Note: Ingredients listed on restricted chemical lists
General Information
Revision date
2013-11-11
Product name
CLEANFORCE DELIMER
CAS No.
7664-38-2
supplier name
Puritan Services Inc
Icons in SDS
Company Information
company name
Puritan Services Inc
Section 2
Appearance/Odor
clear, colorless liquid; nonobjectionable odor *pH (concentrate) = 9 – 10.0 *pH (diluted 1:20) = 9 – 10 SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flash point: none (T.C.C.) Flammable Limits: LEL = N/A UEL = N/A Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical. Special Fire Fighting Procedures: Self-contained positive pressure breathing apparatus and protective clothing should be worn in fighting fires involving chemicals. Unusual Fire and Explosion Hazards: N/A SECTION V -- PHYSICAL HAZARDS Stability: Stable Conditions to Avoid: N/A Incompatibility (Materials to Avoid): Avoid strong oxidizing agents or strong mineral acids. Hazardous Decomposition Products or Byproducts Decomposition products under fire conditions fumes of ammonia, carbon monoxide, carbon dioxide, oxides of nitrogen and various hydrocarbons. Hazardous Polymerization: Will not occur Conditions to Avoid: N/A SECTION VI -- HEALTH HAZARD DATA red liquid; floral odor pH of concentrate: 12.4 -13.4 SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flash point: None to boiling (T.C.C.) Flammable Limits: LEL = N/A UEL = N/A Extinguishing Media: Water, dry chemical, carbon dioxide, foam Special Fire Fighting Procedures: Wear MSHA/NIOSH approved self-contained breathing apparatus. Cool fire-exposed containers with water spray. Unusual Fire and Explosion Hazards: Products of combustion are toxic. SECTION V -- PHYSICAL HAZARDS Stability: Stable Conditions to Avoid: Do not mix with anionic cleaners. Incompatibility (Materials to Avoid): Oxidizing materials Hazardous Decomposition Products or Byproducts: Carbon dioxide, carbon monoxide, ammonia, nitrous oxides, hydrogen chloride Hazardous Polymerization: Will not occur Conditions to Avoid: none known SECTION VI -- HEALTH HAZARD DATA
Principle Routes of Exposure
Inhalation? No Skin? No Ingestion? No Inhalation? Yes Skin? yes Eye? Yes Ingestion? Yes Inhalation? yes Skin? yes Ingestion? yes
Health hazards
1. Acute and 2. Chronic) 1. Not a primary skin irritant per Federal Hazardous Substance Act. Prolonged contact with skin may cause slight irritation. Prolonged contact with eye may produce irritation. Concentrate not acute oral toxicity at 5 g/kg. 2. None known to Hillyard. Chemical listed as Carcinogen or Potential Carcinogen: National Toxicology Program = No I.A.R.C. Monographs = No OSHA = No This product has no carcinogens listed by IARC, NTP, NIOSH, or ACGIH as of this date, greater than or equal to 0.1%. Signs and Symptoms of Exposure: Concentrate may be irritating to eyes if not removed promptly. Breathing of highly concentrated vapors or spray mists may cause irritation to the respiratory tract. (1. Acute and 2. Chronic) 1. Causes irreversible eye damage and skin burns. May be fatal if absorbed through the skin. Do not get in eyes, on skin or on clothing. Wear protective eyewear (goggles or face shield), clothing, and gloves when handling. Harmful if swallowed. Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco. Remove contaminated clothing and wash before reuse. Inhalation of fine fog mist can cause irritation of mucous membranes. Fine fog mist application is not recommended. 2. None known to Hillyard Chemical listed as Carcinogen or Potential Carcinogen: National Toxicology Program = No I.A.R.C. Monographs = No OSHA = No Signs and Symptoms of Exposure: High vapor or aerosol mist concentrations may be irritating to the nose, throat and upper respiratory tract. Excessive inhalation of this material causes headache, dizziness, nausea and loss of motor skills. May cause moderate to severe skin irritation. Product No.: #819 Product Non-Acid Restroom Disinfectant/Cleaner Date: November 11, 2013 SECTION VI -- HEALTH HAZARD DATA continued: (1. Acute and 2. Chronic) 1. Concentrate is corrosive to all body tissue with which it comes in contact. 2. Prolonged and repeated exposure to the skin may produce dermatitis. Fine fog mist application is not recommended. Chemical listed as Carcinogen or Potential Carcinogen: National Toxicology Program = No I.A.R.C. Monographs = No OSHA = No SECTION VI -- HEALTH HAZARD DATA cont. Signs and Symptoms of Exposure: Direct eye contact can cause severe damage; repeated skin contact can cause severe irritation; concentrate is corrosive to eyes and skin. Ingestion of concentrate: immediate burning pain in mouth, throat, abdomen and severe swelling of larynx, skeletal muscle paralysis and affecting the ability to breathe.
