MICROBAN X.590 INSTITUTIONAL SPRAY

2.2 Label elements

Eme ncv Overview Warning

Hazard statements

Causes serious eye irritation May cause drowsiness or dizziness Flammable liquid and vapor P a g e 1 1 9 - Avoid breathing dusvfume/gas/miswapors/spray - Use only outdoors or in a well-ventilated area - Keep away from heavsparksi/open flames/hot surfaces. - No smoking - Keep container lighlly closed - Ground/bond coniainer and receiving equipment - Use explosion-proof electricalfuentilating/lighting/equipment. - use only non-sparking tools - Take precautionary measurcs against statlc discharge - Wear protective gloves/protective clothing/eye protection/face protection - Keep cool

Response

- - Specific Treatment (See Section 4 on the SDS) lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, it present and easy to do. Continue rinsing. lf eye irritalion persists: Get medical advice/attention. lF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. lF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. lF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink plenty of water. In case of fire: Use CO2, dry chemical, or foam for extinction.

Storage

Store in a well-ventilated place. Keep coniainer tightly closed - Store locked up Conditions Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Incompatible materials None known based on information supplied. Gontrol Darameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. 2-Propanol STEL:400 ppm TWA:400 ppm IDLH: 2000 ppm 67-63-0 TWA: 200 ppm TWA:980 mg/m3 TWA:400 ppm (vacated) TWA:400 ppm^ TWA: 980 mg/m" (vacated) TWA: 980 mg/m' STEL: 500 ppm - (vacated) STEL: 500 ppm ^ STEL: 1225 mglm" (vacated) STEL: 1225 molm' ATTOSH IDLH lmmediately Dangerous fo Life or Health

Precautionary statements

Disposal - Dispose of contents/container to an approved waste disposal plant

Further information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity Chemical Name CAS No. Weiqht-% Trade Secret 2-Propanol 67-63-0 10-30 Benzethonium Chloride 121-54-0 1-1 2-Hvdroxvbiohenvl 90-43-7 1-1 First aid measures General advice lmmediate medical attention is required. In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). lf symptoms persist, call a physician. P a g e 2 1 9 Skin Gontact Wash off immediately with plenty of water. lmmediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. lf skin irritation persists, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes lf symptoms persist, call a physician Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician lmmediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing Inhalation Remove to fresh air. lf symptoms persist, call a physician. lmmediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors. Ingestion lmmediate medical attention is not required. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Remove all sources of ignition. Use personal protective equipment as required. Most important svmptoms and effects. both acute and delaved Symptoms Any additional important symptoms and effects are described in Section 11: Toxicology lnformation. Indication of anv immediate medical attention and special treatment needed Note to physicians Treat sym ptomatical ly. Suitable extinouishino media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinquishinq media Do not use a solid water stream as it may scatter and spread fire. Protective equipment and precautions for firefiqhters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Personal orecautions. protective eouiDment and emerqencv Drocedures Personal precautions Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Environmental Drecautions Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleanino uo Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. Dam up. Soak up with inert absorbent material (e.9. sand, silica gel, acid binder, universal binder, sawdust). Soak up with inert absorbent material. P a g e 3 / 9 Precautions for safe handlinq Advice on safe handling Ensure adequate ventilation, especially in confined areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All equipment used when handling the product must be grounded. Use with local exhaust ventilation. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Gonditions for safe storage. includinq anv incompatibilities Density Lbs/Gal 8 VOC Content (%) 25.29 Reactivitv No data available Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Gonditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Information on likelv routes of exoosure Inhalation No data available. Eye contact Severely irritating to eyes. Skin Gontact Prolonged contact may cause redness and irritation. Ingestion May be harmful if swallowed. Ghemical Name Oral LD50 Dermal LD50 Inhalation LC50 2-Propanol = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m' ( Rat ) 4 h 67-63-0 P a g e 5 / 9 Octylphenol Ethoxylate 1700 mg/kg ( Rat = ) 4190 mg/kg 9036-1 9-5 ( R a t ) lnformation on toxicoloqical effects Symptoms No lnformation available. Delaved and immediate effects as well as chronic effects from short and lonq-term exposure Sensitization No lnformation available. Germ cell mutagenicity No Information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Shemical Name ACGIH IARC NTP

