Note: Ingredients listed on restricted chemical lists
EC/CAS
247-714-0/26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
60-80%
General Information
Version
27/03/2023
Revision date
2023-03-27
Product name
Cold Melt Hardener
1.2.1 Relevant identified uses
Polyurethane coating
Emergency telephone
+44 (0) 1865 407 333
Icons in SDS
Company Information
company name
Proteus Waterproofing Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
enquiries@proteuswaterproofing.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture Skin Irrit. 2; H315, Causes skin irritation Skin Sens. 1; H317, May cause an allergic skin reaction Eye Irrit. 2; H319, Causes serious eye irritation Acute Tox. 4; H332, Harmful if inhaled Resp. Sens. 1; H334, May cause allergy or asthma symptoms or breathing difficulties if inhaled STOT SE 3; H335, May cause respiratory irritation Carc. 2; H351, Suspected of causing cancer STOT RE 2; H373, May cause damage to organs through prolonged or repeated exposure
Signal word
Danger
Hazard statements
Causes skin irritation. (H315) May cause an allergic skin reaction. (H317) Causes serious eye irritation. (H319) Harmful if inhaled. (H332) May cause allergy or asthma symptoms or breathing difficulties if inhaled. (H334) May cause respiratory irritation. (H335) Suspected of causing cancer. (H351) May cause damage to organs through prolonged or repeated exposure. (H373)
Precautionary statements
General -
Prevention
Obtain special instructions before use. (P201) Do not handle until all safety precautions have been read and understood. (P202) Do not breathe vapour/mist. (P260) Wash hands thoroughly after handling. (P264) Use only outdoors or in a well-ventilated area. (P271) Contaminated work clothing should not be allowed out of the workplace. (P272) Wear eye protection/protective gloves/protective clothing. (P280) [In case of inadequate ventilation] wear respiratory protection. (P284)
Response
Get medical advice/attention if you feel unwell. (P314) IF ON SKIN: Wash with plenty of water and soap. (P302+P352) IF INHALED: Remove person to fresh air and keep comfortable for breathing. (P304+P340) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (P305+P351+P338) IF exposed or concerned: Get medical advice/attention. (P308+P313) If skin irritation or rash occurs: Get medical advice/attention. (P333+P313) If eye irritation persists: Get medical advice/attention. (P337+P313) If experiencing respiratory symptoms: Call a POISON CENTER/doctor (P342+P311) Take off contaminated clothing and wash it before reuse. (P362+P364)
Storage
Store in a well-ventilated place. Keep container tightly closed. (P403+P233) Store locked up. (P405)
Disposal
Dispose of contents/container in accordance with local regulation. (P501)
Hazardous Ingredients
Methylenediphenyl diisocyanate
Additional information
EUH066, Repeated exposure may cause skin dryness or cracking. EUH204, Contains isocyanates. May produce an allergic reaction. EUH401, To avoid risks to human health and the environment, comply with the instructions for use. As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact with this product. Additional warnings This mixture/product does not contain any substances considered to meet the criteria classifying them as PBT and/or vPvB. This product does not contain any substances considered to be endocrine disruptors in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.
2.1 Classification of the substance or mixture
Skin Irrit. 2; H315, Causes skin irritation. Skin Sens. 1; H317, May cause an allergic skin reaction. Eye Irrit. 2; H319, Causes serious eye irritation. Acute Tox. 4; H332, Harmful if inhaled. Resp. Sens. 1; H334, May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT SE 3; H335, May cause respiratory irritation. Carc. 2; H351, Suspected of causing cancer. STOT RE 2; H373, May cause damage to organs through prolonged or repeated exposure. Classified according to Regulation (EC) No. 1272/2008 (CLP) as retained and amended in UK law.