Microban Glean Garpet Sanitizer

Hazard statements (CLP)

H302

Code

Statements

H302

Harmful if swallowed

2.2 Label elements

E ncv Overuiew Warning

Hazard statements

May be harmful if swallowed Harmful if inhaled Causes mild skin irritation Causes serious eye irritation May cause an allergic skin reaction Toxic to aquatic life with long lasting effects Flammable liquid and vapor

Prevention

+eg - Avoid breathing d ust/ftJ me/gas/misllvapors/spray - Use only outdoors or in a well-ventilated area - Contaminated work clothing should not be allowed out of the wo*place - Avoid release to the environment - Keep away from heausparks/open flames/hot surfaces. - No smoking - Keep container tightly closed - Ground/bond container and receiving equipment - lJse explosion-proof electdcaltuentilating/lighting/equipment. - Use only non-sparking tools - Take precautionary measures against statlc discharge - Wear protective gloves/protective clothing/eye protection/face protection

Response

- Specific Treatment (See Section 4 on the SDS) lF lN EYES: Rinse cautiously with water for several minutes. Remove conlact lenses, if presenl and easy to do. Continue rinsing. lf eye irritatlon persists: Get medical advice/attention. lf skin initation or rash ocrurs: Get medical advice/attention. Wash coniaminated clothing before reuse. lF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. lF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. lF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink plenty of water. In case offire: Use CO2, dry chemical, or foam for extinction. Collect spillage.

Storage

Store in a well-ventilated olace. Keeo cool Conditions Keep out of the reach of children. Keep container tightly closed. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. Incompatible materials None known based on information supplied. Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. 2-Propanol STEL:400 ppm TWA:400 ppm IDLH: 2000 ppm 67-63-0 TWA: 200 ppm TWA:980 mg/m3 TWA:400 ppm^ (vacated) TWA: 400 ppm^ TWA: 980 mg/m" (vacated) TWA: 980 mg/m' STEL: 500 ppm (vacated) STEL: 500 ppm ^ STEL: 1225 mgtm3 (vacated) STEL: 1225 mslm' Hexylene Glycol Ceiling:25 ppm (vacated) Ceiling:25 ppm ^ Ceiling: 25 ppm ^ 107-41-5 (vacated) Ceilinq: 125 mq/m" Ceilino: 125 mo/m' 1-methoxy-2-propanol STEL: 100 ppm (vacated) TWA: 100 ppm^ TWA: 100 ppm- 107-98-2 TWA: 50 ppm (vacated) TWA: 360 mg/m' TWA: 360 mg/m' (vacated) STEL: 150 ppm^ STEL: 150 ppm^ (vacated) STEL: 540 mq/m" STEL: 540 mo/m' ATTOSH IDLH lmmediately Dangerous fo Life or Health

