sheet

Hazard statements (CLP)

H302, H314, H317, H318, H332, H334

Code

Statements

H302

Harmful if swallowed

2.2 Label elements

Persons Other product

Hazard statements

Notes diisocyanate P333 polymer | A isocyanates If classified skin Wear Avoid May May (EC-No.) (CAS-No.) (EC-No.) (CAS-No.) Identifier(s) H332. irritation protective breathing an may as cause cause Composition/information a develop respiratory allergic 212-485-8 822-06-0 500-060-2 28182-81-2 on vapours. skin CAS or Based rash gloves. ingredients cross-sensitisation irritation. §22-06-0 28182-81-2 the occurs: Nbr % <= reaction. 80- physical Get 0.2 medical 100 form, Acute Nota STOT Skin Resp. STOT Skin |Acute (EC) reaction SE Sens. No. exposure H330 H335 |3M™ to Section below Substance for | None pain. test hazard and

Response

P280E P261A

Prevention

H335 H317

SECTION 2: Hazards identification

mark) Ingredient Ingredients: Sealer,

Hazard pictograms

GHS07 ES-2000 WARNING. SIGNAL ‘[3M™ + on P313 WORD

Contains

PRECAUTIONARY (Exclamation Edge 3: a substance Part polymer to Inhalation other Inhalation Toxicity Inhalation Toxicity Part # its address 3 Sealer, if or Route not any specific agree Ecological components. phone either in - A | | | | | - | | | Activated Section substances Green Zebra nervous Green endocrine bladder immune Target repeated Organism respiratory Target ingredient the no heart blood liver blood kidney single based information on currently algae Fish algae | with number data sludge are that 12 system Organ(s) exposure is EU are listed and/or | irritation Experimental {Experimental Type UN SECTION adverse does in polymer information Persistence Endocrine Mobility treated FS-2000 Other material Results data of disposed completely treatment 13: available. not available. soil Bioaccumulative and & of the Edge authorities as product container