Medical Conditions Generally Aggravated by Exposure
N/A Emergency and First Aid Procedures: In case of contact, immediately flush eyes with plenty of water for 15 minutes; get medical attention. If inhaled, remove to fresh air. If breathing is difficult, get medical attention. SECTION VII -- PRECAUTIONS FOR SAFE HANDLING AND USE Steps To Be Taken In Case Material Is Released Or Spilled: Pick up with mop or wet vac and wash away with water. Spills of concentrate should be picked up with wet vac and rinsed thoroughly. Waste Disposal Method Wash down sewer with large quantity of water. Container disposal Triple rinse (or equivalent), then offer clean, dry container for recycling or reconditioning. None known to manufacturer Emergency and First Aid Procedures If in eyes Hold eye(s) open and rinse slowly and gently with water for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Get medical attention. If inhaled: Immediately move person to fresh air. If affected person is not breathing, apply artificial respiration. If breathing is difficult, give oxygen. Seek medical attention. Ingestion: If the material is swallowed, get immediate medical attention or advice. Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Do not induce vomiting. NOTE TO PHYSICIAN: If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Treat the affected person appropriately. SECTION VII -- PRECAUTIONS FOR SAFE HANDLING AND USE Caution: Floors may become slippery. Isolate spill or leak area immediately. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. Wear appropriate personal protective equipment during clean-up. Small Spills: Absorb with earth, sand or other non-combustible materials. Transfer to containers for later disposal. Use clean non- sparking tools to collect absorbed material. Large Spills: Dike ahead of liquid spill for later disposal. Keep spill out of sewers and open bodies of water. Container Disposal: Do not reuse empty container. Triple rinse empty container with water. Return metal drum then offer for reconditioning or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. Plastic containers may be disposed of in a sanitary landfill, incinerated, or if allowed by local authorities, by burning. If burned, stay out of smoke. Offer for recycling if available. For containers 1 gallon or less: Do not reuse empty container (bottle, can, bucket). Wrap container and put in trash. Pesticide Disposal – Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Skin problems such as industrial dermatitis Emergency and First Aid Procedures: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. For eyes call a physician. Remove and wash contaminated clothing before reuse. If swallowed, drink promptly a large quantity of egg whites, gelatin solution or if these are not available, drink large quantities of water. Avoid alcohol. Call a physician immediately. Note to physician: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION VII -- PRECAUTIONS FOR SAFE HANDLING AND USE Steps To Be Taken In Case Material Is Released Or Spilled: Dike and contain spill with inert material (sand, earth, etc.) and transfer liquid and solid separately to containers for recovery or disposal. Small spills: Flush with water and pick up with wet vac or mop when on inside flooring. The pH of the concentrate is 12.4-13.4, thus concentrate is defined as corrosive per EPA Hazardous Waste Classification; when diluted with normal tap water for use to pH below 12.5 is not corrosive per EPA definition but still a pesticide waste. Waste Disposal Method: Pesticide wastes are acutely hazardous. Do not contaminate water, food or feed by storage or disposal. If these wastes cannot be disposed of by use according to label instructions contact you state pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Office for guidance.
