PC-7, PartA

Hazard statements (CLP)

H317

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

OSHA - Appearance Grey paste Physical state Paste Odour Mild Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitisation Category

Signal word

Warning Warning

Hazard statements

EN / HGHS Page 1/9 130519-23C-CA - PC-7, PartA revision 25-Oct-2017 Skin contact Wash with soap and plenty of water. Remove and wash contaminated clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. If skin irritation or rash occurs: Get medical advice/attention. Inhalation Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get medical attention immediately. Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Seek medical advice. Self-protection of the first aider First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Most important symptoms and effects Symptoms Causes eye and skin irritation. Inhalation only possible at elevated temperatures. May cause irritation. May cause an allergic skin reaction. Indication of any immediate medical attention and special treatment needed Note to doctors Skin and eye conditions may be aggravated by long term exposure. 5. FIREFIGHTING MEASURES Suitable Extinguishing Media Dry chemical, CO2 or water spray. Unsuitable extinguishing media Not determined. Specific hazards arising from the — Product is not flammable. chemical Hazardous Combustion Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes. Explosion Data Sensitivity to Mechanical impact None. Sensitivity to Static Discharge None. Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH fire-fighters (approved or equivalent) and full protective gear. Wear positive pressure self-contained breathing apparatus (SCBA). Do not release runoff from fire control methods to sewers or waterways. NFPA Class IIIB. 6: ACCIDENTAL. RELEASE'MEASURES 2.0 a Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Environmental! precautions Environmental precautions See Section 12 for additional Ecological Information. EN / HGHS Page 3/9 130519-23C-CA - PC-7, PartA revision 25-Oct-2017 Skin and body protection Wear protective gloves and protective clothing. If necessary, refer to appropriate regulations and standards. Respiratory protection Ensure adequate ventilation, especially in confined areas. Wear an appropriate NIOSH/MSHA approved respirator if ventilation is inadequate. If necessary, refer to appropriate regulations and standards. General hygiene considerations Avoid contact with skin, eyes and clothing. After handling this product, wash hands before eating, drinking, or smoking. If contact occurs, remove contaminated clothing. if needed, take first aid action shown on section 4 of this SDS. Launder contaminated clothing before reuse. 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Grey paste Colour Grey . Odour Mild Odour Threshold No information available Property Values Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction

Remarks

__* Method pH >/=2.0-</=12.0 Melting Point/Freezing Point Not available Boiling Point/Boiling Range No data Flash Point 248.88 °C / 480 °F CC (closed cup) Evaporation Rate Not determined Flammability (Solid, Gas) Not determined Flammability Limits in Air Upper Flammability Limits Not available Lower Flammability Limit Not available Vapour Pressure Not determined Vapour Density Not available Relative Density 1.16 (1=Water) Water Solubility Insoluble in water Solubility in other solvents Alcohols Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive properties No information available. Oxidising properties No information available.

Further information

Softening Point No information available Molecular weight No information available VOC Content (%) No information available Density 9.5 Ibs/gal Bulk Density No information available --410.. STABILITY AND REACTIVITY Reactivity No information available. Chemical Stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerisation Hazardous polymerisation does not occur. EN / HGHS Page 5/9 130519-23C-CA - PC-7, PartA revision 25-Oct-2017 ~.Delayed and immediate effects as well as chronic effects from short and long-term exposure Respiratory or skin sensitisation May cause an allergic skin reaction. Carcinogenicity Titanium dioxide is a possible carcinogen when it appears as a respirable dust. The table below indicates whether each agency has listed any ingredient as a carcinogen. at Ghemical ‘Name Pesce vACGIHAE Sy \ IARC EEE INTP. ue 2

ECOLOGICAL INFORMATION

Ecotoxicity Toxic to aquatic life with long lasting effects. i “Chemical Name: Talc — ~ 100: 96 h Brachydanio - 14807-96-6 rerio g/L LC50 semi-static| Persistence/Degradability No information available. Bioaccumulation No information available. Mobility Not determined.

Other hazards

No information available. 43, DISPOSAL CONSIDERATIONS Waste Treatment Methods Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with products environmental legislation. Contaminated packaging Do not reuse empty containers. EN / HGHS Page 7/9 130519-23C-CA - PC-7, PartA revision 25-Oct-2017 [16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION | NFPA

Health hazards

2 Flammability 1 Instability 0 Special Hazards Not determined HMIS 2 Flammability 1

Physical hazards

0 Personal Protection B- Safety Glasses, Gloves Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation Issue date 06-Sep-2011 revision 25-Oct-2017 revision Note New format. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet EN / HGHS Page 9/9 130519-20C-CA - PC-7, Part B revision 25-Oct-2017

Prevention

' Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapours/spray Contaminated work clothing should not be allowed out of the workplace

Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of water and soap Take off all contaminated clothing and wash it before reuse If skin irritation or rash occurs: Get medical advice/attention

Disposal

Dispose of contents/container to an approved waste disposal plant

2.1 Classification of the substance or mixture

Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitisation Category 1