Storage

cleaning closed legs, authorities, of Collect appears with respiratory large measures self-contained, in the away prevent agents workplace. using up face bentonite, protection, positive as Store by but dry. Limit table much and mask, a do or type below, protection of this breathing the Safety not hygiene spills 2 and from (eg. qualified seal in an Data recommendations. acids. Avoid product. pressure and the spilled Remember, vermiculite, ventilation, practice. procedures protective or During During During release adding or See Contamination chlorine, Sheet. confined occupational Store with Wash authorised container material and Refer Section covering pressure chromic the as to spaces, to an away water Dispose personal for combustion. exposure from or for thoroughly possible. commercially provide 8 Additional limit exposure for 48 environment. after dust/fume/gas/mist/vapours/spray. acid collected to material protective absorbent sections other demand of person. air. etc.) hours exposed strong Ventilate Place available of areas breathing is If Page: Wash Do not the does this of avoid comments mechanical controls bases. handling. not material the ina available and contamination get pressure 4 head. ventilation | not of area equipment. SDS as inorganic 14 apparatus, with for | Applicable For Half a respirator of An Apron Apron use If Use gloves Applicable Polymer Butyl Material clothing. substance of None Eye/face Use 8.2. No or type(s) respiratory UK polymer protective is tested laminate Note: your Engineering of this Inspect./Ministry Recommended limit Gloves isocyanates results Select 8.2.2. Limits 8.2.1. questions facepiece CEIL STEL TWA exposure Respiratory Free product |3M™ full Polyethylene rubber. made with or an exposure required. Personal and/or general Consult Exposure biological Ceiling UK ES-2000 HSC - — and Skin/hand Biological Short use Term assessment protection about to the Nitrile glove exposure gloves protection from controls (IE) values Exposure and limit Health full Polyethylene assessment. used mixture, to protection control dilution Edge Norms/Standards reduce laminate The coveralls a Norms/Standards and/or protective values Time-Weighted-Average Safety facepiece Sealer, may gloves and/or frequency in EN ventilation exist suitability protection may 374 controls monitoring Limit be for program. needed be manner that following be protective assessment. protective equipment and/or any Commission inhalation Part following may and for a specific air-purifying A necessary. No No No material(s) worn duration, Selection local of $22-06-0 exposure: Based to protective presents clothing (PPE) the decide a Thickness over clothing should data data data are exhaust application, respirator the Select higher on physical be procedures:Information UK clothing and available available available (mm) polymer if approved dust/fume/gas/mist/vapours/spray. on components a suitable results use consult recommended: respirator based to ventilation If HSC such ventilation recommended of on potential for manufacturer body with listed the is material(s) for to laminate for challenges use relevant in organic required. gloves as factors local control protection exposure Section mg/m3 to selection TWA(as your 3 are No No No is exposure data data data respirator not vapours (eg. Breakthrough recommended: airborne available available available monitoring improve temperature standards adequate, this mg/m3;STEL(as If such to of a of assessment, respirator prevent Time as and spraying, appropriate exposure manufacturer. particulates exposures high levels, skin to NCO):0.02 select use — contact Apron safety dexterity. extremes, prevent procedures data NCO):0.07 is from needed, Buty] based and respiratory below sheet. to can splash compatible be the use following other on respirators contact potential concentration based rubber the protection use relevant obtained Respiratory Page: results of on from 5 as of etc.), gloves/protective the Exposure of conditions. part an then equipment. Indust. Sensitizer 14 Strong Strong Strong | Water 10.5 Stable. Heat. 10.4 Hazardous 10.3 10.2 material This 10.1 9.2.2 Percent Other 9.2. Other Density Water Flash 9.1. Odour Odor Use |3Mr ' | EU pH volatile oxidising bases. acids. Incompatible Conditions Vapor Possibility Chemical M Reactivity Decomposition SECTION Flammability Molecular Evaporation Volatile state Relative Relative Partition Solubility- Kinematic Autoignition point Flammable Flammable Boiling Melting Colour Specific Physical Information SECTION respirator a ES-2000 may avoid polymerisation stability Organic information coefficient: non-water Viscosity to of point/boiling Physical 9: safety agents. 10: weight rate density solubility be threshold on Edge Stability characteristics materials temperature hazardous range reactive to Density Part (solid, point/freezing basic conforming Sealer, occur. reactions Compounds physical may Physical EN Limits(UEL) Limits(LEL) gas) Form: n-octanol/water with point certain A and 140 or agents chemical 136: EN under reactivity chemical filter certain properties types No No No 2.3 A conditions data data data 1.16 1.16 & g/l Flash No No Not 203 No No No Pale available. No No properties Appreciable P Yellow Paste data g/l data data data data data °C data data Liquid. - see [Ref point Odourless available. available. available. 34,482.7586206897 available. the Std: applicable. > remaining [Derails: 93 WATER=1] mm2/sec °C (200 headings CONDITIONS: °F) in this Reacts] Page: section 6 of 14 ‘| | Overall Name Acute the a If Persons hexamethylene-di-isocyanate hexamethylene-di-isocyanate diisocyanate Contact Eye diisocyanate Additional sufficient Ingestion contact information: irritation: data Toxicity not component previously Gastrointestinal product Toxicological with is the Data eyes disclosed sensitised during polymer polymer polymer for section product in classification. but isocyanates Signs/symptoms to 3 use not is does may Inhalation- abdominal result develop include not expected appear a to (4 hours) Dust/Mist Dermal Ingestion Dermal (4 hours) Dust/Mist Ingestion Dermal Route in cross-sensitisation significant a table in stomach Rat Rat Rat Rabbit judgeme nal Professio Species below, pain, nt | No No either LCSO LD50 LD50 LD50 reaction upset, LC5O irritation. Value > > > data estimated no available; 0.124 7,000 5,000 5.000 data to mgf to ma/ke me/ke mg‘ke are other nausea, calculated available be 1 - 5 mg/l vomiting ATE for isocyanates. and >5,000 that Page: endpoint diarrhoea. mg/kg 7 of or 14 Refer on and 10.6 internal

2.1 Classification of the substance or mixture

H317 H334 H317 H332 [CLP] to not is Page: Regulation expected. <=0.2 80- 2 % of by 14 Wt 100 5.2. DO 5.1. | Not 4.3. No 4.2. get Eye Closed If Rinse NOT Flush SECTION applicable Indication Hazardous mouth. swallowed Special medical with contact critical Most Carbon Substance containers USE Extinguishing large Decomposition to arising hazards WATER 5: symptoms important attention. of If any you monoxide exposed media feel amounts heat case effects. symptoms or In or of from immediate unwell, and get of from the See Fire-fighting water. fire: By-Products fire medical Section Use effects, medical may substance Remove 11.1, both a build carbon measures attention contact or pressure dioxide information and and acute attention. mixture lenses if delayed or and special on dry easy explode. treatment chemical todo. toxicological During Condition required effects. Continue extinguisher rinsing. combustion. to If extinguish. Page: signs/symptoms persist, 3 of 14 Please |3M™ get Immediately contact applicable Mixtures Inhalation Ingredient see Specific person Description [SECTION information ES-2000 First medical wash of 4: on Sealer, Edge to section 16 first for with fresh Limits Concentration Part soap aid air. the attention. ingredient and aid If full you text measures A water. feel of occupational any unwell, measures Remove H exposure get (EC-No.) (CAS-No.) statements medical limits Identifier(s) or attention. or contaminated PBT 212-485-8 822-06-0 referred to clothing VPvB and this in wash see Status, >= >= Specific section (C (C before 0.5%) 0.5%) Eye Skin Acute sections Skin Resp. Tox. reuse. Dam. Corr. 1C, 4, 1, and Sens. Concentration H318 8 H314 H302 SDS If 1A, 1A, signs/symptoms H317 Limits 12 of this H334 | for Ifa 8.1 Ingredient | component Occupational See 7.3. Control Specific in away suspected, contaminated Contaminated on use is a absorbent Store 7.2. information disperse Do 7.1, 6.4. full Advice | 6.3. 6.2. to 6.1. the | Refer soon fresh 5.3. personal eyes, not remove Avoid SECTION Wear information |3M™ Conditions component. in SECTION Reference Read protection in from Methods as release area. Personal possible. Clean to bunker to and for Oxides Carbon a air. build-up. container Working Evacuate coat from skin, Precautions Section in SECTION do ES-2000 a disclosed exposure parameters Section use(s) oxidising reseal well-ventilated safe or confined other is for Mix end regarding exhaust Ventilate pants, dioxide. 8: not work or 8 to for and approved physical, material. of Hydrogen clothing for 7: up the Environmental 6: protective Edge on and around safe follow health, the limits 7.1 place. clothing. Section Exposure or agents. storage physical vapours, the Handling bands sections clothing, fire-fighters safety with edges for environment. precautions in Part before clothing area residue material precautions, nitrogen. cyanide. Sealer, section recommendations. container. reuse. should Do handling an transportation sufficient of and area and Accidental around with 13 Nbr Store including Avoid be in minimal more CAS precautions environmental spill containment health accordance fresh Keep 7.2 not arms, for the with protective including A 3 but for not and by handling away container contact allowed drink inward, hazards, with air. equipment waist eat, storage appropriate hazard. until and air absorbent = does any on appropriate release helmet, not to incompatibilities the oxidising when Avoid and appear label selected indusirial spill, tightly emergency with exchange. solvent cover good For and Agency

