NU-BIO SCRUB - ISEU-016-02 (Concentrate)

Hazard statements (CLP)

H225, H226, H302, H304, H312, H314, H315, H317, H318, H319, H332, H336, H373, H400, H410, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

3. INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES First-aid measures general : Get medical advice/attention if you feel unwell. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash with plenty of soap and water. First-aid measures after eye contact IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Give nothing or a little water to drink. Get medical advice/attention if you feel unwell. 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Carbon dioxide. Dry powder. Foam. 6. ACCIDENTAL RELEASE MEASURES For non-emergency personnel Emergency procedures: Evacuate unnecessary personnel. For emergency responders Protective equipment: Use personal protective equipment as required. Environmental precautions Avoid release to the environment. Methods and material for containment and cleaning up For containment: Collect spillage. Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. 7. HANDLING AND STORAGE Precautions for safe handling: Avoid contact with eyes. Hygiene measures: Do not eat, drink or smoke when using this product. Technical measures: Does not require any specific or particular technical measures. Storage conditions: Keep container closed when not in use. Incompatible products: Oxidizing agent. Strong acids. Strong bases. Special rules on packaging: Keep only in original container. 8. PERSONAL PROTECTION/EXPOSURE CONTROLS 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : Liquid Appearance : Mobile liquid. Colour : Blue. Odour : Fresh. Odour threshold : No data available pH : 1.7 Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 °C : No data available Relative density : 1.06 Solubility : No data available Log Pow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 10. STABILITY AND REACTIVITY No information available

TOXICOLOGICAL INFORMATION

Acute toxicity : Not classified Skin corrosion/irritation Causes skin irritation. pH 1.7 Serious eye damage/irritation Causes serious eye irritation. pH 1.7 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Acute Toxicity: This material is not expected to be toxic via dermal or oral exposures. In addition, there is not expected to be any irritation of the skin or eyes on contact with this product Sensitization: This product is not expected to cause sensitization Relevant calculated ATE(s): ATE - Oral (mg/kg): >5000 ATE - Dermal (mg/kg): >5000 ATE - Inhalatory, mists (mg/l): >20 Eyes: irritant Skin: Unlikely to be irritant in normal use. Inhalation: Unlikely to be irritant in normal use. Ingestion: Unlikely to be irritant in normal use. We have not carried out any animal testing for this product. Any ATE figures quoted below are from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate) Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer. 11.1 Information on toxicological effects Mixture data:. Relevant calculated ATE(s): ATE - Oral (mg/kg): >5000 Substance data, where relevant and available, are listed below:. Ingredient(s) Endpoint Value Species Method Exposure (mg/kg) time (h) propan-2-ol LD 50 3570 Rat Method not given tetrapotassium pyrophosphate LD 50 > 2000 Rat Method not given alkyl alcohol ethoxylate LD 50 300 - 2000 Method not given alkyldimethylbenzylammoniumchloride LD 50 398 Rat Ingredient(s) Endpoint Value Species Method Exposure (mg/kg) time (h) propan-2-ol LD 50 > 2000 Rabbit Method not given tetrapotassium pyrophosphate LD 50 > 2000 Rabbit Method not given alkyl alcohol ethoxylate LD 50 2000 - 5000 Rat Method not given alkyldimethylbenzylammoniumchloride LD 50 800 - 1420 Rat Method not given Ingredient(s) Endpoint Value Species Method Exposure (mg/l) time (h) propan-2-ol LC 50 > 25 (vapour) Rat OECD 403 (EU 6 B.2) tetrapotassium pyrophosphate LC 50 > 1.1 Rat Method not given 4 alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Result Species Method Exposure time propan-2-ol Not irritant Rabbit OECD 404 (EU B.4) tetrapotassium pyrophosphate Not irritant Method not given alkyl alcohol ethoxylate Not irritant Method not given alkyldimethylbenzylammoniumchloride Corrosive Method not given Ingredient(s) Result Species Method Exposure time propan-2-ol Irritant Rabbit OECD 405 (EU B.5) tetrapotassium pyrophosphate Irritant Method not given alkyl alcohol ethoxylate Severe damage Rabbit Method not given alkyldimethylbenzylammoniumchloride Severe damage Method not given Ingredient(s) Result Species Method Exposure time propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Result Species Method Exposure time (h) propan-2-ol Not sensitising Guinea pig OECD 406 (EU B.6) / Buehler test tetrapotassium pyrophosphate Not sensitising Method not given alkyl alcohol ethoxylate Not sensitising Guinea pig Method not given alkyldimethylbenzylammoniumchloride Not sensitising Method not given Ingredient(s) Result Species Method Exposure time propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method (in-vitro) (in-vivo) propan-2-ol No evidence for mutagenicity, OECD 471 No data available negative (EU test results B.12/13) tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No evidence for mutagenicity, OECD 473 No data available negative test results alkyldimethylbenzylammoniumchloride No evidence for mutagenicity, OECD 471 No data available negative test results (EU B.12/13) Ingredient(s) Effect propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No evidence for carcinogenicity, negative test results alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other (mg/kg time effects reported bw/d) propan-2-ol No data available tetrapotassium No data pyrophosphate available alkyl alcohol ethoxylate NOAEL > 250 Rat Not No effects on known fertility No developmental toxicity alkyldimethylbenzylam No data moniumchloride available Ingredient(s) Endpoint Value Species Method Exposure Specific effects and (mg/kg time organs affected bw/d) (days) propan-2-ol No data available tetrapotassium pyrophosphate NOAEL No data Rat OECD 408 90 days available (EU B.26) alkyl alcohol ethoxylate NOAEL 80 - 400 Method not given alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Endpoint Value Species Method Exposure Specific effects and (mg/kg time organs affected bw/d) (days) propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate NOAEL 80 OECD 411 90 (EU B.28) alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Endpoint Value Species Method Exposure Specific effects and (mg/kg time organs affected bw/d) (days) propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Eyes: May cause eye irritation, avoid eye contact. Skin: May cause skin irritation, avoid skin contact. Not expected to be a skin sensitizer. Inhalation: Unlikely to be irritant in normal use. Ingestion: Health injuries are not known or expected under normal use. Inhalation: High concentrations of vapour even for short periods must be avoided since this may be dangerous and cause unconsciousness and prove suddenly fatal. Skin Contact: Contact with liquid will cause freezing of body tissues and frostbite. Eye Contact: Irritation is likely contact with liquid causes freezing of body tissues and frostbite. . .

