Sure Kiean Fast Acting Stripper

SECTION 2: Hazards identification

Category 4 Acute toxicity - Oral Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye Irritation Category 1B Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 2 exposure) Specific target organ toxicity (repeated Category 3 Flammable liquids Label

2.2 Label elements

clenier>. Emergency Overview Danger

Hazard statements

(Harmful if swallowed \, |Gauses skin irritation Causes serious eye irritation Vay cause cancer ‘ay cause damage to organs \ cause damage to organs through prolonged or repeated exposure ‘mable liquid and vapor 20051 Sure Klean® Fast Acting Stripper ( [Appearance clear Physical state Liquid gel Odor Irritating

Prevention

Obtain special instructions before use Do not handle until ail Safety precautions have been read and Use understood personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear eye/face protection De not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/ -? fequipment Use only non-sparking tools Take precautionary measures against static discharge

Response

IF exposed or concerned: Get medical advice/attention If IF IN EYES; Rinse cautiously with water for several minutes. eye Remove contact lenses, if present ( irritation persists: Get medical and easy to do. Continue advice/attention rinsing If skin irritation occurs: Get medical advice/attention Wash IF ON SKIN (or hair): Remove/Take off immediately all contaminated contaminated clothing. Rinse skin with clothing before reuse water/shower IF SWALLOWED: Call Rinse mouth a POISON CENTER or doctor/physician if you feel unwell In case of fire: Use CO2, dry chemical, or foam for extinction