Classifications

include during based in are EU redness, localised components, information products material on swelling, include this swelling, may (EC) are redness, blistering, nasal mandated in combustion. sneezing, material No Condition GHS may itching, difficulty and a Section

PBT Substances

and 822-06-0 cured effects disrupting Cas CAS 822-06-0 Sealer, of processes. in (or methods hazardous substances/mixtures/preparations permitted accordance properties a 28182-81-2 No. 822-06-0 or 822-06-0 28182-81-2 any Empty as for Study BOD Study an and a Log

Disposal

in Part Nbr N/A industrial endocrine 21 72 48 96 Hydrelytic Hydrolytic 3 Kow days hours by or transporting N/A Non-standard _jtest OECD Non-standard 4.2 Non-standard 10 27 71 mg/l 842 14.8 of considered, chemicals alternative, Page: Consult effects method Closed method - with additional 10 the bottle of fuel 14 | ADR 14.7 user 14.6 14.5 14.4 | 14.3 namie 14.2 Not 14.1 EU and 3M, The 08 [3M™ Control arpol Emergency class(es) 04 waste complied 080501* waste coding Transport no according Transport UN proper UN number Tunnel 73/78 amendments) Packing hazardous SECTION code with of ES-2000 09* to Special and Code Environmental a group for and Edge code(s) waste Annex in Temperature IBC II to 14: bulk

vPvB Substances

degradability to any potential A determine polymerized) substances assessment Estimated not Estimated Hydrolysis Experimental Hydrolysis Experimental flea Activated flea classified material Bioconcentration for Data Test available Test Water Green Water Medaka Green the wastes waste insufficient type Algae with that Biodegradation sludge available drums/barrels/containers incineration a considerations unless as |N/A the 28 are facilities. local/regional/national/intemational disruptor 0.02 N/A in |7.7 Duration 28 {Experimental treatment otherwise Hazardous used facility. permitted assessed days Estimated to be defined per Proper Type applicable destruction waste half-life applicable and waste facility. minutes hours may |5 1 Test 82% 1/2) % 1/2) Test ECS50 NOEC ECS50 EC50 LC50 regulations. handling weight regulations) require a for result As BOD/ThBOD (t environmental (t |Protocol 301D |Protocol mg/l regulations. be shall hazardous use

Precautionary statements

Waste Waste (product always assign Category for Code Sealer, Temperature shipping as stream of Transportation Code for waste use the Part further ections Please (ADR) isocyanates licensed correct after sold) products A is | a transportation. INo No adhesives No based data and on Ground use of refer available. information. SDS the available. waste available. the sealants available. code to the will to information be containing provided. other for Transport contractor. your application of waste the Data information. Sections Please refer Data No Data No Not Data No stream. No product No Air organic Please Applicable to Transport refer Ensure the of Available by Available SDS the Available the to solvents the or other for (IATA) national European consumer. other further dangerous and/or Waste Since further sections Please No (IMDG) No Marine No regional Code No this Data is Data out Page: Available information. SDS the Available Transport refer regulations of substances (EWC of the to - the 2000/532/EC other for 11 are control of 14 Section Section Section Section Section Section Section Section Section Section Section Section Section Section Revision CLP: EU H335 H334 H332 H330 H318 H317 H314 H302 09: 04 03 03 9: 9: 9: 03: 5: 1: 5: Section 3: Kinematic Explosive Evaporation Hazardous Fire Information table table Emergency 09: information: Odor Melting Color - SCL Ingredient Mixture pH point not Composition/