Precautionary statements
To Be Taken In Handling And Storing Freezing of product may rupture container. Product shelf life is best retained by storage at 45-100°F temperature. Other Precautions: This product contains no reportable quantities of toxic chemicals subject to reporting requirements of Sec. 313 of SARA Title III Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR Part 372. SECTION VIII -- CONTROL MEASURES: Respiratory Protection (Specify Type): Not required Ventilation: Local Exhaust = Not required Mechanical (General) = N/A Special = N/A Other = N/A Protective Gloves: None required Eye Protection: Safety goggles suggested where splash of concentrate is a concern. Other Protective Clothing or Equipment: None required Work / Hygienic Practices: Wash thoroughly after handling. SECTION IX - TRANSPORTATION INFORMATION: Applicable regulations: 49 CFR = no; IMCO = no; IATA = no Proper shipping name: Cleaning compound UN No. not applicable Limited Qty. not applicable Hazard Class = not applicable Labels required not required DOT Exception not applicable EPA Hazardous waste number / code: not listed Hazardous waste characteristics: Ignitability = not applicable; Corrosivity = not applicable; Reactivity = not applicable DISCLAIMER OF WARRANTIES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein is presented in good faith and is believed to be appropriate and accurate. THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL REGULATIONS CONCERNING THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS. Version 2, * Denotes revisions since last published MSDS. Supersedes Version 1 August 16, 2006 #819 EPA Reg. No. 1839-169-1658 EPA Est. No. 1658-MO-1 To Be Taken In Handling And Storing Avoid contact with skin and eyes. Avoid breathing vapors or mists of this product. Wash hands before drinking, smoking or using toilet facilities. As with all chemicals, good industrial hygiene practices should be followed when handling this material. To Be Taken In Handling And Storing Do not store on side. Avoid creasing or impacting of side walls of package. Other Precautions Container disposal Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorities by burning. If burned stay out of smoke. This product contains no reportable quantities of toxic chemicals subject to reporting requirements of Section 313 of SARA Title III Emergency Planning and Community Right to Know Act of 1986 and 40 CFR Part 372. SECTION VIII -- CONTROL MEASURES Respiratory Protection (Specify Type): None normally required. If exposed to fine mist droplets of less than 15 microns, a NIOSH/MSHA approved respirator should be worn. Ventilation: 10 air changes per hour recommended Local Exhaust = N/A Mechanical (General) = recommended Special = N/A Other = N/A Protective Gloves: rubber or neoprene with concentrate Eye Protection: chemical goggles or face shield with concentrate Other Protective Clothing or Equipment: None Work / Hygienic Practices: Wash thoroughly after handling. SECTION IX - TRANSPORTATION INFORMATION Applicable regulations: 49 CFR = no; IMCO = no; IATA = no. Proper shipping name: Cleaning Compound UN No.: not applicable Limited Qty.: not applicable
NFPA Ratings
Health = 3 Flammability = 1 Reactivity = 0 Health = 3 Flammability = 0 Reactivity = 0
HMIS® ratings
Health = 3 Flammability = 1 Reactivity = 0 SECTION I -- IDENTITY AND MANUFACTURER'S INFORMATION (543N-19A) Manufacturer's Name: HILLYARD INDUSTRIES Product Name: NON-ACID RESTROOM DISINFECTANT/CLEANER Address: 302 North Fourth Street Date Prepared November 11, 2013 (version 5) St. Joseph, MO 64501 Prepared by: Regulatory Affairs Department Emergency Telephone No.: (800) 424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or accident involving chemicals.) Health = 3 Flammability = 0 Reactivity = 0 SECTION I -- IDENTITY AND MANUFACTURER'S INFORMATION (0442C) Manufacturer's Name: HILLYARD INDUSTRIES Product Name: RE-JUV-NAL 165 Address: 302 North Fourth Street Date Prepared May 13, 1994 St. Joseph, MO 64501 Prepared by: Regulatory Affairs Department Emergency Telephone No.: (800)-424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or accident involving chemicals.) Other information calls: (816) 233-1321 (Ext. 2303) www.hillyard.com SECTION II -- INGREDIENTS/IDENTITY INFORMATION Components ACGIH OTHER LIMITS (Specific Chemical Identity: CAS# OSHA TLV RECOMMENDED % Common Name(s) PEL Octyl Decyl Dimethyl Ammonium Chloride Dioctyl Dimethyl Ammonium Chloride Didecyl Dimethyl Ammonium