Aspiration hazard

Not classified Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density of the product. Potential adverse health effects and symptoms Effects and symptoms related to the product, if any, are listed in subsection 4.2.

ECOLOGICAL INFORMATION

No information available 13. DISPOSAL CONSIDERATIONS No information available 14. TRANSPORT INFORMATION Not regulated for transport 15. REGULATORY INFORMATION: EU-Regulations Contains no substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Ecotoxicity: This product is not expected to cause any significant adverse effects on the environment. Bioaccumulation: Not expected to bioaccumulate Mobility: Soluble in water Persistence and degradability: Readily biodegradable 13. DISPOSAL CONSIDERATIONS No data is available on the mixture. 13. DISPOSAL CONSIDERATIONS The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging material is suitable for energy recovery or recycling in line with local legislation. 14. TRANSPORT INFORMATION No data is available on the mixture. The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. When used for its intended purpose this product should not cause adverse effect in the environment. 13. DISPOSAL CONSIDERATIONS The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit. Release of waste to sewers is discouraged the cleaning packaging material is suitable for energy recovery or recycling in line with local legislation. European waste catalogue: Detergents other than those mentioned in 20 01 29 Recommendation: Dispose of observing national or local regulations. Suitable cleaning agents: Water, if necessary with cleaning agent. 14. TRANSPORT INFORMATION ARD, RID, AND, IMO/IMDG, ICAO/IATA 15. REGULATORY INFORMATION: Not regarded as dangerous for the environment. Toxicity We have not carried out any Aquatic testing; therefore we have no Aquatic Toxicity Data specifically for this product. The Aquatic Toxicity Data, where provided by the raw material manufacturer for ingredients with aquatic toxicity, can be made available on request Persistence and degradability This product, at use dilutions, is readily broken down in biological effluent treatment plants Bio accumulative potential The product does not contain any substances expected to be bio accumulating. Mobility in soil Mobility not known. This product does not contain any PBT or vPvB substances. 13. DISPOSAL CONSIDERATIONS Small amounts (less than 5 Litres) of unwanted product may be flushed with water to sewer. Larger volumes must be sent for disposal by approved waste contractor. Consign empty container to normal waste 14. TRANSPORT INFORMATION Product in pack size of 5 Litres or less is classed as a "Limited Quantity" for transport and so will have the white with black points transport hazard diamond. Pack size greater than 5 litres will have the red Flammable Liquid UN1987 Transport hazard diamond. 15. REGULATORY INFORMATION: Guidance Notes Workplace Exposure Limits EH40. EU Legislation Safety Data Sheet prepared in accordance with REACH Commission 12.1 Toxicity No data is available on the mixture. Substance data, where relevant and available, are listed below: Ingredient(s) Endpoint Value Species Method Exposure (mg/l) time (h) propan-2-ol LC 50 > 100 Pimephales Method not given 48 promelas tetrapotassium pyrophosphate LC 50 > 100 Oncorhynchus OECD 203 (EU 96 mykiss C.1) alkyl alcohol ethoxylate LC 50 5 - 7 Fish 92/69/EEC, C1, 96 semi-static alkyldimethylbenzylammoniumchloride LC 50 > 0.1-1 Fish Method not given 96 Ingredient(s) Endpoint Value Species Method Exposure (mg/l) time (h) propan-2-ol EC 50 > 100 Daphnia Method not given 48 magna Straus tetrapotassium pyrophosphate EC 50 > 100 Daphnia OECD 202 (EU 48 magna C.2) Straus alkyl alcohol ethoxylate EC 50 5.3 Daphnia 92/69/EEC 48 alkyldimethylbenzylammoniumchloride EC 50 0.02 Daphnia Method not given 48 Ingredient(s) Endpoint Value Species Method Exposure (mg/l) time (h) propan-2-ol EC 50 > 100 Scenedesmus Method not given 72 quadricauda tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate EC 50 1.4 - 47 Not specified 92/69/EEC 72 alkyldimethylbenzylammoniumchloride EC 50 0.06 Pseudokirchner OECD 201 (EU 96 iella C.3) subcapitata Ingredient(s) Endpoint