Storage

Store locked up Store in a well-ventilated place. Keep cool

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

Further information

+ May be harmful in contact with skin 1.954% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENT. Chemical Name CAS No Methylene chloride Weight-% Trade Secret 75-09-2 Triethanolamine 60 - 100 * 102-71-6 5-10 Methanol 67-56-41 * { 1-5 * AN 20051 Sure Kiean® Fast Acting Stripper 1-5 Potassium Oleate * 143-18-0 97-99-4 1-5 Tetrahydrofurfuryl alcohol * 1330-20-7 01-4 Xylene * 100-41-4 01-1 Ethylbenzene * The exact percentage (concentration) of composition has been withheld as a trade secret. “IRST. AID MEASURES First ikea First aid ald measures In case of accident or unweliness, seek medical advice immediately (show directions for General advice use or safety data sheet if possible). Eye contact Immediately flush with plenty of water. After initia! flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Skin Gontact Remove to fresh air. If breathing is irregular stopped, administer artificial respiration. or Inhalation barrier give mouth-to-mouth resuscitation. Call a to Avoid direct contact with skin. Use physician. Ingestion Do NOT induce vomiting. Rinse mouth. Drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison contro! center immediately. Self-protection of the first aider Remove all sources of ignition. Most important symptoms and effects, both acute and delayed Symptoms Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. FIRE-FIGHTING MEASURE Suitable Extinguishing Media Use. Dry chemical. Carbon dioxide (C02), Water spray (fog). Alcohol resistant foam. Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. "ACCIDENTAL RELEASE MEASURES Nersonal precautions, protective equipment and emergency procedures \ 20051 Sure Klean® Fast Acting Stripper ’ Personal precautions Remove all sources of ignition. Pay aitention to flashback. Evacuate personnel! to safe areas. Ensure adequate ventilation, especially in confined areas. Take precautionary measures against static discharges. Use personal protective equipment as required, Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See Section 12 for additional ecological information. ee Methods and Se material ete lal for for containment containment and and cleaning u up | Methods for containment Dike far ahead of liquid spill for later disposal. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Dam up. Cover liquid spill with sand, earth or other non-combustible absorbent material. Pick up and transfer to properly labeled containers. Use only non-sparking tools. Take transferring material. precautionary measures against static discharges. Ground and bond containers when ANDLING AND STORAGE Precautions for safe handling Advice on safe handling Ensure adequate ventilation, especially in confined areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and grounded, explosion-proof equipment. Ail equipment used when handling the product must be ( Conditions for safe Storage, including any incompatibilities , Storage Conditions containers. Keep tightly closed in a dry and cool place. Keep away from heat. Keep in properly labeled Incompatible materials reompatible with oxidizing agents. Reducing agent. Aluminum. Metals. Acid anhydrides. cids. _ EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH Methylene chloride IDLH TWA: 50 ppm 75-09-2 TWA: 25 ppm IDLH: 2300 ppm (vacated) TWA: 500 ppm (vacated) STEL: 2000 ppm 5 min in any 3h (vacated) Ceiling: 1000 ppm STEL: 125 ppm see 29 CFR Triethanolamine 1910,1052 TWA: 5 mg/m - 102-71-6 - Methanol STEL: 250 ppm TWA; 200 ppm 67-56-1 TWA: 200 ppm IDLH: 6000 ppm TWA: 260 mg/m TWA: 200 ppm Ss (vacated) TWA: 200 ppm TWA: 260 mg/m? (vacated) TWA: 260 mg/m STEL: 250 ppm (vacated) STEL: 250 ppm STEL: 325 mg/m? (vacated) STEL: 325 mg/m? (vacated) S* ( 20051 Sure Klean® Fast Acting Stripper 100 ppm - Xylene STEL: 150 ppm TWA: TWA: 160 ppm TWA; 435 mg/m? 41330-20-7 (vacated) TWA: 100 ppm (vacated) TWA; 435 mg/m? (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m 100 ppm IDLH: 800 ppm TWA: Ethylbenzene TWA: 20 ppm TWA: 435 mg/m? TWA: 100 ppm 100-41-4 (vacated) TWA: 100 ppm TWA; 435 mg/m? (vacated) TWA; 435 mg/m? STEL: 125 ppm STEL: 545 mg/ms (vacated) STEL: 125 ppm (vacated) STEL: $45 maim? NIOSH IDLH Immediately Dangerous to Life or Health Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 Other Information (11th Cir, 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems. Ground/bond container and receiving equipment. Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin and body protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. ND CHEMICAL PROPERTIES Information on basic physica! and chemical properties Physical state Liquid ge! Odor Irritating Appearance clear No information Slight yellow available Odor threshold Color Values. Remarks _+ Method Not Applicable pH Melting pointifreezing point -30 °C | -22 °F Boiling point/boiling range No information available Flash point 27 °C | 81 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limits No information available Lower flammability limit No information available Vapor pressure No information available Vapor density No information available ‘Specific Gravity 4.22 20051 Sure Klean® Fast Acting Stripper Water solubility partially soluble Solubility in other solvents No information available ( Partition coefficient No information available Autoignition temperature Decomposition temperature No information available Kinematic viscosity Dynamic viscosity No information available Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. incompatible materials Incompatibie with oxidizing agents, Reducing agent. Aluminum. Metals. Acid anhydrides. Acids. Hazardous Decomposition Products Carbon oxides. Hydrogen chloride. Phosgene. Chlorine. Unidentified organic compounds. Information on likely routes of exposure Product Information Harmful if swallowed Causes serious eye irritation Causes