusive but not sufficient for classification Acute toxicity Xn; R20/21/22 Acute toxicity- irreversible damage after single conclusive but not sufficient for classification exposure Repeated dose toxicity conclusive but not sufficient for classification Irritation / Corrosion Xi: R36/37/38 Sensitization conclusive but not sufficient for classification Carcinogenicity Carcinogen Category 2; R45 conclusive but not sufficient for classification Mutagenicity - Genetic Mutagen Category2 ; R46 conclusive but not sufficient for classification Toxicity Toxicity to reproduction fertility conclusive but not sufficient for classification Toxicity to reproduction conclusive but not sufficient for classification development Toxicity to reproduction - conclusive but not sufficient for classification breastfed babies

Environmental hazards

conclusive but not sufficient for classification conclusive but not sufficient for classification Acute Aquatic Hazard 3

Hazard statements

F+ - extremely flammable T H224: Extremely flammable liquids and gases H302: Harmful if swallowed H312: Harmful in contact with skin H315: Causes skin irritation H319: causes serious eye irritation H332: Harmful if inhaled H335: May cause respiratory irritation H340: May cause genetic defects via the intraperintoneal route only H350: May cause cancer H224: Extremely flammable liquid and vapor H302: Harmful if swallowed H312: Harmful in contact with skin H319: Causes serious eye irritation H332: Harmful if inhaled H335: May cause respiratory irritation H340: May cause genetic defects via the intraperitoneal route only H350: May cause cancer H402: Harmful to aquatic life

R-phrase(s)

R12 Extremely flammable R20/21/22 harmful by inhalation, in contact with skin and if swallowed R36/37/38 irritating to eyes, respiratory system and skin R45 may cause cancer R46 may cause heritable genetic damage

S-phrase(s)

S45 in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S54 S53 - avoid exposure - obtain special instructions before use

2.1 Classification of the substance or mixture

2.2.1 Classification and labeling in Annex of Directive 67/548/EEC: Endpoints Classification Reason for no classification Explosiveness conclusive but not sufficient for classification Oxidizing properties conclusive but not sufficient for classification Flammability F+; R12 Thermal stability conclusive but not sufficient for classification Acute toxicity Xn; R20/21/22 Acute toxicity- irreversible damage after single conclusive but not sufficient for classification exposure Repeated dose toxicity conclusive but not sufficient for classification Irritation / Corrosion Xi: R36/37/38 Sensitization conclusive but not sufficient for classification Carcinogenicity Carcinogen Category 2; R45 conclusive but not sufficient for classification Mutagenicity - Genetic Mutagen Category2 ; R46 conclusive but not sufficient for classification Toxicity Toxicity to reproduction fertility conclusive but not sufficient for classification Toxicity to reproduction conclusive but not sufficient for classification development Toxicity to reproduction - conclusive but not sufficient for classification breastfed babies Environment conclusive but not sufficient for classification

Signal word

Danger Danger

Precautionary statements

P201: Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/... / equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge P201: Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/... / equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P273: Avoid release to the environment P501: Dispose of contents/container in accordance with local/regional/national/international regulations (to be specified). Sensitivity This content has been classified as Petro Rabigh General Use

EU Classification

Globally Harmonized System of Classification and Labelling of Chemicals [UN- /GHS] Endpoints Reason for no classification Explosiveness conclusive but not sufficient for classification Oxidising properties conclusive but not sufficient for classification Flammability Flammable Liquid 1 Thermal stability conclusive but not sufficient for classification Acute toxicity Acute Toxicity 4 Acute toxicity- irreversible damage after single STOT SE 3 Sensitivity: This content exposure has been classified as Petro Rabigh: General Use classification is not warranted based on expert judgment of several Aspiration physicochemical properties Repeated dose toxicity Irritation / Corrosion Eye Irritation 2 Sensitization conclusive but not sufficient for classification Carcinogenicity Carcinogen 1B Mutagenicity - Genetic Mutagen 1B Toxicity Toxicity to reproduction fertility conclusive but not sufficient for classification Toxicity to reproduction conclusive but not sufficient for classification development Toxicity to reproduction - conclusive but not sufficient for classification breastfed babies

2.3 Other hazards

Substance meets the criteria for PBT or vPvB according to Regulation Not applicable.

Other hazards which do not result in classification

Not applicable.