Value Species Method Exposure (mg/l) time (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Inoculum Method Exposure (mg/l) time propan-2-ol EC 50 > 1000 Activated Method not sludge given tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate EC 50 > 140 Bacteria Method not 3 hour(s) given alkyldimethylbenzylammoniumchloride EC 20 10 Activated OECD 209 0.5 hour(s) sludge Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/l) time propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate EC 10 8.983 Not specified Method not 21 day(s) given alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/l) time propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate EC 10 2.579 Daphnia sp. Method not 21 day(s) given alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/kg dw time sediment) (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/kg dw time soil) (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/kg dw time soil) (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Species Method Exposure Effects observed time (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/kg dw time soil) (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available Ingredient(s) Endpoint Value Species Method Exposure Effects observed (mg/kg dw time soil) (days) propan-2-ol No data - available tetrapotassium pyrophosphate No data - available alkyl alcohol ethoxylate No data - available alkyldimethylbenzylammoniumchloride No data - available 12.2 Persistence and degradability Ingredient(s) Inoculum Analytical DT 50 Method Evaluation method propan-2-ol 95 % in 21 OECD 301E Readily biodegradable day(s) tetrapotassium pyrophosphate Not applicable (inorganic substance) alkyl alcohol ethoxylate 60 % in 28 Method not Readily biodegradable day(s) given alkyldimethylbenzylammoniumchloride Oxygen depletion > 60% OECD 301D Readily biodegradable 12.3 Bioaccumulative potential Ingredient(s) Value Method Evaluation Components of this product have been identified as having potential environmental concerns. Ecotoxicity – Freshwater Algae – Acute Toxicity Data Isopropanol, 96 HRS EC50 Desmodesmus subspicatus >1000 mg/l; 72 Hr EC Desmodesmus subspicatus: >1000 mg/l Ecotoxicity – Freashwater Fish – Acute Toxicity Data Ammonium hydroxide, 96 Hr LC Pimephales promelas: 8.2 mg/l Ethanol, 96 Hr LC Oncohynchus mykiss 12.0 – 16.0 mL/L [flow-through]; 96 Hr LC Pimephales promelas 11130 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: >1400000 µg/L Ecotoxity – Water flea – Acute toxicity Data Ammonium hydroxide, 48 Hr EC water flea 0.66 mg/L; 48 Hr EC50 Daphnia pulex 0.66 mg/L Ethanol, 48 Hr LC50 Daphnia magna 9268 – 14221 mg/L; 24 Hr EC50 Daphnia magna 10800 mg/L; 48 Hr EC50 Daphnia magna 2mg/L [static] Isopropanol, 48 Hr EC50 Daphnia magna: 13299 mg/L 13. DISPOSAL CONSIDERATIONS Product Disposal: Can be disposed of in accordance with all applicable local regional and national requirements. Operators should be informed that the product contains white spirit. For further information contact your local waste authority. Container Disposal: Containers may be disposed of by consumers in the normal domestic waste stream. 14. TRANSPORT INFORMATION EEC Regulation - IMDG/UN : Proper Shipping Name Turpentine Substitute, Class 3, Subsidiary Risk N/A, Packing Group III, Marine Pollutant YES, EMS F-E, S-E, MFag Obsolete, Limited Quantity 5L inner packaging 30 Kg gross weight/combined packaging, 20 K gross weight /Tray, Special provisions: None Stowage and segregation Ecotoxicity: Because product is so volatile if it is released into the environment the liquid would very quickly turn into vapour. 13. DISPOSAL CONSIDERATIONS Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. 14. TRANSPORT INFORMATION UN NO. ROAD 1950 UK ROAD CLASS 2.2 ADR CLASS NO. 2.2 ADR CLASS Class 2: Gases PROPER SHIPPING NAME AEROSOL, ASPHYXIANT UN NO. SEA 1950 IMDG CLASS 2.1 UN NO. AIR 1950 AIR CLASS 2.1 15. REGULATORY INFORMATION: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION: Persistence and degradability: Biodegradable. Bioaccumulative potential: No bioaccumulation potential. Mobility: Readily absorbed into soil PBT identification: This product is not identified as a PBT/vPvB substance.

Further information

MSDS DATE of issue 15/08/2017 Version 10. JR&Co COSHH issue 3 13/07/2020 COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: Substance: CA 007 OdorBac Tec⁴ MSDS DATE 13/07/2020 Physical Form Clear pale liquid Use of the A multi - purpose cleaning product used no matter the surface or delivery Material method. Method of Do not carry out any cleaning activity without prior washing hands and selecting Use the appropriate PPE stipulated in this assessment. This assessment requires all operatives to wear chemical resistant gloves EN374 Use in trigger sprays, mop & bucket, extraction and scrubbing machines to effortlessly complete the clear majority of cleaning tasks Quantity Used Dilute according to attended usage – see reverse label on bottle Associated with the Material Can a Safer No practical commercial alternatives exist, and physical methods cannot be Alternative Be used. Used Persons Operator Can cause eye irritation low risk – mitigated through Exposed, use of PPE, user training and product being used in Method of low quantities Exposure and Risk Level Indirectly Low risk to third party as product is only to be handled by authorised users only and it is stored in locked cupboard when not in use. Risk reduced further as product is applied directly to cloth and is immediately safe to touch so suitable for use in public environments where control measures maintained Control Minimum quantities used consistent with effective performance. Exposure Measures timeframe limited, prior training and instruction and PPE worn as detailed below. Used PPE Used No personal equipment is required but JR&Co require all operatives to wear full uniform and chemical resistant gloves EN374 First Aid Arrangements Emergency Environmental Precautions: Avoid spilled material from entering storm drains or Arrangements surface waterways. Clean-up Procedures: Follow company spillage instructions. Notes JR&Co COSHH Revision 5, 13/07/2020 Name Of Rebecca Elliott Assessor: Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: OdorBac Tec⁴ 3. INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES 5. FIRE FIGHTING MEASURES Extinguishing Media: Water, Carbon Dioxide, polymer foam, dry chemical powder Exposure Hazards: May release oxygen on heating Protection of Fire Fighters: Wear standard firefighting protective clothing 6. ACCIDENTAL RELEASE MEASURES Environmental Precautions: Avoid spilled material from entering storm drains or surface waterways. Clean-up Procedures: Follow company spillage instructions. 7. HANDLING AND STORAGE Handling Requirements: Avoid direct contact with eyes. Avoid excessive direct inhalation. Do not ingest. JR&Co COSHH issue 5. 13/07/2020 COSHH & ENVIRONMENT ASSESSMENT FORM CA 008 Substance: Shield Cleaner Disinfectant Concentrate MSDS DATE 13/07/2020 Physical Clear blue liquid slightly perfumed Form Use of the Cleaner and disinfectant with odour neutralising technology. Cleans and disinfects in one step Material ensuring hard surfaces are hygienically clean. Suitable for all areas except food/ drink preparation and service areas. Method of Use instructions Use Wear appropriate personal protective equipment: protective gloves EN 374, safety glasses (EN 166) and protective clothing when handling undiluted product Dilute the product 1:40 (2.5%) with water Hard Surface Cleaning 1. Apply the product to surface using trigger spray, sponge or cloth 2. Allow 5 minutes contact time 3. Rinse and allow to dry Floor Cleaning 1. Apply the product using mop and bucket. 2. Agitate area with mop or brush allowing 5 minutes contact time. 3. Rinse and allow to air dry Quantity Dilute the product 1:40 (2.5%) with water Used Associated with the Material Can a Safer No practical commercial alternatives exist and physical methods cannot be used. Alternative Be Used Operator Persons Low risk of skin contact during pouring as long as the Exposed, pouring is carefully carried out; risks of skin contact are Method of mitigated by the use of PPE. Exposure Low risk of splashing into the eyes as bottle spout for and Risk squirting points downward away from the face. Training in Level correct application. Indirectly Not used in areas with access by clients or the public, area closed off or material used out of normal working hours. PPE Used Undiluted product: Hand protection: Protective gloves (EN374). Eye protection: Safety glasses (EN166). Skin protection: Protective clothing. If the product is diluted by using specific dosing systems with no risk of