Chloride OR Di-N-Alkyl (C8/C10-50%; C10/C10-30%; C8/C8-20%) not dimethyl ammonium chloride 68424-95-3 established N/A 1.08 Alkyl (C14, 50%; 40%; 10%) Dimethyl Benzyl C12, C16, 68424-85-1 not N/A 0.72 Ammonium Chloride established Ethanol 64-17-5 1000 ppm 1000ppm N/A less than 2% Sodium metasilicate 6434-92-0 not 2 mg/m3 0.2 - 0.7 established Water 7732-18-5 none N/A --- Tetrasodium ethylene diamine tetraacetate 64-02-8 not N/A --- established Nonylphenol Ethoxylate 9016-45-9 not N/A --- established SECTION III -- PHYSICAL / CHEMICAL CHARACTERISTICS Boiling Point: 738 mm 202ºF Specific Gravity (H20 = 1): 25ºC = 1.01 & 39ºC = 1.01 Vapor Pressure (mm Hg.): 17.6 Percent Volatile by Volume (%): 92.6 Vapor Density (AIR = 1): less than 1 Evaporation Rate (ethyl ether = 1): slower than 1 Solubility in Water: appreciable
Further information
calls (816) 233-1321 (Ext. 8285) http://www.hillyard.com *SECTION II -- INGREDIENTS/IDENTITY INFORMATION Components (Specific Chemical Identity: ACGIH OTHER LIMITS Common Name(s) CAS# OSHA PEL TLV RECOMMENDED % Water 7732-18-5 N/E N/A 82-87 Alkyl dimethyl benzyl ammonium chloride 68424-85-1 N/E N/A 2.170 *Octyl decyl dimethyl ammonium chloride 32426-11-2 N/E N/A 1.627 Dioctyl dimethyl ammonium chloride 5538-94-3 N/E N/A 0.814 Didecyl dimethyl ammonium chloride 7173-51-5 N/E N/A 0.814 N/E = Not Established N/A = Not Applicable SECTION III -- PHYSICAL / CHEMICAL CHARACTERISTICS Boiling Point: >201°F (PMCC) Specific Gravity (H2O = 1): 25°C = 1.001 Density= 8.32 lb/gal. Vapor Pressure (mm Hg.): 17.6 Percent Volatile by Weight (%): 91.5 – 92.5 Vapor Density (AIR = 1): 0.6 Evaporation Rate (ethyl ether = 1): Slower than 1 Solubility in Water: complete Appearance and Odor: Clear, blue liquid; floral fragrance pH (concentrate): 6 – 7 SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flash point: >200ºF (PMCC) Flammable Limits: LEL = Not applicable UEL = Not applicable Extinguishing Media: Dry chemical, foam, carbon dioxide, water fog Special Fire Fighting Procedures: Firefighters should wear full fire-fighting turn-out gear (full Bunker gear) including NIOSH-approved self-contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode. SECTION V -- PHYSICAL HAZARDS Stability: Stable Conditions to Avoid: Avoid strong oxidizing agents Incompatibility (Materials to Avoid): Anionic Compounds and strong oxidizing agents Hazardous Decomposition Products or Byproducts: Upon decomposition, this product may yield oxides of nitrogen and ammonia. Hazardous Polymerization: Will not occur Conditions to Avoid: None known to Hillyard SECTION VI -- HEALTH HAZARD DATA
Storage
Procedures Do not contaminate water, food or feed by storage or disposal. Keep the container tightly closed and in a cool well-ventilated place. Avoid freezing or excessive heat. SECTION VIII -- CONTROL MEASURES Engineering Controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory Protection: If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection should be worn. Protective Gloves Use impervious gloves. Eye Protection Wear chemical goggles and face shield Clothing or Equipment: Eye wash fountain and emergency showers are recommended. SECTION IX - TRANSPORTATION INFORMATION Applicable regulations: 49 CFR = No; IMCO = No; IATA = No Proper shipping name Cleaning Compound; UN No. Not applicable; Limited Qty. Not applicable;
Hazard categories
Not applicable Labels required Not required Exception Not applicable EPA Hazardous waste number/code: Not listed Hazardous waste characteristics: Ignitability = Not applicable; Corrosivity = Not applicable; Reactivity = Not applicable DISCLAIMER OF WARRANTIES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET. The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein is presented in good faith and is believed to be appropriate and accurate. THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL REGULATIONS CONCERNING THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS. Version 5, * Denotes revisions since last published MSDS. Supersedes Version 4 July 5, 2012 #165 not applicable Labels required not required DOT Exception not applicable EPA Hazardous waste number/code: not listed Hazardous waste characteristics: Ignitability = not applicable; Corrosivity = yes; Reactivity = not applicable. DISCLAIMER OF WARRANTIES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein is presented in good faith and is believed to be appropriate and accurate. THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL