Note: Ingredients listed on restricted chemical lists
EC/CAS
68909-20-6
Name of the chemical
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica
Concentration
7732-18- >50 53633-54 <3 174761-16 <3 7732-18- <50 100%
General Information
Revision date
2017-01-04
Product name
Refer to individual company listing (annex II)
CAS No.
68909-20-6
Icons in SDS
Company Information
company name
Lakmé Cosmetics S.L.
Section 2
Health hazards
Information Acute: Swallowed: Chronic: Eye: First Aid: Skin: Inhaled: Precautions for Use: Exposure standards: Engineering controls: Personal protection: Flammability: Safe Handling Information Storage and transport: Spills and disposal: Fire/explosion hazard:
Further information
The name, address and emergency telephone number of the Spanish manufacturer or supplier - What is the name of the product? - What does it look like? - Does it smell? - What does it contain? - What may happen if too much of the product is: Breathed in? Gets into eyes? Gets into skin? Swallowed? - What should I do if someone is over exposed? - Are there special handling Solutions containing hydrogen peroxide and bleach powders may sometimes produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie. aluminium as in glitter sprays or other forms). Should this occur, remove mixture from the hair by rinsing at the basin! PEROXIDE SOLUTIONS 7 – 12% MATERIAL SAFETY DATA SHEET NO. 1 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 2984 DANGEROUS GOOD CLASS: 5.1 (> 8%) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Low viscosity cream BOILING POINT: >35 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.02 – 1.05g/mL FLAMMABILITY LIMITS: not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Hydrogen peroxide 7722 – 84 – 1 7 to 12 Other ingredients determined not to be hazardous to 100 18 Date: 04/01/2017 HEALTH HAZARD INFORMATION Solutions containing hydrogen peroxide and bleach powders may sometimes produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie. aluminium as in glitter sprays or other forms). Should this occur, remove mixture from the hair by rinsing at the basin! BLEACH PRODUCTS MATERIAL SAFETY DATA SHEET NO. 2 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Mixed with solutions containing hydrogen peroxide to bleach/lighten the colour of the hair. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Fine to granular powder. BOILING POINT: Not applicable. FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: Not determined FLAMMABILITY LIMITS Not determined pH 9.0 – 10.0 (when mixed) SOLUBILITY IN WATER: Miscible with water. INGREDIENTS CAS No. % w/w content Potassium persulfate 7727 - 21 -1 20 – 45 Ammonium persulfate 7727 - 54 – 0 10 – 20 21 Date: 04/01/2017 Sodium persulfate 7775 - 27 - 1 1 – 5 Silica 7631 - 86 – 9 2 – 10 112945 - 52 – 5 Sodium metasilicate 6834 - 92 - 0 5 - 10 Other ingredients determined not to be hazardous to 100 HEALTH HAZARD INFORMATION 23 Date: 04/01/2017 • Mixtures of bleach powders and solutions containing hydrogen peroxide (6, 9 and 12%) may produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie aluminium as in glitter sprays or other forms). Should a reaction occur, remove mixture from the hair by rinsing at the basin! • Do not mix with perm lotions. • Skin sensitivity test: follow manufacturer’s instructions. • Added heat during application: follow manufacturer’s instructions. PEROXIDE SOLUTIONS 3 - 6% MATERIAL SAFETY DATA SHEET NO. 3 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Low viscosity cream BOILING POINT: >35 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.02 – 1.05g/mL FLAMMABILITY LIMITS: Not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Hydrogen peroxide 7722 – 84 – 1 3 to 6 Other ingredients determined not to be hazardous to 100 24 Date: 04/01/2017 HEALTH HAZARD INFORMATION ALKALINE PERMS & RELAXERS MATERIAL SAFETY DATA SHEET NO. 4 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Permanent waving of the hair MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Liquid with characteristic odour BOILING POINT: Not applicable. FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 1.03 – 1.05g/ml FLAMMABILITY LIMITS: Not flammable pH: 8 – 9.5 (when mixed) SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Ammonia 7664 - 41 – 7 1 – 3 27 Date: 04/01/2017 Tioglicolic acid 68 - 11 - 1 7 - 10 Other ingredients determined not to be hazardous to 100 HEALTH HAZARD INFORMATION Do not mix with hydrogen peroxide (3, 6, 9 or 12%) solutions or bleach powders. 