Precautionary statements

Disposal - Dispose of contents/container to an approved waste disposal plant

Further information

Unknown Acute Toxicity O% of the mixture consists of ingredient(s) of unknown toxicity Chemical Name CAS No. Weisht-% Trade Secret Sodium Dodecvlbenzene Sulfonate 25155-30-0 5-10 * Tetra ootassi um Pvrophosohate 7320-34-5 3-7 * 2-Hvdroxvbiphenvl 90-43-7 1-5 2-Propanol 67-63-0 1-5 Hexvlene Glvcol 107-41-5 1-5 1-methoxv-2-propanol 107-98-2 1-5 Trade Secret Proorietarv 1-5 * Oranoe Teroenes 5989-27-5 1-5 * First aid measures General advice lf symptoms persist, call a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. lf skin irritation persists, call a physician. Wash off immediately with soap and plenty of water. lmmediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes lf symptoms persist, call a physician lmmediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing lnhalation Remove to fresh air. lf symptoms persist, call a physician. lmmediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors or decomposition products. Ingestion Do NOT induce vomiting. Drink plenty of water. lmmediate medical attention is not required. Rinse mouth. Clean mouth with water and drink aftenvards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important svmptoms and effects. both acute and delaved Symptoms Any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of anv immediate medical attention and special treatment needed Note to physicians May cause sensitization of susceptible persons. Treat symptomatically. Suitable extinquishinq media Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam. Unsuitable extinquishinq media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arisinq from the chemical In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Keep product and empty container away from heat and sources of ignition. Risk of ignition. Protective equipment and precautions for firefiqhters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Personal orecautions. protective equipment and emerqencv procedures Personal precautions Use personal protective equipment as required. Avoid contact with eyes and skin. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. Envi ronmenta I orecautions Environmental precautions Prevent entry into watenrvays, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaninq up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. After cleaning, flush away traces with water. Prevent product from entering drains. Dam up. Take precautionary measures against static discharges. Precautions for safe handlinq Advice on safe handling Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Use with local exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heaUsparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/misUvapors/spray. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Gonditions for safe storage. includinq anv incompatibilities Density Lbs/Gal 9.2 VOC Content (%) 10.63 Reactivitv No data available Stability Stable under recommended storage conditions. Possibif ity ol Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Information on likelv routes of exposure lnhafation No data available. Eye contact Severely irritating to eyes. Skin Gontact May cause irritation. Ingestion May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 lnhalation LC50 Sodium Xylene Sulfonate = 1000 mg/kg ( Rat ) 1300-72-7 Sodium Dodecylbenzene Sulfonate = 438 mg/kg ( Rat = ) 500 mg/kg 251 55-30-0 Rat ) Tetrapotassium Pyrophosphate = 2980 mg/kg ( Rat ) > 4640 mg/kg ( Rabbit ) 7320-34-5 Ortho-Benzyl Para-Ch lorophenol = 1700 mg/kg ( Rat ) 120-32-1 2-Hydroxybiphenyl = 1049 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) > 0.949 mg/L ( Rat ) t h 90-43-7 2-Propanol = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m' ( Rat ) 4 h 67-63-0 Hexylene Glycol = 3692 mg/kg ( Rat ) = 8560 pl/kg ( Rabbit ) > 310 mg/m" ( Rat ) t h 107-41-5 1-methoxy-2-propanol = 7200 mg/kg (Rat) = 13000 mg/kg (Rabbit) = 7500 mgil (Rat) 6 h 107-98-2 FRAGRANCE = 4462 mg/kg ( Rat ) = 4308 mg/kg ( Rabbit ) = 300.56 mg/L ( Rat ) 4 h P292 Phenol, 4-(1, 1 -Dimethylpropyl)- = 1830 mgikg ( Rat ) = 2 glkg ( Rabbit ) 80-46-6 Benzenesulfonic Acid, > 2500 mg/kg ( Rat ) = 5 mg/m" ( Rat )4 h Decyl(sulfophenoxy)-, Disodium Salt 36445-71-3 Orange Terpenes = 440O mg/kg ( Rat ) > 5 g/kg ( Rabbit ) 5989-27-5 Sodium Sulfite = 3560 mg/kg ( Rat ) = 5500 mgim' ( Rat ) 4 h 7757-83-7 Tetrasodium EDTA = 10 g/kg ( Rat = ) 1658 mg/kg ( 64-02-8 Rat ) Sodium Hydroxyacetate = 7110 mg/kg ( Rat ) 2836-32-0 Trisodiu m nitri lotriacetate = 920 mg/kg ( Rat ) > 5 m g / L ( R a t ) 4 h 5064-31-3 lnformation on toxicoloqical effects Symptoms No lnformation available. Delaved and immediate effects as well as chronic effects from short and lonq-term exoosure lrritation MAY CAUSE SKIN IRRITATION. Sensitization No lnformation available. Germ cell mutagenici$r No Information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. 3hemical Name ACGIH IARC NTP

Remarks

Method pH 1 0 . 5 - 1 1 . 5 Specific Gravity 1 . 1 Viscosity Water Thin Melting point/freezing point No Information available Flash point 53 "C 127 0F Boiling point / boiling range No Information available Evaporation rate Same as water Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: No lnformation available Lower flammability limit: No Information available Vapor pressure No Information available Vapor density No Information available Water solubility Soluble in water Partition coefficient No Information available Autoignition temperature No lnformation available Decomposition tem peratu re No Information available

