Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
5-<10%
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
2.5-<5%
General Information
Revision date
2024-03-29
Product name
11010 - Rocathaan Primer SG4
1.2.1 Relevant identified uses
1-component primer. For professional users only
1.2.2. Uses advised against
All uses not specified in this section or in section 7.3
Emergency telephone
+31 (0) 85 78 200 20
Icons in SDS
Company Information
company name
Prokol Protective Coatings
e-mail address of the competent person responsible for the Safety Data Sheet
sds@prokol.nl
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H304, H315, H317, H319, H332, H334, H335, H351, H373, H412
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture GB CLP Regulation Classification of this product has been carried out in accordance with GB CLP Regulation Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412 Asp. Tox. 1: Aspiration hazard, Category 1, H304 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Flam. Liq. 3: Flammable liquids, Category 3, H226 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Oral), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335
2.2 Label elements
GB CLP Regulation: Danger
Hazard statements
Acute Tox. 4: H332 - Harmful if inhaled. Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects. Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Flam. Liq. 3: H226 - Flammable liquid and vapour. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure (Inhalation). STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure. STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure (Oral). STOT SE 3: H335 - May cause respiratory irritation.
Precautionary statements
SECTION 2: HAZARDS IDENTIFICATION (continued) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P370+P378 In case of fire Use Foam extinguisher (AB), Dry Chemical Powder (ABC) Fire Extinguisher, Carbon dioxide extinguisher (BC) to extinguish. P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.
Supplemental label elements
EUH204: Contains isocyanates. May produce an allergic reaction.
Hazardous Ingredients
Xylene; Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.-hydro-.omega.-hydroxypoly(oxy (methyl-1,2-ethanediyl)]; 4,4´-methylenediphenyl diisocyanate, isomers and homologues; 4,4´- methylenediphenyl diisocyanate
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
Product does not meet PBT/vPvB criteria
2.1 Classification of the substance or mixture
GB CLP Regulation: Classification of this product has been carried out in accordance with GB CLP Regulation. Acute Tox. 4: Acute inhalation toxicity, Category 4, H332 Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412 Asp. Tox. 1: Aspiration hazard, Category 1, H304 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Flam. Liq. 3: Flammable liquids, Category 3, H226 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Inhalation), H373 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2, H373 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Oral), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335