splashes or Control direct skin contact, the personal protection equipment as described in this section is Measures not required. Used Avoid direct contact and/or splashes where possible. Train personnel. Provide a good standard of general ventilation. First Aid General information: If you feel unwell, call a doctor or poison control centre. Arrangements Skin contact: Wash skin with plenty of lukewarm, gently flowing water. Take off immediately all contaminated clothing and wash it before re-use. If skin irritation occurs: Get medical advice or attention Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor or physician. Ingestion: Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious person. Get medical attention or advice if you feel unwell. Inhalation: Get medical attention or advice if you feel unwell. Extinguishing media: Carbon dioxide. Dry powder. Water spray jet. Fight larger Emergency fires with water spray jet or alcohol-resistant foam. Arrangements As in any fire, wear self-contained breathing apparatus and suitable protective clothing including gloves and eye/face protection. Name Of Rebecca Elliott Assessor: Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: Shield Cleaner Disinfectant Concentrate SDS code: MS1003506 MSDS issue 1: 15/02/2017 JR&CO COSHH issue 3 13/07/2020 Full text of the H and EUH phrases mentioned in section 3: • H302 - Harmful if swallowed. • H312 - Harmful in contact with skin. • H314 - Causes severe skin burns and eye damage. • H318 - Causes serious eye damage. • H332 - Harmful if inhaled. • H373 - May cause damage to organs through prolonged or repeated exposure. • H400 - Very toxic to aquatic life. • H410 - Very toxic to aquatic life with long lasting effects. Abbreviations and acronyms: • AISE - The international Association for Soaps, Detergents and Maintenance Products • DNEL - Derived No Effect Limit • EUH - CLP Specific hazard statement Handle and apply only as recommended, for full information see product information sheet. COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: CA 010 Substance: MSDS DATE 13/07/2020 Cleanline Glass and Stainless Steel Cleaner Physical Form Blue Liquid Use of the Material Neutral, cleaner for Glass, Mirrors and Stainless Steel. Method of Use Do not carry out any cleaning activity without prior washing hands and selecting the appropriate PPE stipulated in this assessment. This assessment requires all operatives to wear chemical resistant rubber gloves EN 374 and suitable clothing to protect skin contact Spray onto cloth & wipe. Quantity Used Generally small depending on area. Associated Information Sources Material Safety Data Sheet, Misc. manufacturers. CLP Class - Table 3.1 List of harmonised classification and labelling of hazardous substances. CHIP Class - Table 3.2 The list of harmonised classification and labelling of hazardous substances from Annex I to Directive 67/548/EEC. ECHA - C&L Inventory database. Revision Comments This product is now using classification from GHS/CLP Surface tension (N/m): Not determined Corrosion to metals: Not corrosive 10. STABILITY AND REACTIVITY 10.1 Reactivity No reactivity hazards known under normal storage and use conditions. 10.2 Chemical stability Stable under normal storage and use conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known under normal storage and use conditions. 10.4 Conditions to avoid Keep from freezing. 10.5 Incompatible materials Reacts with water and acids. 10.6 Hazardous decomposition products None known under normal storage and use conditions. JR&Co COSHH issue 4: 13/07/2020 MSDS issue 1: 09/03/2020 Classification procedure The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No Safety data sheet following regulation The following risk phrases relate to the raw materials in the product and not the product itself:- SDS GENERATED DATE 05/04/2016 JR&CO COSHH last review: 13/07/2020 COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: Substance: CA 014 CLEANLINE HARD SURFACE CLEANER MSDS DATE 13/07/2020 Green viscous liquid with an apple smell. Physical Form Use of the Cleanline Hard Surface Cleaner is a fast acting, multi-purpose cleaner for walls, Material doors, paintwork and most hard surfaces. Removes stubborn stains effectively with a refreshing lemon fragrance. Method of Do not carry out any cleaning activity without prior washing hands and Use selecting the appropriate PPE stipulated in this assessment. This assessment requires all operatives to wear rubber gloves, safety goggles and