29 Date: 04/01/2017 HAIR COLOUR (Semipermanent Cream) MATERIAL SAFETY DATA SHEET NO. 5 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair Colour MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Creamy soft mass BOILING POINT: Not Determined FLASH POINT: Not flammable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:0.98- 1.0g/mL FLAMMABILITY LIMITS: Not Applicable pH: 9.0 – 11.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content 30 Date: 04/01/2017 Toluene-2,5-Diamine Sulfate 615 – 50 - 9 < 5 Resorcinol 108 – 46 - 3 < 2 Phenylendiamines < 2 Aminophenols < 2 Ethanolamine 141 - 43 - 5 <10 Other ingredients determined not to be hazardous to 100 HEALTH HAZARD INFORMATION HAIR COLOUR (Permanent Cream) MATERIAL SAFETY DATA SHEET NO. 6 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair Colour MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Creamy soft mass with ammonia odour BOILING POINT: Not Determined FLASH POINT: Not flammable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:0.98- 1.0g/mL FLAMMABILITY LIMITS: Not Applicable pH: 10.0 - 11.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content 33 Date: 04/01/2017 Ammonia 7664 – 41 –7 < 5 Toluene-2,5-Diamine Sulfate 615 – 50 - 9 < 5 Resorcinol 108 – 46 - 3 < 2 Phenylendiamines < 2 Aminophenols < 2 Other ingredients determined not to be hazardous to 100 HEALTH HAZARD INFORMATION 36 Date: 04/01/2017 HAIRSPRAYS/LACQUERS (AEROSOLS) MATERIAL SAFETY DATA SHEET NO. 7 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 1950 DANGEROUS GOOD CLASS: 2 PRODUCT USE: Hair styling preparation. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Clear liquid BOILING POINT: Not determined FLASH POINT: Not applicable VAPOUR PRESSURE: 275 – 345 KPa SPECIFIC GRAVITY: 0.86 – 0.90g/ml FLAMMABILITY LIMITS: 1.9 – 9.5 pH: 6.0 – 8.5 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Hydrocarbon propellant (LPG) 37 Date: 04/01/2017 - Propane 74 - 98 - 6 30 – 50 - Isobutane 75 - 28 -5 Dimethyl ether 115 - 10 - 6 30 – 40 Ethyl alcohol 64 - 17 - 5 40 - 65 Other ingredients determined not to be hazardous to 100 HEALTH HAZARD INFORMATION 39 Date: 04/01/2017 AEROSOLS MOUSSE (STYLING & CONDITIONING) MATERIAL SAFETY DATA SHEET NO. 8 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 1950 DANGEROUS GOOD CLASS: 9 PRODUCT USE: Hair styling/conditioning preparation. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: White foam BOILING POINT: Not determined FLASH POINT: - 87ºC VAPOUR PRESSURE: 448 – 517 KPa SPECIFIC GRAVITY: 0.88 – 0.74g/ml FLAMMABILITY LIMITS: 1.9 – 9.5% pH: 4.0 – 7.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Hydrocarbon propellant (LPG) - Propane 74 - 98 - 6 1 - 5 - Isobutane 75 - 28 -5 1 - 5 Ethyl alcohol 64 - 17 - 5 <20 Other ingredients determined not to be hazardous to 100 40 Date: 04/01/2017 HEALTH HAZARD INFORMATION 42 Date: 04/01/2017 SHAMPOOS MATERIAL SAFETY DATA SHEET NO. 9 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To cleanse hair and scalp. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Viscous liquid BOILING POINT: Approx. 100 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.0 - 1.10g/mL FLAMMABILITY LIMITS Not Combustible pH 4. – 7.5 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Anionic and amphoteric surfactants such as: Sodium laureth sulphate 9004 - 82 - 4 6 –12% 1335 – 72 - 4 Cocamido propyl betain 61789 – 40 – 0 1 – 5% Coco Glucoside 141464 – 42 - 8 1 – 3 % Other ingredients determined not to be hazardous to 100 43 Date: 04/01/2017 HEALTH HAZARD INFORMATION 45 Date: 04/01/2017 CONDITIONERS, MASKS & TREATMENTS MATERIAL SAFETY DATA SHEET NO. 10 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To condition and beautify hair after cleansing. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Viscous liquid BOILING POINT: Approx. 100ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: 0.88 – 0.74g/ml FLAMMABILITY LIMITS Not combustible pH 3.5 – 5.5 SOLUBILITY IN WATER: Miscible INGREDIENTS CAS No. % w/w content Cationic surfactants such as: Certrimonium chloride 112 - 02 – 7 <3 Behentrimonium chloride 17301 - 53 – 0 < 3 Other ingredients determined not to be hazardous to 100 46 Date: 04/01/2017 HEALTH HAZARD INFORMATION HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Eye contact may cause some stinging and tears. Transient reddening of the eye may also occur. Skin: No appreciable irritation is expected by this route but however, prolonged repeated skin contact should be avoided. Inhaled: No appreciable irritation is expected by this route. CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two glasses of water and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor if pain persists. Skin: Remove contaminated clothing and wash affected area with water. Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. For prolonged use gloves are advised. Eyes: No protection need. Flammability:Product is not flammable.. 47 Date: 04/01/2017 SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place. TRANSPORT: SPILL AND Spills are slippery. Remove possible leaking containers. Mop up DISPOSAL: small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. FIRE / Will not burn. Not considered a significant risk. EXPLOSION HAZARD: ECOLOGICAL IMFORMATION Large quantities should not be discharged into waterways to prevent pollution of the waterways. TOXICOLOGICAL INFORMATION Medical Conditions Generally Aggravated by Exposure: None known. OTHER INFORMATION 48 Date: 04/01/2017 HAIR CARE PREPARATIONS (STYLING GEL, HAIR CARE LIQUID PRODUCTS) MATERIAL SAFETY DATA SHEET NO. 11 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair care and styling. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Viscous liquid, gel or wax. BOILING POINT: Approx. 100ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: 0.88 – 0.74g/ml FLAMMABILITY LIMITS Not combustible pH 4.0 – 8.0 SOLUBILITY IN WATER: Miscible INGREDIENTS CAS No. % w/w content Liquids: - Water 7732 - 18 - 5 >50 Gels and waxes: - Polyquaternium - 11 53633 - 54 – 8 <3 - Polyquaternium – 46 174761 - 16 – 1 <3 - Water 7732 - 18 - 5 < 50 Other ingredients determined not to be hazardous to 100 49 Date: 04/01/2017 HEALTH HAZARD INFORMATION HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Eye contact may cause some stinging and tears. Transient reddening of the eye may also occur. Skin: No appreciable irritation is expected by this route but however, prolonged repeated skin contact should be avoided. Inhaled: No appreciable irritation is expected by this route. CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two glasses of water and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor if pain persists. Skin: Remove contaminated clothing and wash affected area with water. Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. Eyes: No protection need. Flammability:Product is not flammable. 50 Date: 04/01/2017 SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place. TRANSPORT: SPILL AND Spills are slippery. Remove possible leaking containers. Mop up DISPOSAL: small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. FIRE / Will not burn. Not considered a significant risk. EXPLOSION HAZARD: ECOLOGICAL IMFORMATION Large quantities should not be discharged into waterways to prevent pollution of the waterways. TOXICOLOGICAL INFORMATION Medical Conditions Generally Aggravated by Exposure: None known. OTHER INFORMATION 51 Date: 04/01/2017 HAIR CARE PREPARATIONS (STYLING POWDER PRODUCTS) MATERIAL SAFETY DATA SHEET NO. 12 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair care and styling. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: POWDER DENSITY: Approx. 2.2 GR/CM3 FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined BULK DENSITTY:100-300 kg/m3 LAMMABILITY LIMITS Not combustible pH 6.0 – 9.0 SOLUBILITY IN WATER: No miscible INGREDIENTS CAS No. % w/w content 68909-20-6 Hydrofobic dispersed silica 100 % 52 Date: 04/01/2017 HEALTH HAZARD INFORMATION HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Eye contact may cause some stinging and tears. Transient reddening of the eye may also occur. Skin: No appreciable irritation is expected by this route but however, prolonged repeated skin contact should be avoided. Inhaled: TLV-GB 6 mg/m3 inhalable dust. Not recommended CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two glasses of water and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor if pain persists. Skin: Wash with water and soap an apply a cream Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. Eyes: No protection need. Flammability:Product is not flammable. 