19403-H - Rocathaan Hotspray PA 400 - Hardener

Prokol Protective Coatings

Revision date : 2024-03-29

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GHS08 GHS07
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

10-<25% 5-<10%

General Information

Revision date

2024-03-29

Product name

19403-H - Rocathaan Hotspray PA 400 - Hardener

1.2.1 Relevant identified uses

Hardener for Hotspray . For professional users only

1.2.2. Uses advised against

All uses not specified in this section or in section 7.3

Emergency telephone

+31 (0) 85 78 200 20

Icons in SDS

E011 E012 GHS07 GHS08 M008 M009 M013 M017 M026

Company Information

company name

Prokol Protective Coatings

e-mail address of the competent person responsible for the Safety Data Sheet

sds@prokol.nl

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

H317

May cause an allergic skin reaction

H319

Causes serious eye irritation

H332

Harmful if inhaled

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335

May cause respiratory irritation

H351

Suspected of causing cancer

H373

May cause damage to organs through prolonged or repeated exposure

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture GB CLP Regulation Classification of this product has been carried out in accordance with GB CLP Regulation Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335

2.2 Label elements

GB CLP Regulation: Danger

Hazard statements

Acute Tox. 4: H332 - Harmful if inhaled. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure (Inhalation). STOT SE 3: H335 - May cause respiratory irritation.

Precautionary statements

SECTION 2: HAZARDS IDENTIFICATION (continued) P201: Obtain special instructions before use. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.

Supplemental label elements

EUH204: Contains isocyanates. May produce an allergic reaction.

Hazardous Ingredients

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1'-methylenebis [isocyanatobenzene]; Reaction mass of 4,4´- methylenediphenyl diisocyanate and o-(p- isocyanatobenzyl)phenyl isocyanate; 4,4´-methylenediphenyl diisocyanate; 4,4´-Methylenediphenyl diisocyanate, oligomers

Additional information

As from 24 August 2023 adequate training is required before industrial or professional use.

2.3 Other hazards

Product does not meet PBT/vPvB criteria

2.1 Classification of the substance or mixture

GB CLP Regulation: Classification of this product has been carried out in accordance with GB CLP Regulation. Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335

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