Pyrotek Coating 3321

SECTION 2: Hazards identification

OSHA Not a dangerous substance or mixture according to the Globally Harmonized System (GHS) Acute toxicity - Inhalation (Dusts/Mists) Category 4 Respiratory sensitization Category 1B

2.2 Label elements

Warning

Contains

Titanium Dioxide, Calcined Clays.

Hazard statements

May be harmful if inhaled May cause respiratory irritation

Prevention

Wash hands thoroughly after handling Wear protective gloves Wear eye/face protection IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Collect spillage

2.3 Other hazards

None known

Further information

Ale Class Ssifi¢ationsu Water 7732- 18-5 Kaolinite, Hydrous Aluminum 1332-58-7 1334 Silicate Titanium dioxide 13463-67-7 The exact percentage (concentration) of composition is not shown due to component range variations, withheld or trade secret ingredients. Skin Contact Wash off with soap and water. Remove and wash contaminated clothing before re-use. If symptoms persist, call a physician. If skin irritation persists, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Inhalation Remove to fresh air. If symptoms persist, call a physician. Ingestion Drink 1 or 2 glasses of waiter. If symptoms persist, call a physician. Notes to Physician Treat symptomatically. Flammable properties Not flammable. Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding fire. Unsuitable Extinguishing Media None known. Specific hazards arising from the chemical No information available. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ma] ent cc dental ‘Release Measu Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Dam up. Soak up with inert absorbent material. Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Conditions for safe storage, including any incompatibilities Keep tightly closed in a dry and cool place. Do not freeze. Do not re-use empty containers. Store in original container. Keep in properly labelled containers. Do not store in reactive metal containers. Storage between 39-90 °F (4-32 °C). Materials to avoid Acids. Control parameters Chemical name ACGIH TLV VOC Content (%) Not applicable [2 0. Stability Reactivity Chemical stability Stable. Possibility of Hazardous Reactions Hazardous polymerization does not occur. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible materials Acids. Hazardous Decomposition Products None known. Information on likely routes of exposure Eye Contact Contact with eyes may cause irritation. Skin Contact Substance may cause slight skin irritation. Ingestion Not a normal route of exposure. Ingestion may cause gastrointestinal irritation. Inhalation May cause irritation of respiratory tract. Information on toxicological effects Delayed and immediate effects as well as chronic effects from short and long-term exposure Mutagenic effects None known.

Appearance/Odor

Coating Slight Color Grey Odor threshold Not applicable Property Values

Remarks

+ Methods pH 10.5-11.5 Melting point / freezing point Not applicable Boiling point / boiling range 100 °C / 212 Flash point Not flammable None known Evaporation rate Flammability Limit in Air Upper flammability limit: Not applicable Lower flammability limit: Not applicable Vapor pressure Not applicable Vapor density No information available Specific gravity 1.30 - 1.32 Water solubility Soluble in water Solubility(ies) Not applicable Partition coefficient Autoignition temperature Not applicable Decomposition temperature No data available Kinematic viscosity Dynamic viscosity Explosive properties Non explosive

Medical Conditions Generally Aggravated by Exposure

Respiratory disorder. STOT - single exposure None known. STOT - repeated exposure None known. Chronic Toxicity None known Numerical measures of toxicity Product Information Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Water > 90 mL/kg (Rat) - Kaolinite, Hydrous Aluminum > 5 g/kg (Rat) > 5000 mg/kg ( Rat ) - Silicate Dermal LD50 Titanium dioxide > 10000 mg/kg _( Rat) - > 6820 mg/m? Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen: Chemical name IARC NTP OSHA Mexico Water Not Listed Kaolinite, Hydrous Aluminum Not Listed A4 - Not classifiable as a Silicate human carcinogen Titanium dioxide Group 2B Not Listed Present A4 - Not classifiable as a human carcinogen Chemical name Argentina Chile Venezuela Water Not Listed Kaolinite, Hydrous Aluminum Silicate Not Listed Present Titanium dioxide Not Listed Present IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Ecotoxicity Component Algae/aquatic plants Fish Toxicity to Crustacea microorganisms Water No data available 7732-18-5 (45 - 55 % ) Kaolinite, Hydrous Aluminum No data available Silicate 1332-58-7 (10-20 %) Titanium dioxide No data available 13463-67-7 (10 - 20 %) Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media No information available. Ozone depletion potential (ODP) Not applicable. sposal Consideration Waste disposal methods Dispose of in accordance with federal, state and local regulations. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. DOT Not regulated International Inventories Chemical name TSCA EINECS | ELINCS DSL NDSL PICCS ENCS China AICS KECL Water x Xx - xX - x - x Xx Kaolinite, Hydrous xX X - Xx - x - x Xx xX Aluminum Silicate Titanium dioxide xX - xX - x X x Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances USA Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product may contain a chemical or chemicals, if listed below, which are subject to the reporting requirements of the Act and Title 40n of the Code of Federal Regulations, Part 372: SARA 311/312 Hazardous Categorization Chemical name CERCLA/SARA 302 TPQ OSHA PRINT THRESHOLD Titanium dioxide (CAS #: 13463-67-7) 0.1 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical name California Prop. 65 Type Water (CAS #: 7732-18-5) Not Listed - Kaolinite, Hydrous Aluminum Silicate (CAS #: 1332-58-7) Not Listed - Titanium dioxide (CAS #: 13463-67-7) Carcinogen - State Right-to-Know CANADA Chemical name WHMIS Water (CAS #: 7732-18-5) Uncontrolled product according to WHMIS classification criteria Kaolinite, Hydrous Aluminum D2A Silicate (CAS #: 1332-58-7) Titanium dioxide (CAS #: D2A (In certain cases, this classification does not apply. For more information, consult 13463-67-7) the section Substance Specific Issues - Titanium dioxide, mixture containing on Health Canada's WHMIS Division website.) 16.