Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
2.5-<5%
General Information
Revision date
2024-04-16
Product name
19251-H - Prokol MegaGrip S - Hardener
1.2.1 Relevant identified uses
Hardener for Hotspray . For professional users only
1.2.2. Uses advised against
All uses not specified in this section or in section 7.3
Emergency telephone
+31 (0) 85 78 200 20
Icons in SDS
Company Information
company name
Prokol Protective Coatings
e-mail address of the competent person responsible for the Safety Data Sheet
sds@prokol.nl
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567) Classification of this product has been carried out in accordance with GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567) Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335
2.2 Label elements
GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Danger
Hazard statements
Acute Tox. 4: H332 - Harmful if inhaled. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure (Inhalation). STOT SE 3: H335 - May cause respiratory irritation.
Precautionary statements
SECTION 2: HAZARDS IDENTIFICATION (continued) P201: Obtain special instructions before use. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.
Supplemental label elements
EUH204: Contains isocyanates. May produce an allergic reaction.
Hazardous Ingredients
Oxirane, methyl-, polymer with 1,1´-methylenebis[isocyanatobenzene], methyloxirane polymer with oxirane ether with oxybis[propanol] (2:1), and oxirane; 4,4´-methylenediphenyl diisocyanate; Reaction mass of 4,4´- methylenediphenyl diisocyanate and o-(p- isocyanatobenzyl)phenyl isocyanate
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
Product does not meet PBT/vPvB criteria
2.1 Classification of the substance or mixture
GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Classification of this product has been carried out in accordance with GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567). Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335