Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10-<25% 5-<10%
General Information
Revision date
2024-03-29
Product name
19403-H - Rocathaan Hotspray PA 400 - Hardener
1.2.1 Relevant identified uses
Hardener for Hotspray . For professional users only
1.2.2. Uses advised against
All uses not specified in this section or in section 7.3
Emergency telephone
+31 (0) 85 78 200 20
Icons in SDS
Company Information
company name
Prokol Protective Coatings
e-mail address of the competent person responsible for the Safety Data Sheet
sds@prokol.nl
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
H317
May cause an allergic skin reaction
H319
Causes serious eye irritation
H332
Harmful if inhaled
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335
May cause respiratory irritation
H351
Suspected of causing cancer
H373
May cause damage to organs through prolonged or repeated exposure
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture GB CLP Regulation Classification of this product has been carried out in accordance with GB CLP Regulation Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335
2.2 Label elements
GB CLP Regulation: Danger
Hazard statements
Acute Tox. 4: H332 - Harmful if inhaled. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure (Inhalation). STOT SE 3: H335 - May cause respiratory irritation.
Precautionary statements
SECTION 2: HAZARDS IDENTIFICATION (continued) P201: Obtain special instructions before use. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.
Supplemental label elements
EUH204: Contains isocyanates. May produce an allergic reaction.
Hazardous Ingredients
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis [isocyanatobenzene]; Reaction mass of 4,4´- methylenediphenyl diisocyanate and o-(p- isocyanatobenzyl)phenyl isocyanate; 4,4´-methylenediphenyl diisocyanate; 4,4´-Methylenediphenyl diisocyanate, oligomers
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
Product does not meet PBT/vPvB criteria
2.1 Classification of the substance or mixture
GB CLP Regulation: Classification of this product has been carried out in accordance with GB CLP Regulation. Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335