53 Date: 04/01/2017 SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place. TRANSPORT: SPILL AND Spills are slippery. Remove possible leaking containers. Mop up DISPOSAL: small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. FIRE / Will not burn. Not considered a significant risk. EXPLOSION HAZARD: ECOLOGICAL IMFORMATION Large quantities should not be discharged into waterways to prevent pollution of the waterways. TOXICOLOGICAL INFORMATION Medical Conditions Generally Aggravated by Exposure: None known. OTHER INFORMATION
Precautionary statements
I should follow? - Use in well ventilate areas - What protective clothing or equipment do I need? Gloves, apron, mask? - What ventilation is required? - How should the material be stored? - Are there materials this product should not come in contact with? - How do I clean us s spill? - How do I dispose of it properly? - Will it burn or explode? 8 Date: 04/01/2017 ANNEX I MSDS DESCRIPTION No. 1 Peroxide Solutions 7- 12% 2 Bleach Powder 3 Peroxide Solutions 3 – 6% 4 Alkaline Perms and relaxers 5 Hair colours (Semipermanent Cream) 6 Hair Colours (Permanent Cream) 7 Hairsprays/Lacquers (Aerosol) 8 Aerosol Mousses (Styling and Conditioning) 9 Shampoos 10 Conditioners, mask and Treatments 11 Hair Care Preparations (Styling gel, hair care liquid products) 12 Hair Care Preparations (Styling powder products) 9 Date: 04/01/2017 ANNEX II MSDS DESCRIPTION 1 Peroxide Solutions 7- 12% Collage Hydrox 30 vol Collage hydrox 40 vol Chroma developer 28 vol 2 Bleach powders kblonde dust free 3 Peroxide solution 3-7 % Gloss emulsion Gloss emulsion long Lasting Collage Hydrox 20 vol Collage Hydrox 10 vol Chroma developer 18 vol Masterperm neutralizer K-straight Neutralizing Balm 4 Alkaline perms and relaxers Masterperm “0” Masterperm “1” Masterperm “2” K-wave “0” K-wave “1” K-wave “2” K-straight ”0” K-straight “1” 5 Hair colours (semipermanent cream) Gloss (all shades) Chroma (all shades) 6 Hair colours (permanent cream) Collage Hair Color Cream (all shades) Red motion by collage (all shades) Collage mix-tone (all shades) Collage Clair (all shades) 10 Date: 04/01/2017 ANNEX II MSDS DESCRIPTION 7 Hair sprays /lacques (aerosols) Master Lak Master lak strong K-style Hard K-style Pliable k-style crunchy k-style polish Ecolak k-style Brush up 8 Aerosols mousses (styling and conditioning) k-style power k-style natural boost 9 Shampoo Teknia color stay shampoo Teknia curl up shampoo Teknia deep care shampoo Teknia body maker shampoo Teknia gentle balance shampoo Teknia ultra clair shampoo Teknia ultra red shampoo Teknia ultra copper shampoo Teknia ultra Brown shampoo Teknia ultra violet shampoo Teknia ultra gold shampoo Teknia extreme cleanse shampoo Teknia straight shampoo Teknia sun care shampoo k-therapy repair shampoo k-therapy active shampoo k-therapy purifying shampoo k-therapy peeling oily shampoo k-therapy peeling dry shampoo k-therapy peeling gel shock k-therapy sensitive shampoo k-therapy bioargan shampoo 11 Date: 04/01/2017 ANNEX II MSDS DESCRIPTION 10 Conditioners, treatments, mask Master Restructuring Hair mask Lak-2 conditioner Teknia color stay conditioner Teknia color stay treatment Teknia curl up conditioner Teknia deep care conditioner Teknia deep care treatmenr Teknia body care treatment Teknia ultra clair treatment Tekina ultra red treatment Teknia ultra copper treatment Teknia ultra brown treatment Teknia ultra violet treatment Teknia ultra gold treatment Teknia straight treatment Teknia sun care treatment k-therapy repair mask k-therapy repair conditioning fluid k-therapy active mask k-therapy sensitive balm k-therapy purifying maks k-therapy bio-argan mask i.plex keratech i.power i.plex hair perfection 11 Hair Care Preparations (Styling gel, hair care liquid products) Master care oil Master care lotion Master care tonic Master scalp protector Master stain remover Teknia deep care drops Teknia straight gel Teknia sun care serum Teknia sun care protection Teknia straight thermal protector k-therapy repair gel k-therapy active concentrate k-therapy active lotion k-therapy repair concentrate k-therapy sensitive drops