Second Nature Shades, Luminize Gentle Conditioning Lightener, Lasting Color

Physical hazards

OSHA Hazards Flammable. Section V -~ Reactivity Data Stability: Stable. Conditions to Avoid: Heat and sunlight. Incompatibility (Materials to Avoid): Acids. Hazardous Decomposition or ByProducts: None. Section Vi- Health Hazards and Hazard Data The TLV of the mixture has not been established. 1. Effects of Acute Accidental Exposure Eye Contact: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide),the mixture may cause severe irritation and possible permanent eye injury. Skin Contact: May cause skin irritation or sensitization in sensitized individuals. Inhalation: Inhalation of ammonia vapors may result in respiratory irritation. Ingestion: Moderately toxic. 2. Effects of Chronic Exposure A composite mixture of these products has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. 3. Carcinogen Status: OSHA: No NTP: No IARC: No None. Section V - Reactivity Data Stability: Stable. Conditions to Avoid: None. Incompatibility (Materials to Avoid): Not applicable. Hazardous Decomposition or By Products: None. Section VI - Health Hazards and Hazard Data The TLV of the mixture has not been established. 1. Effects of Acute Accidental Exposure Eye Contact: Potential eye irritant. Skin Contact: Non-irritating. Inhalation: Not applicable. Ingestion: Practically non toxic. 2. Effects of Chronic Exposure For purposes of chronic exposure under the OSHA Hazard Communication Standard, this is an untested mixture. These products have been used extensively by consumers and Beauty Care is not aware of any significant adverse effects. Target Organs: These products contain ingredients which have been shown to affect tissues or organs when fed at high levels of exposure in animal studies not encountered in normal use. Target Organs identified in animal studies are as follows Propylene Glycol CNS; Section VI — Health Hazards and Hazard Data (Continued) 3. Carcinogen Status: OSHA: No NTP: No IARC: No None. Section V - Reactivity Data Stability: Unstable. Conditions to Avoid: Heat and sunlight. Incompatibility (Materials to Avoid): Reducing agents; such as waving lotions; heavy metals and many many flammables. Do not use metallic bowls or stirrers. Hazardous Decomposition or By Products: Oxygen. Section VI - Health Hazards and Hazard Data The TLV of the mixture has not been established. 1. Effects of Acute Accidental Exposure Eye Contact: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. Skin Contact: Prolonged contact with skin may bleach it and cause burns. Inhalation: Not likely to be inhaled. Ingestion: Moderately toxic. 2. Effects of Chronic Exposure When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin. 3. Carcinogen Status: OSHA: No NTP: No IARC: No

Principle Routes of Exposure

Inhalation: Yes Ingestion: Yes Skin: Yes 5. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. 6. Emergency and First Aid Procedures Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center. as Section VN - Precautions for Safe Nandiing and oe oo de Lise Steps to be taken in Case Material is released or Spilled: Contain spill and promptly clean up. Flush with water and wipe with towel or rinse to drain. Floor can be slippery when wet. Waste Disposal Method: Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA (40 CFR 261.21(a) (1) ). Additionally, disposal should be in accordance with all applicable Local, State and Federal Regulations. Precautions to be Taken in Handling and Storage: Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. Ventilation: Exhaust system ventilation should be adequate to avoid buildup of vapors. Hand Protection: Use impervious gloves to avoid possible skin irritation/sensitization. Eye Protection: Avoid contact with eyes. Use protective eyewear, if splashing is possible. Other Types of Protection: Not applicable. Respiratory Protection: Avoid inhalation. Work Hygienic Practices: Always follow good hygienic work practices. Avoid all skin, eye, and clothing contact with products. In case of contact, rinse thoroughly with water. Promptly clean up all spills. secbiopas GY Wace ose ees oben ties if on GCHON GA fos Fon ores ations = PFS SDOMSTON ITOrnianon DOT Class: Consumer IMDG: Isopropyl! Alcohol, IATA/ICAO: Consumer Commodity ORM-D 3.2, UN1219 Limited Commodity Class: Quantity 9, ID 8000 Packing Instruction 910 Material Safety Data Sheet MSDS: 00008 Status: Date: Approved 12/20/2002 Clairol, A Division of P&G One Blachley Road Stamford, CT 06922 Emergency Telephone Number: Transportation Emergency: (203) 357-5678 Call Chemtrec 1-800-424-9300 This sheet has been prepared in accordance with the Requirements of the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Section | - Categorization Category: Conditioners. Pertinent Text: Fragranced emulsions designed to enhance the appearance and feel of hair, increase hair body or suppleness, facilitate styling, improve gloss or sheen and improve the texture of hair. Product Names:Color ProTec Conditioner and Balm, L'lmage Conditioner, Loving Care Conditioner, Herbal Essences Hair Color After-Treatment, Miss Clairol Revitalizing Treatment, Motif Conditioner, Natural Instincts Treatment & Conditioner, Nice 'N Easy Conditioner, Revitalique Conditioner, Shimmer Lights Conditioner, Summer Blonde After Sun Conditioner, Textures & Tones Conditioner, Ultress Conditioner, Maxi Blonde Conditioner, Lasting Color Conditioner, Infusium 23 Pro-Vitamin Treatment in Frost & Tip, Shimmer Lights Conditioner Section Il — Ingredients Conditioners generally contain the following hazardous ingredients (1% concentration or greater; 0.1% for carcinogens): CPP A NAME CASE PROPYLENE GLYCOL 57556 GLYCERIN 56815 STEARALKONIUM CHLORIDE 122190 CETEARYL ALCOHOL 67762270 ACETAMIDE MEA 142267 CETYL ALCOHOL 36653824 POLYSORBATE 20 9005645 SORBITOL 50704 CETYL ALCOHOL 36653824 MINERAL OIL 8012951 CETYL ESTERS 8002231 STEARYL ALCOHOL 112925 DICETYLDIMONIUM CHLORIDE 1812539 GLYCERYL STEARATE 31566311 PEG-40 STEARATE 9004993G GLYCOL STEARATE 111604 AMODIMETHICONE 977091647 CETRIMONIUM CHLORIDE 112027 QUATERNIUM- 18 61789808 MYRISTYL MYRISTATE 3234853 DISODIUM WHEATGERMAMPHODIACETATE 977169304 LINOLEAMIDOPROPYL DIMETHYLAMINE DIMER DILINOLEATE 125804106 Section Il — Ingredients (Continued) CYCLOMETHICONE 69430246 TRIMETHYLSILYLAMODIMETHICONE 977088826 CYCLOPENTASILOXANE 541026 DIMETHICONE 9006659 BEHENTRIMONIUM CHLORIDE 17301530 SODIUM COCOAMPHOPROPIONATE 68988636 CETEARETH-20 68439496 OLEYL ALCOHOL 143282 POLYQUATERNIUM-11 53633548 POLYQUATERNIUM-7 26590056 STEARAMIDOPROPYL DIMETHYLAMINE 16889148 Section Ill - Physical/Chemical Characteristics Specific Gravity (H2O=1): 0.8-1.15 pH: N/A Solubility in Water: Poor. Dispersible in water. Inhalation: No Ingestion: Yes Skin: Yes 5. Pre-existing dermatitis would likely be made worse by exposure to these products. 6. Emergency and First Aid Procedures Eye Contact: Remove contact lenses, if used. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin reaction develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center. Section VII - Precautions for Safe Handling and Use Steps to be taken in Case Material is Released or Spilled: Contain spill and promptly cleanup. Flush with copious amounts of water until floor is not slippery. Waste Disposal Method: Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. Precautions to be Taken in Handling and Storage: None. Section Vill - Control Measures Ventilation: Exhaust system ventilation should be adequate to avoid buildup of vapors. Hand Protection: Use impervious gloves to avoid possible skin reaction. Eye Protection: Avoid contact with eyes. Use protective eyewear, if splashing is possible. Other Types of Protection: Not applicable. Respiratory Protection: Avoid inhalation. Work Hygienic Practices: Always follow good hygienic work practices. Avoid all eye, clothing and prolonged skin contact with products. In case of contact, rinse thoroughly with water. Promptly clean up all spills. Section IX - Transportation Information DOT Class: Not regulated. IMDG: Not regulated. IATA/ICAO: Not regulated. Material Safety Data Sheet MSDS: 00004 Status: Date: Approved 12/20/2002 Clairol, A Division of P&G One Blachley Road Stamford, CT 06922 Emergency Telephone Number: Transportation Emergency: (203) 357-5678 Call Chemtrec 1-800-424-9300 This sheet has been prepared in accordance with the Requirements of the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Section | - Categorization Category: Peroxides (Ten (10) and Twenty (20) Volume Developers). Pertinent Text: VWater-like or white emulsions containing 3% or 6% levels of hydrogen peroxide, emulsifying waxes and OH buffer. Product Names: A Touch of Sun, Balsam Color Developing Lotion for all Shades except Shades 598 and 599 (See MSDS Inhalation: No Ingestion: Yes Skin: Yes 5. Pre-existing dermatitis would likely be made worse by exposure to these products. 6. Emergency and First Aid Procedures Eye Contact: Remove contact lenses, if used. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If irritation develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center. TRADE MSDS #4 Page 20f Section VII - Precautions for Safe Handling and Use Steps to be taken in Case Material is released or Spilled: Contain spill and promptly clean up. Flush with water and wipe with towel or rinse to drain. Floor can be slippery when wet. Waste Disposal Method: Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. Precautions to be Taken in Handling and Storage: Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat, sparks and flame. Do not store any tint, lightener lotion or bleach powder after it has been mixed with developer; the container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. Section VIII - Control Measures Ventilation: Exhaust system ventilation should be adequate to avoid buildup of vapors. Hand Protection: Use impervious gloves to avoid possible skin irritation. Eye Protection: Avoid contact with eyes. Use protective eyewear, if splashing is possible. Other Types of Protection: Not applicable. Respiratory Protection: Avoid inhalation. Work Hygienic Practices: Always follow good hygienic work practices. Avoid all skin, eye, and clothing contact with products. In case of contact, rinse thoroughly with water. Promptly clean up all spills. Section IX

Appearance/Odor

Mild fragranced liquids, cremes, pourable emulsions Section IV - Fire and Explosion Hazard Data Flashpoint: N/A Unit: N/A Type: Not applicable. Method: Not applicable. Fire Fighting Procedures: Extinguish fires with ABC all-purpose extinguisher. The type of extinguisher used should be in conformance with local fire regulations. Fire fighters should use self contained breathing apparatus in enclosed areas. Unusual Fire and Explosion Hazards: None. Clear-water-thin liquids or viscous creamy white and bluish emulsion. Faint fragrance or no odor Section IV - Fire and Explosion Hazard Data Flashpoint: Non combustible. Unit: N/A Type: Not applicable. Method: Not applicable. Fire Fighting Procedures: Extinguish fires with ABC all-purpose extinguisher. The type of extinguisher used should be in conformance with local fire regulations. Fire fighters should use self contained breathing apparatus in enclosed areas. Unusual Fire and Explosion Hazards: Decomposition, which may be caused by heat or combustion, will release oxygen which will increase the explosive limit range and burning rate of flammable vapors.