suitable clothing to protect skin contact DIRECTIONS • Dilute 1 15 cold water for use in trigger bottles. • Dilute 1 40 in warm water for floors and general surfaces. • Dilute 1:10 in cold water for heavily soiled areas. • Dilute 1:20 cold water for use on walls. • Apply by mop or Spray. Dilute 1 15 cold water for use in trigger bottles. • Dilute 1 40 in warm water Quantity Used for floors and general surfaces. • Dilute 1:10 in cold water for heavily soiled areas. • Dilute 1:20 cold water for use on walls. Associated with the Material Can a Safer Operator should consider using ‘Nu-Kleen Smell’ an enzyme-based cleaning Alternative Be product Used Operator Persons Low risk of skin contact during dilution, mitigated through Exposed, use of PPE and training using pelican pumps Method of Low risk of splashing into the eyes as product is diluted Exposure and using a pelican pump. Training in correct application. Risk Level Operator also required to wear safety goggles during application Inhalation of vapour carries only low risk since material is of low toxicity and low vapour pressure. Risk reduced through appropriate ventilation Indirectly Not used in areas with access by clients or the public. Area closed off or material used out of normal working hours. Toilets should ideally be closed to users whilst the cleaner is in the toilet pans. Control Minimum quantities used consistent with effective performance. Containers are Measures kept closed when not in use. Used PPE Used First Aid Arrangements Emergency Arrangements Notes This safety data sheet is prepared in accordance with Commission Regulation (EU) COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: Substance: CA 015 CLEANLINE ACID WASHROOM AND LIMESCALE MSDS DATE 13/07/2020 REMOVER Physical Yellow liquid Form A concentrated liquid designed to clean, disinfect and deodorise most Use of the washroom surfaces, including stainless steel. Material It is effective against most common forms of bacteria Method of Do not carry out any cleaning activity without prior washing hands and selecting Use the appropriate PPE stipulated in this assessment. This assessment requires all operatives to wear rubber gloves EN374, safety goggles EN166 for usage in spray application and suitable clothing to protect skin contact For General Washroom Cleaning: Dilute 1 part to 60 parts water. For Stainless Steel Cleaning: Dilute 1 part to 40 parts water. Use neat for disinfecting drains. Apply to surface by cloth, allow a few minutes contact time, agitate and then wipe away with a damp cloth leaving a clean disinfected surface. It will kill most commonly found bacteria. Always clean vertical surfaces from the bottom up to avoid unsightly streaking. Ideal for many washroom surfaces including toilets, urinals, washbasins, sinks, tiles, counter surfaces and floors. Do not use on acid sensitive surfaces or vitreous enamel. Dilute 1 15 cold water for use in trigger bottles. • Dilute 1 40 in warm water for Quantity floors and general surfaces. • Dilute 1:10 in cold water for heavily soiled areas. • Used Dilute 1:20 cold water for use on walls. Associated with the Material Can a Safer No practical commercial alternatives exist and physical methods cannot be used. Alternative Be Used Persons Operator Low risk of skin contact during dilution, mitigated Exposed, through use of PPE and training using pelican pumps Method of Low risk of splashing into the eyes as product is Exposure and diluted using a pelican pump. Training in correct Risk Level application. Operator also required to wear safety goggles during application Inhalation of vapour carries only low risk since material is of low toxicity and low vapour pressure. Risk reduced through appropriate ventilation Indirectly Not used in areas with access by clients or the public. Area closed off or material used out of normal working hours. Toilets should ideally be closed to users whilst the cleaner is in the toilet pans. Control Minimum quantities used consistent with effective performance. Containers are Measures kept closed when not in use. Used PPE Used EN374 First Aid Arrangement s Emergency Personal precautions: Mark out the contaminated area with signs and prevent Arrangement access to unauthorised personnel. Do not attempt to take action without suitable s protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid. Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Notes This safety data sheet is prepared in accordance with Commission Regulation (EU) Other information