k-therapy bio argan oil 12 Date: 04/01/2017 k-stylke i-tool k-style shape k-style fiber paste k.tyle matter k-style ring k-style sea mist k-style curl action k-style smooth k-style lift k-style x-treme k-style water touch k-style top ten k-style texture putty k-style body shaper i.plex Premium bond 12 Hair Care Preparations (powder) k-style chalk 13 Date: 04/01/2017 MATERIAL SAFETY DATA SHEET “CATEGORIES” 14 Date: 04/01/2017 PEROXIDE SOLUTIONS 7 – 12% MATERIAL SAFETY DATA SHEET NO. 1 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 2984 DANGEROUS GOOD CLASS: 5.1 (> 8%) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155 PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Low viscosity cream BOILING POINT: >35 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.02 – 1.05g/mL FLAMMABILITY LIMITS: not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. % w/w content Hydrogen peroxide 7722 – 84 – 1 7 to 12 Other ingredients determined not to be hazardous to 100 15 Date: 04/01/2017 HEALTH HAZARD INFORMATION
Potential health effects
Irritant. Attacks eyes. Protect eyes when using ACUTE EFFECTS: Swallow: Severe systemic poisoning may cause headache, dizziness, vomiting, diarrhoea, tremors, numbness, convulsions, pulmonary oedema, unconsciousness and shock. Eye: Eye contact may cause ulceration of the cornea. The appearance of the eye damage would be delayed Skin: Avoid contact. Temporary whitening or bleaching of the skin may occur. Irritation and formation of blisters may also occur. Inhaled: Exposure to high vapour concentration may cause irritation of nose and throat. Irritant. Attacks eyes. Protect eyes when using ACUTE EFFECTS: Swallow: Severe systemic poisoning may cause headache, dizziness, vomiting, diarrhoea, tremors, numbness, convulsions, pulmonary oedema, unconsciousness and shock. Eye: Eye contact may cause ulceration of the cornea. The appearance of the eye damage would be delayed Skin: Avoid contact. Temporary whitening or bleaching of the skin may occur. Irritation and formation of blisters may also occur. Inhaled: Exposure to high vapour concentration may cause irritation of nose and throat. ACUTE EFFECTS: Swallow: Harmful if swallowed can cause irritation of the gastrointestinal tract. Eye: Irritating to eyes. Skin: Irritating to skin. May cause sensitisation by skin contact.. Inhaled: Irritating to the respiratory system. May cause sensitisation by inhalation. Irritant. Attacks eyes. Protect eyes when using ACUTE EFFECTS: Swallow: Can cause irritation of the gastrointestinal tract. Eye: Eye contact can cause irritation. Skin: Temporary whitening of the skin may occur. Prolonged skin contact should be avoided. May cause skin irritation. Inhaled: Inhalation of vapours may cause irritation of nose and throat. ACUTE EFFECTS: Swallow: Harmful if swallowed. May cause irritation of the gastrointestinal tract. Eye: Avoid contact. Corrosive in concentrate form. Skin: Avoid contact. May cause skin irritation. Inhaled: Inhalation of vapours may cause irritation of nose and throat. This product contains ingredients which may cause skin irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows. ACUTE EFFECTS: Swallow: Harmful if swallowed. Product may cause irritation of the gastrointestinal tract. Eye: Corrosive to the eye. Skin: Avoid contact. Prolonged skin contact may cause skin irritation. Inhaled: This product contains ingredients which may cause skin irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows. ACUTE EFFECTS: Swallow: Harmful if swallowed. Product may cause irritation of the gastrointestinal tract. Eye: Corrosive to the eye. Skin: Avoid contact. Prolonged skin contact may cause skin irritation. Inhaled: Ammonia vapours may cause irritation of the nose and throat. Warning intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. ACUTE EFFECTS: Swallow: Low toxicity by the oral route. May cause irritation of the gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness. Eye: Splashes in the eye may cause immediate stinging sensation and tears. Transient reddening of the eye may also occur. Skin: No appreciable irritation of the skin is expected. Inhaled: At relatively vapour concentrations ethyl and isopropyl alcohol are irritants to the nose and throat and may cause central nervous system depression. ACUTE EFFECTS: Swallow: Low toxicity by the oral route. May cause irritation of the gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness. Eye: Contact may irritate eye. Skin: Prolonged and repeated skin contact should be avoided. Inhaled: Inhalation of aerosol products may cause irritation to the nose and throat. ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Splashes in the eye may cause stinging sensation and tears. Transient reddening of the eye may also occur. Skin: Prolonged and repeated skin contact should be avoided. Inhaled: No appreciable irritation is expected by this route.
