Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2017-08-10
Product name
PRECIDIUM MTI 2200 ISO
Manufacturer Name
Quantum Technical Services Ltd.
Icons in SDS
Company Information
company name
Quantum Technical Services Ltd.
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H304, H312+H332, H315+H318, H317, H334, H335, H351, H360FD, H372
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
OSHA Regulatory Status: This material is considered hazardous by the OSHA Hazard Communication Standard (CFR 1910.1200) WHMIS B2 Flammable Liquid D-2A Materials causing other toxic effects – (very toxic) D-2B Material causing other toxic effects (toxic) Flammable Liquids – Category 3 Acute Toxicity: Inhalation – Category 4 Acute Toxicity (Dermal) – Category 4 Skin Corrosion/Irritation – Category 2 Serious Eye Damage/Eye Irritation – Category 2A Specific Target Organ Toxicity (single exposure) [Respiratory Tract Irritation] – Category 3 Specific Target Organ Toxicity (repeated exposure) [Liver, Kidney, Central Nervous System] – Category 2 Specific Target Organ Toxicity (repeated exposure) [Oral] – Category 2
Aspiration hazard
Category 1 Respiratory Sensitization – Category 1 Skin Sensitization – Category 1 Carcinogenicity - Category 2 Reproductive Toxicity - Category 1B
Hazard pictograms
2
Signal word
DANGER
Hazard statements
H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H312+H332: Harmful in contact with skin or if inhaled. H315+H318: Causes skin irritation. Causes serious eye damage. H317: May cause an allergic skin reaction. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H372 Causes damage to organs (lungs) through prolonged or repeated exposure. R42/43: May cause sensitization by inhalation and skin contact. R68/20 Harmful possible risk of irreversible effects through inhalation H360FD: May damage fertility. May damage the unborn child. H351: Suspected of causing cancer.
Precautionary statements
P202: Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No Smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion proof electrical/ventilating/lighting equipment. P242 Use only non-sparking tools. P243 Take action to prevent static discharges. P262: Do not get in eyes, on skin, or on clothing. P281: Use personal protective equipment as required. P264: Wash exposed skin thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P260: Do not breathe dust/fumes/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P285: In case of inadequate ventilation wear respiratory protection.
Response
P301+P310 IF SWALLOWED Immediately call a POISON CENTER/Doctor P303+P361+P353 IF ON SKIN (or Hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P333+P313 If skin irritation or rash occurs Get medical advice/attention P361+P364: Take off immediately all contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do so. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P304+P340+P312 IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P314: Get medical advice/attention if you feel unwell. P331: Do NOT induce vomiting. P370+P378: In case of fire use dry sand, dry chemical, or alcohol resistant foam to extinguish.
Storage
P403: Store in a well-ventilated place. P233: Keep container tightly closed. P235: Keep cool. P405: Store locked up.
Disposal
P501: Dispose of contents/containers in accordance with local /regional/national/ international regulations. 3