PYRIPROXYFEN 100EC

Hazard statements (CLP)

H227, H302, H304, H315, H320, H332, H335, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. R65, R20/22, R36/38, R50/53. Harmful May cause lung damage if swallowed. Harmful by inhalation and if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H227: Combustible liquid. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S2, S13, S20, S23, S38, S45, S46, S51, S61, S24/25, S36/37. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. When using, do not eat or drink. Do not breathe vapours or spray mists. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately (show this SDS where possible). If swallowed, contact a doctor or Poisons Information Centre immediately and show this SDS or label. Use only in well ventilated areas. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid contact with skin and eyes. Wear suitable protective clothing and gloves.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING

Prevention

P102: Keep out of reach of children. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Yellowish liquid. Odour: Characteristic odour.

Health hazards

harmful by inhalation and if swallowed, irritating to eyes and skin, skin irritant, if aspirated, may cause lung damage.

Potential health effects

Inhalation: Short Term Exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: Available data indicates that this product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.