Potential chronic health
Long term exposure may cause dermatitis FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor. Skin: Remove contaminated clothing and wash skin thoroughly with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm) 16 Date: 04/01/2017 ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be handling this product. Disposable gloves must not be latex. Eyes: Eye protection must be worn (safety glasses) to avoid accidental splashes into eyes. Flammability:Product is not flammable, but can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. SAFE HANDLING INFORMATION STORAGE AND Store product upright in a cool place away from heat and direct sun TRANSPORT: light. Store away from corrosive and flammable products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods class 5. SPILL AND Dilute small spills with water, contain and absorb larger spills in Long term exposure may cause dermatitis FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor. Skin: Remove contaminated clothing and wash skin thoroughly with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA 19 Date: 04/01/2017 CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be handling this product. Disposable gloves must not be latex. Eyes: Eye protection must be worn (safety glasses) to avoid accidental splashes into eyes. Flammability:Product is not flammable, but can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. SAFE HANDLING INFORMATION STORAGE AND Store product upright in a cool place away from heat and direct sun TRANSPORT: light. Store away from corrosive and flammable products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods class 5. SPILL AND Dilute small spills with water, contain and absorb larger spills in May cause allergic dermatitis. Prolonged or repeated inhalation may cause sensitisation. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water and contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor. Skin: Remove contaminated clothing and wash skin thoroughly with water. Inhaled: Remove person to fresh air and see a doctor. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Amorphous fumed silica (respirable dust) 2 mg/m3 Persulphate (ACGIH TLV standard) 5 mg/m3 22 Date: 04/01/2017 ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this or its mixtures with solutions containing hydrogen peroxide. Disposable gloves must not be latex. Eyes: Safety glasses must be worn to avoid product or dust entering the eye. Flammability:Product is not flammable, but its mixtures with peroxide can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. SAFE HANDLING INFORMATION STORAGE AND Store product in a cool dry place away from heat and direct sun TRANSPORT: light. Store away from corrosive and flammable products. SPILL AND Avoid creating dust. Collect into clean plastic containers and dispose Long term skin contact may cause dermatitis FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor. Skin: Remove contaminated clothing and wash skin thoroughly with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA 25 Date: 04/01/2017 CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended when handling this product. Disposable gloves must not be latex. Eyes: Eye protection (safety glasses) must be worn to avoid accidental splashes into eyes. Flammability:Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND Store product upright in a cool place away from heat and direct sun TRANSPORT: light. Store away from corrosive and flammable products. SPILL AND Dilute small spills with water, contain and absorb larger spills in Long term or repeated exposure may result in skin irritation in some individuals. FIRST AID: Swallowed: If swallowed do not induce vomiting, give a glass of water and contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor. Skin: Do not rub. Rinse with water. Remove contaminated clothing. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Ammonia 17 mg/m3 (25 ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex. 28 Date: 04/01/2017 Eyes: Safety glasses must be worn to avoid product or dust entering the eye. Flammability:Product is not flammable, but its mixtures with peroxide can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. SAFE HANDLING INFORMATION STORAGE AND Store product in a cool dry place away from heat and direct sun TRANSPORT: light. Store away from corrosive and flammable products. SPILL AND Avoid creating dust. Collect into clean plastic containers and dispose Long term or repeated skin contact may lead to dermatitis. Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Contact a doctor Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Skin: Wash affected area with water. If irritation develops seek medical advice. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA* 31 Date: 04/01/2017 CHEMICAL NAME: Resorcinol 45mg/m3(10ppm) Phenylendiamines (refer to pack copy 0.1mg/ m3 for specific ingredients) Ethanolamine 7.5mmg/ m3(3ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product or the mixture between products and solutions containing hydrogen peroxide. Disposable gloves must not be latex Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes. Flammability: Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place out of sun and away from food stuffs. TRANSPORT: SPILL AND Dilute small spills with water. Contain and absorb in inert material Long term or repeated skin contact may lead to dermatitis Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Contact a doctor Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Skin: Wash affected area with water. If irritation develops seek 34 Date: 04/01/2017 medical advice. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Ammonia 17mg/m3(25ppm) Resorcinol 45mg/m3(10ppm) Phenylendiamines (refer to pack copy 0.1mg/ m3 for specific ingredients) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product or the mixture between products and solutions containing hydrogen peroxide. Disposable gloves must not be latex Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes. Flammability: Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place out of sun and away from food stuffs. TRANSPORT: SPILL AND Dilute small spills with water. Contain and absorb in inert material Long term exposure to ethyl and isopropyl alcohol may result in irritation of the nose and mouth, headaches, lack of concentration and drowsiness. Prolonged or repeated skin contact may lead to dermatitis. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor if pain persists. Skin: Wash affected area with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrocarbon propellant (LPG) 1800mg/m3 (1000 ppm) Ethyl alcohol 1880mg/m3 (1000 ppm) 38 Date: 04/01/2017 ENGINEERING CONTROLS: Use in well ventilated areas and away from ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged skin conduct with the product. Eyes: Protect eyes when using. Flammability:Highly flammable, keep away from heat, flame or ignition source. SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place out of direct sunlight. Store away from TRANSPORT: corrosive products. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous goods Class 2. SPILL AND Remove all ignition sources and ventilate area. Remove possible Prolonged or repeated exposure may lead to skin dryness FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor if pain persists. Skin: Wash affected area with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrocarbon propellant (LPG) 1800mg/m3 (1000 ppm) Ethyl alcohol 1880mg/m3 (1000 ppm) ENGINEERING CONTROLS: Use in well ventilated areas and away from ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged skin conduct with the product. Eyes: Protect eyes when using. Flammability:Highly flammable, keep away from heat, flame or ignition source. 41 Date: 04/01/2017 SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place out of direct sunlight. Store away from TRANSPORT: corrosive products. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous goods Class 2. SPILL AND Remove all ignition sources and ventilate area. Remove possible May produce dermatitis on repeated or prolonged contact with skin. FIRST AID: Swallowed: If swallowed DO NOT induce vomiting. Give a glass of water and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Skin: Wash affected area with water. Inhaled: Remove from further exposure. Advice to Doctor: Treat symptomatically. PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA ENGINEERING CONTROLS: None required. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended if prolonged contact with the product is envisaged. Eyes: None Flammability: Product is not flammable. 44 Date: 04/01/2017 SAFE HANDLING INFORMATION STORAGE AND Store product in a cool place TRANSPORT: SPILL AND Spills are slippery. Remove possible leaking containers. Mop up
Disposal
inert material (sand). Dispose in accordance with local regulations. FIRE / Will not burn, but may release oxygen when subjected to heat. EXPLOSION At concentration above 10%, hydrogen peroxide may ignite a fire if inert material (sand). Dispose in accordance with local regulations. FIRE / Will not burn, but may release oxygen when subjected to heat. EXPLOSION At concentration above 10%, hydrogen peroxide may ignite a fire if spilled in combustible materials (ie. wood , paper, cardboard). In case of fire water, water fog, dry chemical CO2 or foam can be caused. in accordance with local regulations. Wipe area with wet mop/cloth. FIRE / When heated product can release oxygen. This can cause other EXPLOSION materials to burn. On decomposition can release fumes or ammonia, sulfates and oxides of nitrogen and potassium. Respirators and eye protection is required. In case of fire water, water fog, dry chemical CO2 or foam can be used. inert material (sand). Dispose in accordance with local regulations. FIRE / Will not burn, but may release oxygen when subjected to heat. EXPLOSION In case of fire water, water fog, dry chemical CO2 or foam can be caused. in accordance with local regulations. Wipe area with wet mop/cloth. FIRE / When heated product can release oxygen. This can cause other EXPLOSION materials to burn. On decomposition can release fumes or ammonia, sulfates and oxides of nitrogen and potassium. Respirators and eye protection is required. In case of fire water, water fog, dry chemical CO2 or foam can be used. (ie. sand or vermiculate). Dispose of in accordance with local regulations. FIRE / The material is not flammable. In case of fire water, water fog, dry EXPLOSION chemical, CO2 or foam can be used. (ie. sand or vermiculate). Dispose of in accordance with local regulations. 35 Date: 04/01/2017 FIRE / The material is not flammable. In case of fire water, water fog, dry EXPLOSION chemical, CO2 or foam can be used. leaking containers. Dilute spills with water. Do no t puncture or incinerate cans even when empty. Dispose of in accordance with local regulations. Highly flammable. Vapours are heavier than air, distant ignition FIRE / source possible. Closed containers may rupture when exposed to EXPLOSION heat greater than 50ºC. may react with oxidising agents. May produce toxic vapours on decomposition. Fog, fine water spray, carbon dioxide, foam or dry chemical can be used to extinguish fires. leaking containers. Dilute spills with water. Do no t puncture or incinerate cans even when empty. Dispose of in accordance with local regulations. Flammable. Closed containers may rupture when exposed to heat FIRE / greater than 50ºC. Fog, fine water spray, carbon dioxide, foam or EXPLOSION dry chemical can be used to extinguish fires. small pills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. FIRE / Will not burn. Not considered a significant risk. EXPLOSION
SECTION 2: Hazards identification
spilled in combustible materials (ie. wood , paper, cardboard). In case of fire water, water fog, dry chemical CO2 or foam can be caused.
ECOLOGICAL INFORMATION
Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways. Large quantities should not be discharged into waterways to prevent pollution of the waterways.
Medical Conditions Generally Aggravated by Exposure
None known 17 Date: 04/01/2017 None known 20 Date: 04/01/2017 None known None known 26 Date: 04/01/2017 None known None known 32 Date: 04/01/2017 None known None known None known None known