I&I Guard -SCF 200

Hazard statements (CLP)

H301, H302, H303, H315, H317, H318, H319, H330, H334, H336, H351, H402, H412

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

GHS Classification Acute toxicity, Oral Acute toxicity, Oral Acute toxicity, Oral Skin corrosion/irritation Respiratory or skin sensitization Skin Serious Eye Damage/Eye Irritation Serious Eye Damage/Eye Irritation Acute toxicity Inhalation Respiratory or skin sensitization Respiratory Specific target organ toxicity Single exposure, 3 Carcinogenicity Hazards to the aquatic environment Acute, 3 Hazards to the aquatic environment Chronic, 3

Signal word

• Danger

Hazard statements

H301 • Toxic if swallowed H302 • Harmful if swallowed H303 • May be harmful if swallowed H315 • Causes skin irritation 2 . HAZARDS IDENTIFICATION (CONTINUED) H317 • May cause an allergic skin reaction H318 • Causes serious eye damage H319 • Causes serious eye irritation H330 • Fatal if inhaled H334 • May cause allergy or asthma symptoms or breathing difficulties if inhaled H336 • May cause drowsiness or dizziness H351 • Suspected of causing cancer. H402 • Harmful to aquatic life H412 • Harmful to aquatic life with long lasting effects P201 • Obtain special instructions before use. P202 • Do not handle until all safety precautions have been read and understood. P260 • Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 • Wash skin thoroughly after handling. P270 • Do not eat, drink or smoke when using this product. P271 • Use only outdoors or in a well-ventilated area. P272 • Contaminated work clothing should not be allowed out of the workplace. P273 • Avoid release to the environment. P280 • Wear protective gloves/ eye protection/ face protection. P284 • Wear respiratory protection. P301 + P310 • IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P302 + P352 • IF ON SKIN: Wash with plenty of soap and water. P304 + P340 • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present • and easy to do. Continue rinsing. P310 • Immediately call a POISON CENTER or doctor/ physician. P320 • Specific treatment is urgent (see supplemental first aid instructions on this label). P330 • Rinse mouth. P333 + P313 • If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 • If eye irritation persists: Get medical advice/ attention. 2 2 . HAZARDS IDENTIFICATION (CONTINUED) P362 • Take off contaminated clothing and wash before reuse. P403 + P233 • Store in a well-ventilated place. Keep container tightly closed. P405 • Store locked up. P501 • Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

or not Covered by GHS

Principle Routes of Exposure

Eyes; Ingestion; Inhalation; Skin Target Organs Respiratory system; Skin; Eyes Inhalation At room temperature, MDI vapors are minimal due to low vapor pressure. However, heating, spraying, foaming, or otherwise mechanically dispersing (drumming, venting or pumping) operations may generate vapor or aerosol concentrations sufficient to cause irritation or other adverse effects. Excessive exposure may cause irritation of the eyes, upper respiratory tract and lungs. Severe overexposure may lead to pulmonary edema. May cause respiratory sensitization with asthma- like symptoms in susceptible individuals. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Symptoms may include coughing, dryness of throat, headache, nausea, difficult breathing and a feeling of tightness in the chest. Effects may be delayed. Impaired lung function (decreased ventilator capacity) has been associated with overexposure to isocyanates Chronic: As a result of previous repeated overexposures or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma) or tissue injury in the upper respiratory tract. Animal tests indicate skin contact alone may also lead to allergic respiratory reaction. These effects may be permanent. Any person developing asthmatic reaction or other sensitization should be removed from further exposure. Skin Contact No irritation is likely to develop following short contact periods with skin. Prolonged or repeated exposure can cause skin irritation, reddening, dermatitis, and in some individuals, sensitization. Skin contact may result in allergic skin reactions or respiratory sensitization, but is not expected to result in absorption of amounts sufficient to cause other adverse effects. May stain skin. Eye Contact As a liquid or dust, may cause irritation, inflammation, and/or damage to sensitive eye tissue. Symptoms include watering or discomfort of the eyes. Corneal injury is unlikely. Ingestion Single dose oral toxicity is considered to be extremely low. Can result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. Ingestion is not an applicable route of entry for intended use. 3

2.1 Classification of the substance or mixture

Acute toxicity, • 3 Oral Acute toxicity, • 4 Oral Acute toxicity, • 5 Oral Skin corrosion/irritation • 2 Respiratory or skin sensitization • 1 Skin Serious Eye Damage/Eye Irritation • 1 Serious Eye Damage/Eye Irritation • 2 A Acute toxicity • 1 Inhalation Respiratory or skin sensitization • 1 Respiratory Specific target organ toxicity • Single exposure, 3 Carcinogenicity • 2 Hazards to the aquatic environment • Acute, 3 Hazards to the aquatic environment • Chronic, 3