skin irritation Inhalation Avoid breathing vapors or mists. May be harmful if inhaled, Eye contact Avoid contact with eyes. Causes serious eye irritation. Skin Contact Avoid contact with skin. Causes skin irritation. Ingestion Do not taste or swallow. Chemical Name Oral LD50 Methylene chloride Dermal LDS0 > 2000 mg/kg (Rat) inhalation LC56 75-09-2 - = 76000 mgim? (Rat) 4h Triethanolamine = 4190 mg/kg (Rat) 102-71-6 > 2000 mg/kg { Rabbit )> 16 mLikg Methanol - (Rat) 67-56-1 = 5628 mg/kg (Rat) = 15800 mgikg (Rabbit) = 83.2 mg/L. (Rat) 4h = 64000 Potassium Oleate > 5 gikg (Rat) ppm (Rat) 4h 143-18-0 > 2 g/kg (Rat) . Tetrahydrofurfury! alcohol = 1600 mg/kg (Rat) 97-99-4 - Xylene = 4300 mg/kg (Rat) 1330-20-7 > 1700 mg/kg ( Rabbit } = 6000 ppm (Rat) 4h = 47635 Ethylbenzene = 3500 mg/L (Rat) 4h mg/kg (Rat) = 100-41-4 = 17.2mg/L (Rat) 4h 15354 mg/kg (Rabbit) ( 20051 Sure Klean® Fast Acting Stripper Information on toxicological effects Symptoms Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. Harmful if swallowed. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group |), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Chemical Name ACGIH IARC NTP OSHA Methylene chloride A3 Group 2B Reasonably Anticipated Xx 75-09-2 Triethanolamine - Group 3 - 102-71-6 Xylene - Group 3 - 1330-20-7 Ethylbenzene A3 Group 2B - x 100-41-4 ACGIH (American Conference of Governmental indusirial Hygienists) A3 - Animal Carcinogen IARC (international Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X- Present Reproductive toxicity Na information available. STOT - single exposure Target Organs. STOT - repeated exposure Target Organs. Chronic toxicity May cause adverse liver effects. Target Organ Effects central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract (Gl), liver, lungs, Respiratory system, Skin. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 1.954% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1089 mg/kg ATEmix (dermal) 4598 mg/kg mg/l ATEmix (inhalation-dustimist) 9 mg/l ATEmix (inhalation-vapor) 1704.6 mg/l Ecotoxicity Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea microorganisms 20051 Sure Kiean® Fast Acting Stripper Methylene chioride é 500: 96 h 140.8 - 277.8: 96h EC50 = 4 mg/L 24h 4532 - 1847: 48 h Daphnia’ 75-09-2 Pseudokirchnerielia Pimephales promelas mg/L EC50 = 2,88 mg/L 15 min magna mg/L EC50 Static subcapitata mg/L EC50 500: LC50 flow-through 262 - 190: 48 h Daphnia magna 72 h Pseudokirchneriella 855: 96 h Pimephales mg/L EC50 subcapitata mg/L EC50 promelas mg/L LC50 static 4193: 96 h Lepomis macrochirus mg/L LC50 static 193: 96 h Lepomis macrochirus mg/L LC50 flow-through Triethanolamine 216: 72 h Desmaodesmus 10600 - 13000: 96 h 1386: 24 h Daphnia magna 102-71-6 subspicatus mg/L EC50 169: Pimephales promeias mg/i. mgd. EC5O 96 h Desmodesmus LC50 flow-through 1000: 96 subspicatus mg/L EC50 h Pimephates promelas mg/L LC50 static 450 - 1000; 96h Lepomis macrachirus mg/L LC50 static Methanoi 28200: 96 h Pimephales 67-56-1 promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L. L.C50 flow-through 18 - 20: 96 h Oncorhynchus mykiss mL/L LCS0 static 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through Tetrahydrofurturyl alcohol 3400: 48 h Chaetodonoides 97-99-4 mg/L LC50 Xylene 13.4: 96 h Pimephales 3.82: 48 h water flea mg/L | 1330-20-7 promelas mg/L LC50 EC50 0.6: 48h Gammarus, flow-through 2.664 - 4.093: lacustris mg/L LC50 96 h Oncorhynchus mykiss mg/L LC50 static 13.5 - 17.3: 96 h Oncorhynchus mykiss mg/L LC50 13.1 - 16.5: 86h Lepomis macrochirus mg/L LC50 flow-through 19: 96 h Lepomis macrochirus mg/L LCS0 7.711 - 9.591: 96h Lepomis macrochirus mg/L LC50 static 23,53 - 29.97: 96] h Pimephales promelas mg/L LC50 static 780: 96 h Cyprinus carpio mg/L LC50 semi-static 780: 96 h Cyprinus carpio mg/L LC50 30.26 - 40.75: 96 h Poecilia reticulata mg/L. LC50 static Ethylbenzene 4.6: 72h 411.0 - 18.0: 96 h 1.8 - 2.4: 48 h Daphnia 100-41-4 Pseudokirchneriella Oncorhynchus mykiss mg/L magna mg/L EC50 subcapitata mg/L EC50 438: LC50 static 4.2: 96h 96 h Pseudokirchneriella Oncorhynchus mykiss mg/L subcapitata mg/L EC50 2.6 - LC50 semi-static 7.55 - 11: 11.3: 72h 96 h Pimephates promelas Pseudokirchnerielta mg/L LC50 flow-through 32: subcapitata mg/L EC50 96 h Lepomis macrochirus static 1.7- 7.6: 96h mg/L LC50 static 9.1 - 15.6: Pseudokirchneriella 96 h Pimephales promelas subcapitata mg/L EC50 mg/L LC50 static 9.6: 96 h static Poecilia reticulata mg/L LC50 static Persistence and degradability No information available. 20051 Sure Klean® Fast Acting Stripper Bioaccumulation No information available. Chemical Name Partition coefficient Methylene chloride 4.25 75-09-2 Triethanolamine -2.53 102-71-6 Methanol -0.77 67-56-1 Xylene 3.15 1330-20-7 Ethylbenzene 3.118 100-41-4 Other adverse effects No information available 43. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing | RCRA - D Series Wastes | RCRA-U Series Wastes Methylene chloride Uo8so Inctuded in waste streams: - U08e 75-09-2 F001, F002, F024, F025, FO39, K009, KO10, K156, K157, K158 Chemical Name RGRA - Halogenated RCRA -P Series Wastes | RCRA-F Series Wastes | RCRA - K Series Wastes Organic Compounds Methylene chloride Category | - Volatiles - Toxic waste - 75-09-2 waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution, This product contains one or more substances that are listed with the State of California as a hazardous waste. \NSPORT INFORMATION nnaT Dari latad 20051 Sure Klean® Fast Acting Stripper ’, UN/ID No UN1263 4 Proper shipping name Paint related material Hazard Class 3 Packing Group Hl 5. REGULATORY INFORMATION - International Inventories TSCA Complies DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS No Weight-% SARA 313 - Threshold | Values % Methylene chloride - 75-09-2 75-09-2 60 - 100 0.4 Methanol - 67-56-1 67-56-1 1-5 1.0 Ethylbenzene - 100-41-4 100-41-4 O4-4 0.4 SARA 341/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA - Hazardous Quantities