Aspiration hazard

No Information available. Numerical measures of toxicitv

Product information

Unknown Acute Toxicity Oo/o oI the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document Ecotoxicitv Ghemical Name Algae/aquatic plants Fish Crustacea Sodium Dodecylbenzene Sulfonate 10.8: 96 h Oncorhynchus mykiss 25155-30-0 mq/L LC50 static Tetrapotassium Pyrophosphate 100: 96 h Oncorhynchus mykiss 100: 48 h water flea mg/L EC50 7320-34-5 mo/L LC50 2-Hydroxybiphenyl 0.85:72 h Desmodesmus 3.4: 96 h Pimephales promelas 1 - 2.5:48 h Daphnia magna mg/L 90-43-7 subspicatus mg/L EC50 mgiL LC50 flow-through 2.74:96 h EC50 Static Lepomis macrochirus mg/L LC50 2.75: 96 h Oncorhynchus mykiss mg/L LC50 5.8: 96 h Poecilia reticulata mq/L LC50 static 2-Propanol 1000: 96 h Desmodesmus 9640 96 h Pimephales promelas 13299 48 h Daphnia magna mg/L 67-63-0 subspicatus mg/L EC50 1000 72 h mg/L LC50 flow{hrough 11130 96 EC50 Desmodesmus subspicatus mg/L h Pimephales promelas mg/L LC50 EC50 static 1400000: 96 h Lepomis macrochirus uq/L LC50 Hexylene Glycol 10500 - 11000 96 h Pimephales 2700 - 3700 48 h Daphnia magna 107-41-5 promelas mg/L LC50 flow-through mg/L EC50 10000: 96 h Lepomis macrochirus mg/L LC50 static 8690: 96 h Pimephales promelas mg/L LC50 flow{hrough 10700:96 h Pimephales promelas mg/L LC50 static 1-methoxy-2-propanol 20.8 96 h Pimephales promelas g/L 23300 48 h Daphnia magna mg/L 107-98-2 LC50 static 4600 - 10000: 96 h EC50 Leuciscus idus mo/L LC50 static Orange Terpenes 0.619 - 0.796: 96 h Pimephales 5989-27-5 promelas mg/L LC50 flow-through 35: 96 h Oncorhynchus mykiss mg/L LC50 Persistence and deqradabilitv No Information available. Bioaccumulation No lnformation available. 2-Hydroxybiphenyl 3 . 1 8 90-43-7 2-Propanol 0.05 67-63-0 Hexylene Glycol 0 . 1 4 10741-5 1-methoxy-2-propanol -0.437 107-98-2

Other hazards

This product is toxic to fish. Do not discharge effuent containing this product into lakes, streams, ponds, estuaries, oceans or other water unless in accordance with the requirments of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to the discharge. Do not discharge effuent containing this product to sewer systems withour previously notifying the local sewage treatment plant authority. For guidance, conatct your State water board or Regional office of the EPA. Waste treatment methods Disposal of wastes Pesticide wastes are acutely hazardous. lmproper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. lf these wastes can not be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. 70385-7 (containers equalto or less than 5 gallons) Container Disposal: Non-refillable container. Do Not reuse or refill this container. Triple rinse container (or equivalent) promptly after emptying. Triple rinse as follows: empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 114 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture and dispose of in sanitary landfill, or by incineration, or, if allowed by state and local authorites, by burning. lf burned, stay out of smoke. 70385-7 For non-refillable containers that only list household/residential uses: Container Disposal: Non-refillable container. Do not re-use or refill this container. Wrap (container) and put in trash or offer for recycling, if avialable. Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status 2-Propanol Toxic 67-63-0 lonitable Orange Terpenes Toxic 5989-27-5 Note: The basic description beiow is specific to the container size. This information is provided forat a glance DOT information. Please refer to the container endlor shipping papers for the appropriate shipping description before tendering this meterial for shipment- For additional information, please contact the distributor listed in section 1 of ihis SDS. U.S. Department of Transoortation IUSDOTI 4x1 Gallon Case Not regulated Pails & Drums (<l'19 Gallons) Not regulated lnternational Inventories TSCA Complies DSL/NDSL Complies 'SCA - Urited Statas loxic Substances Contol Act Section 8(b) lnventory DSLINDSL - Canadian Do|'lestic Subslances List/lvon-Domesrb Subsfarces Llst US Federal Reoulations SARA 313 Section 3'13 of Title lll of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporling requirements of the Act and Title 40 ofthe Code of Federal Regulalions, Part 372 Shemical Name SARA 313 - Threshold Values % 2-Hvdroxvbiohenvl - 90-43-7 2-Prooanol- 67-63-0 SARA 311/312 Hazard Gateqories

Acute Health Hazards

Yes

Health hazards

No Fire hazard Yes Reactive Hazard No Sudden release of pressure hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 cFR 122.42) Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Sodium Dodecylbenzene 1000 tb Sulfonate 25155-30-0

Hazardous Ingredients

RQs CERCLA/SARA RQ Reportable Quantitv (RQ) Sodium Dodecylbenzene Sulfonate 1000 lb RQ 1000 lb final RQ 251 55-30-0 RQ 454 ko final RQ US State Requlations