Storage

Conditions Store in a cool well-ventilated area. Keep containers tightly closed Suitable Packaging: Must only be kept in original packaging. 8. PERSONAL PROTECTION/EXPOSURE CONTROLS 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Colour: Clear pale aqua Odour: None Solubility in Water: Miscible in all proportions Relative Density 1.015 pH 3-6 10. STABILITY AND REACTIVITY General Stability: Stable under normal conditions Conditions to avoid: Extremes of temperature and light. Materials to avoid: Do not mix with any other chemical product Hazardous decomposition products: None. May release oxygen on heating Precautions Store in cool, dry frost free place away from sources of ignition and out of reach of children 8. PERSONAL PROTECTION/EXPOSURE CONTROLS Hand : Wear rubber gloves if exposure is likely to be prolonged. Eyes None necessary under normal working conditions. Skin Wear an apron or coveralls if exposure is likely to be prolonged. Respiration : None necessary under normal working conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous Liquid Odour: Ammonical Flash Point 38-45 degrees Celsius pH-Value, Conc,. 11 10. STABILITY AND REACTIVITY Stability: DO NOT MIX WITH BLEACH or use in conjunction with other household products. Conditions to Avoid: Protect from sources of ignition. Avoid high temperatures, do not mix with other chemicals, excessive heat and moisture. Materials to Avoid: Strong oxidising agents.