Remarks

Method pH 6.5 - 7.5 Specific Gravity .96 Viscosity Water Thin Melting poinUfreezing point No Information available Flash point 27 "C 77 "F Boiling point / boiling range No Information available Evaporation rate Same as water Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: No Information available Lower flammability limit: No lnformation available Vapor pressure No Information available Vapor density No Information available Water solubility Miscible in water Partition coefficient No Information available Autoignition temperature No Information available Decomposition temperatu re No Information available

Aspiration hazard

No Information available. Numerical measures of toxicitv - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document Ecotoxicitv Chemical Name Alqae/aquatic plants Fish Crustacea 2-Propanol 1000: 96 h Desmodesmus 9640 96 h Pimephales promelas 13299 48 h Daphnia magna mg/L 67-63-0 subspicatus mg/L EC50 1000 72 h mg/L LC50 flow-through 11130 96 EC50 Desmodesmus subspicatus mg/L h Pimephales promelas mg/L LC50 EC50 static 1400000: 96 h Lepomis macrochirus uo/L LC50 2-Hydroxybiphenyl 0.85:72 h Desmodesmus 3,4: 96 h Pimephales promelas 1 - 2.5:48 h Daphnia magna mg/L 90-43-7 subspicatus mg/L EC50 mg/L LC50 flow-through 2.74:96 h EC50 Static Lepomis macrochirus mg/L LC50 2.75:96 h Oncorhynchus mykiss mg/L LC50 5.8: 96 h Poecilia reticulata mq/L LC50 static Persistence and deqradabilitv No Information available. Bioaccumulation No Information available. rcc t@ P a g e 6 / 9 2-Propanol 0.05 67-63-0 2-Hydrorybiphenyl 3 . 1 8 90-43-7

Other hazards

This pesticide is toxic to fish and aquatic invertebrates. Do not discharge effuent containing this product into lakes, streams, ponds, estuaries, oceans or other water unless in accordance with the requirments of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to the discharge. Do not discharge effuent containing this product to sewer systems withour previously notifying the local sewage treatment plant authority. For guidance, conatct your State water board or Regional office of the EPA. Waste treatment methods Disposal of wastes 70385-4 Pesticide Disposal: To avoid wastes, use all matieral in this container by application according to label directions. lf wastes cannot be avoided, off remaining product to a waste disposal facility or pesticide disposal program (often such programs are run by state or local governments or by industry). 73085-4 Container Disposal: Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if availble. lf recycling is not avialable, puncture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorites, by buring. lf burned, stay out of smoke. Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status 2-Propanol Toxic 67-63-0 lqnitable Note: The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping descrjption before tendering th;s malerial for shipment. For additional information, please contact the distributor listed in section 1 of this SDS. U.S. Departmenl of Transportation {USDOTI 4xl Gallon Case Compound Cleaning Liquid, NOl, LTD aTY (LTDY Pails & Drums (<119 Gallons) uN1993, FLAMMABLE LtQUtD, NOS, (CONTAINS /SOPROPANOL), 3, ilt (HM-FSsA) DOT Notes This SDS is a universal document for all package/container sizes. This product is a PG lll and MAY be transported under 49CFR as a "Limited Quantity or LTD QTY" in 4xl gallon or smaller packages. Refer to package markings and/or shipping paper for an accurate basic description. I nternational Inventories TSCA Complies DSL/NDSL Complies Page 7 l9 ISCA - United States Toxic Substances Contol Act Section 8(b) lnventory DSLINDSL - Canadian Dortestic Subsfances L,'brNon-Oom€stic Subsfarces L,:st US Federal Reoulations SARA 3I3 Section 313 of Title lll of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 hemical Name SARA 313 - Threshold Values % l-Prooanol- 67-63-0 SARA 311/312 Hazard Gateqories

Acute Health Hazards

Yes Ghronic Health Hazard No Fire hazard Yes Reactive Hazard No Sudden release of pressure hazard No CWA (Clean Water Actl This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 cFR 122.42)