Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
30-50 ≥5%
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10-30 4.01-2119457014- ≥5% ≥5%
EC/CAS
219-799-4/2536-05-2
Name of the chemical
2,2’-Methylenediphenyl diisocyanate
Concentration
<1 ≥5% ≥5%
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
<1 ≥5%
EC/CAS
200-866-1/75-37-6
Name of the chemical
1,1-Difluoroethane
Concentration
5-20
EC/CAS
231-783-9/7727-37-9
Name of the chemical
Nitrogen N2
Concentration
5-20
General Information
Version
2.2
Revision date
2022-06-30
Product name
TECRON - LOW TEMP PU INSULATION ADHESIVE, GREEN, CANISTER
Product name
TECRON - LOW TEMP PU INSULATION ADHESIVE, GREEN, CANISTER
Identification on the label/Trade name
CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. (contains 1,1-difluoroethane)
Product Synonyms
Not Available
Chemical name
Not Applicable
1.2.1 Relevant identified uses
SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites
Emergency telephone
+353 1 443 4289, +61 3 9573 3188
Icons in SDS
Company Information
company name
QUIN GLOBAL (BV) LTD
e-mail address of the competent person responsible for the Safety Data Sheet
technicalhelp.uk@quinglobal.com, sales@tecron.ie
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H222+H229, H315, H317, H319, H334, H335, H351, H373
Section 2
SECTION 2: Hazards identification
No 1272/2008 Classification of the substance or mixture
Signal word
Danger
Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H351 H222+H229 Suspected of causing cancer. Extremely flammable aerosol. Pressurized container: may burst if heated.
Supplemental label elements
EUH204 Contains isocyanates. May produce an allergic reaction.
Prevention
P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe gas. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace.
Response
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.
Storage
P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Continued... P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
2.1 Classification of the substance or mixture
H334 - Sensitisation (Respiratory) Category 1, H373 - Specific Target Organ Toxicity - Repeated Exposure Category 2, H335 - Specific Target regulation (EC) No 1272/2008 Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H315 - Skin Corrosion/Irritation Category 2, H319 - Serious Eye [CLP] and amendments [1] Damage/Eye Irritation Category 2, H317 - Sensitisation (Skin) Category 1, H351 - Carcinogenicity Category 2, H222+H229 - Aerosols Category 1 Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI 2.2. Label elements Hazard pictogram(s) Signal word Danger Hazard statement(s) H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H222+H229 Extremely flammable aerosol. Pressurized container: may burst if heated. Supplementary statement(s) EUH204 Contains isocyanates. May produce an allergic reaction. Precautionary statement(s) Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe gas. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Continued... P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. 2.3. Other hazards Cumulative effects may result following exposure*. Repeated exposure potentially causes skin dryness and cracking*. Vapours potentially cause drowsiness and dizziness*. 4,4'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate (MDI) 2,2'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate 2,4'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate Not Applicable SECTION 3 Composition / information on ingredients 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1.CAS No Nanoform 2.EC No Classification according to regulation (EC) No %[weight] Name 3.Index No SCL / M-Factor Particle 1272/2008 [CLP] and amendments Characteristics 4.REACH No Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2, Sensitisation (Skin) 1.9016-87-9 Category 1, Sensitisation (Respiratory) Category 1, 2.Not Available Carcinogenicity Category 2, Specific Target Organ 30-50 MDI oligomer 3.Not Available Not Available Toxicity - Single Exposure (Respiratory Tract Irritation) 4.Not Available Category 3 , Specific Target Organ Toxicity - Repeated Exposure Category 2; H315, H319, H317, H334, H351, H335, H373, EUH204 [1] Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Serious Eye Eye Irrit. 2; H319: Damage/Eye Irritation Category 2, Sensitisation (Skin) C ≥ 5 % | Skin Irrit. 1.101-68-8 Category 1, Sensitisation (Respiratory) Category 1, 2; H315: C ≥ 5 % | 2.202-966-0|406-550-1 10-30 4,4'-diphenylmethane Carcinogenicity Category 2, Specific Target Organ Resp. Sens. 1; Not Available 3.615-005-00-9 diisocyanate (MDI) Toxicity - Single Exposure (Respiratory Tract Irritation) 4.01- 2119457014-47-0000 H334: C ≥ 0,1 % | Category 3 , Specific Target Organ Toxicity - Repeated STOT SE 3; H335: Exposure Category 2; H332, H315, H319, H317, H334, C ≥ 5 % H351, H335, H373 [2] Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Serious Eye Eye Irrit. 2; H319: Damage/Eye Irritation Category 2, Sensitisation (Skin) C ≥ 5 % | Skin Irrit.