TECRON - LOW TEMP PU INSULATION ADHESIVE, GREEN, CANISTER

QUIN GLOBAL (BV) LTD

Revision date : 2022-06-30

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

30-50 ≥5%

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

10-30 4.01-2119457014- ≥5% ≥5%

EC/CAS

219-799-4/2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

<1 ≥5% ≥5%

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

<1 ≥5%

EC/CAS

200-866-1/75-37-6

Name of the chemical

1,1-Difluoroethane

Concentration

5-20

EC/CAS

231-783-9/7727-37-9

Name of the chemical

Nitrogen N2

Concentration

5-20

General Information

Version

2.2

Revision date

2022-06-30

Product name

TECRON - LOW TEMP PU INSULATION ADHESIVE, GREEN, CANISTER

Product name

TECRON - LOW TEMP PU INSULATION ADHESIVE, GREEN, CANISTER

Identification on the label/Trade name

CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. (contains 1,1-difluoroethane)

Product Synonyms

Not Available

Chemical name

Not Applicable

1.2.1 Relevant identified uses

SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites

Emergency telephone

+353 1 443 4289, +61 3 9573 3188

Icons in SDS

GHS02 GHS07 GHS08 M004 M008 M009 M010 M017 T013

Company Information

company name

QUIN GLOBAL (BV) LTD

e-mail address of the competent person responsible for the Safety Data Sheet

technicalhelp.uk@quinglobal.com, sales@tecron.ie

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H222+H229, H315, H317, H319, H334, H335, H351, H373

Section 2

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H351 H222+H229 Suspected of causing cancer. Extremely flammable aerosol. Pressurized container: may burst if heated.

Supplemental label elements

EUH204 Contains isocyanates. May produce an allergic reaction.

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe gas. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace.

Response

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.

Storage

P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Continued... P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

2.1 Classification of the substance or mixture

H334 - Sensitisation (Respiratory) Category 1, H373 - Specific Target Organ Toxicity - Repeated Exposure Category 2, H335 - Specific Target regulation (EC) No 1272/2008 Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H315 - Skin Corrosion/Irritation Category 2, H319 - Serious Eye [CLP] and amendments [1] Damage/Eye Irritation Category 2, H317 - Sensitisation (Skin) Category 1, H351 - Carcinogenicity Category 2, H222+H229 - Aerosols Category 1 Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI 2.2. Label elements Hazard pictogram(s) Signal word Danger Hazard statement(s) H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H222+H229 Extremely flammable aerosol. Pressurized container: may burst if heated. Supplementary statement(s) EUH204 Contains isocyanates. May produce an allergic reaction. Precautionary statement(s) Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe gas. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Continued... P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. 2.3. Other hazards Cumulative effects may result following exposure*. Repeated exposure potentially causes skin dryness and cracking*. Vapours potentially cause drowsiness and dizziness*. 4,4'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate (MDI) 2,2'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate 2,4'-diphenylmethane Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply) diisocyanate Not Applicable SECTION 3 Composition / information on ingredients 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1.CAS No Nanoform 2.EC No Classification according to regulation (EC) No %[weight] Name 3.Index No SCL / M-Factor Particle 1272/2008 [CLP] and amendments Characteristics 4.REACH No Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2, Sensitisation (Skin) 1.9016-87-9 Category 1, Sensitisation (Respiratory) Category 1, 2.Not Available Carcinogenicity Category 2, Specific Target Organ 30-50 MDI oligomer 3.Not Available Not Available Toxicity - Single Exposure (Respiratory Tract Irritation) 4.Not Available Category 3 , Specific Target Organ Toxicity - Repeated Exposure Category 2; H315, H319, H317, H334, H351, H335, H373, EUH204 [1] Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Serious Eye Eye Irrit. 2; H319: Damage/Eye Irritation Category 2, Sensitisation (Skin) C ≥ 5 % | Skin Irrit. 1.101-68-8 Category 1, Sensitisation (Respiratory) Category 1, 2; H315: C ≥ 5 % | 2.202-966-0|406-550-1 10-30 4,4'-diphenylmethane Carcinogenicity Category 2, Specific Target Organ Resp. Sens. 1; Not Available 3.615-005-00-9 diisocyanate (MDI) Toxicity - Single Exposure (Respiratory Tract Irritation) 4.01- 2119457014-47-0000 H334: C ≥ 0,1 % | Category 3 , Specific Target Organ Toxicity - Repeated STOT SE 3; H335: Exposure Category 2; H332, H315, H319, H317, H334, C ≥ 5 % H351, H335, H373 [2] Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Serious Eye Eye Irrit. 2; H319: Damage/Eye Irritation Category 2, Sensitisation (Skin) C ≥ 5 % | Skin Irrit.

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