E:ISO

PUR-Systems GmbH

Revision date : 2013-06-25

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

30-60

General Information

Version

REACH GHS/CLP

Revision date

2013-06-25

Product name

E:ISO

Product Synonyms

Polymer

CAS No.

9016-87-9

1.2.1 Relevant identified uses

A component of a polyurethane system

Emergency telephone

+49 174 975 1711, +49 172 999 3193

Icons in SDS

GHS07 GHS08

Company Information

company name

PUR-Systems GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

info@pursystems.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

Classification according to Acute toxicity, inhal., Vapours, Cat. 4, H332

EU Classification

Carc. Cat. 3; R40 Directives 67/548/EEC or Xi; R36/37/38 1999/45/EC R42/43 Xn; R48/20

Additional information

For the full text of the phrases mentioned in this Section, see

2.2 Label elements

X

Signal word

Danger

Hazard statements

H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H373inh: May cause damage to organs through prolonged or repeated exposure if inhaled.

Precautionary statements

P260: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301+P330+P331 IF SWALLOWED rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair) Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P341 IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/ attention. P363: Wash contaminated clothing before reuse. Additional advice Contains isocyanates. May produce an allergic reaction.

Product definition

Isocyanic acid,polymethylenepolyphenylene ester, CAS-No. 9016- 87-9 4,4'-Methylenediphenyl diisocyanate, CAS-No. 101-68-8, REACH No. 01-2119457014-47 Labelling according

R-phrase(s)

R40: Limited evidence of a carcinogenic effect. R36/37/38: Irritating to eyes, respiratory system and skin. R42/43: May cause sensitisation by inhalation and skin contact. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s)

S23: Do not breathe vapour S24: Avoid contact with skin. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37: Wear suitable gloves. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60: This material and its container must be disposed of as hazardous waste. Hazardous component(s) which None. must be listed on the label

2.3 Other hazards

No hazards to be especially mentioned.

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