Potential chronic health

None known or expected Chronic Toxicity: None expected CMR effects: None expected

Disposal

Operations Waste must be disposed of in accordance with Controlled Waste Regulations 1992 (+ amendments) Disposal of packaging: Return packaging to the supplier wherever possible for recycling. Dispose of as normal industrial waste. NB: Please ensure that you are aware of the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION No text available 15. REGULATORY INFORMATION:

Hazard pictograms

No significant Hazard Authorisation or restrictions (Regulation (EC) No Dangerous for the environment

Hazard statements

None H315 - Causes skin irritation. H318 - Causes serious eye damage. H412 - Harmful to aquatic life with long lasting effects. In Full R10 Flammable. R11 Highly flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. R67 Vapours may cause drowsiness and dizziness In Full H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. COSHH & ENVIRONMENT ASSESSMENT FORM CA 011 Substance: Shield Cleaner Disinfectant Trigger MSDS DATE 13/07/2020 Physical Form Clear, colourless liquid Use of the No rinse ready to use cleaner and disinfectant with Neutrafresh technology. Material For professional use only. AISE-P301 - General purpose cleaner. Manual process AISE-P302 - General purpose cleaner. Spray and wipe manual process AISE-P305 - Sanitary cleaner. Manual process AISE-P306 - Sanitary cleaner. Spray and wipe manual process AISE-P314 - Surface disinfectant. Manual process AISE-P315 - Surface disinfectant. Spray and rinse manual process Can be used in all areas except food preparation areas Method of Use Wear appropriate personal protective equipment: chemical resistant gloves (EN 374) and JR&Co uniform. For extended periods, where there is an increased risk of splashing, safety goggles (EN166) should also be worn Spray onto cloth and wipe. No rinse required Quantity Used Pre-diluted. Use as required H319 – Causes serious eye irritation. H412 – Harmful to aquatic life with long lasting effects. Can a Safer No safer alternatives available that are regulatory approved Alternative Be Used Operator Persons Low risk of splashing into the eyes, mitigated by the use of eye PPE Exposed, for prolonged use, users trained in safe handling and in correct Method of application. User is trained to spray product directly onto cloth so Exposure and risk of contact is low Risk Level Indirectly Low risk to third party as product is only to be handled by authorised users only and it is stored in locked cupboard when not in use. Risk reduced further as product is applied directly to cloth and is immediately safe to touch so suitable for use in public environments where control measures maintained For normal application the following should be worn: PPE Used Hand protection: Protective gloves EN 374. Skin protection: Protective clothing. For extended cleaning with higher risk of splashing, the user should also wear safety goggles (EN166) Control Product is to be handled by trained users only and stored safely when not in use Measures Used Avoid direct contact and/or splashes where possible. Product to applied direct to cloth only (no misting) and protective gloves EN374should always be worn in application Ventilate areas where possible Inhalation: Get medical attention or advice if you feel unwell. First Aid Arrangements Skin contact: Wash skin with plenty of lukewarm, gently flowing water. If skin irritation occurs: Get medical advice or attention. Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation occurs and persists, get medical attention. Ingestion: Immediately drink 1 glass of water. Never give anything by mouth to an unconscious person. Get medical attention or advice if you feel unwell. Self-protection of first aider: Consider personal protective equipment as indicated in subsection PPE Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use Emergency water spray to cool containers. Water spray. Dry chemical powder. Alcohol resistant foam. Arrangements Carbon dioxide. Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Name Of Rebecca Elliott Assessor: Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: Shield Cleaner Disinfectant Trigger H319 – Causes serious eye irritation. H412 – Harmful to aquatic life with long lasting effects. 3. INFORMATION ON INGREDIENTS Ingredient(s) EC number CAS REACH number Range Ethanol 64-17-5 0.1 -1 Oxalic acid 6153-56-6 1-5 Isopropanol 67-63-0 1-5 Limestone 1317-65-3 1-5 Pumice 1332-09-8 3-7 Ammonium hydroxide 215-647-6 001336-21-6 1-5% C, N R34, R50 4. FIRST AID MEASURES Eyes : Rinse thoroughly with copious amounts of water, If in any doubt, obtain medical attention. Skin: Wash affected areas thoroughly with water, using soap Inhalation : Move victim to fresh air and keep in rest. If in doubt, obtain medical attention. Ingestion : Do not induce vomiting. Seek medical attention. Keep away from sources of ignition. No smoking. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Avoid contact with eyes and skin. Keep out of reach of children. 5. FIRE FIGHTING MEASURES Extinguishing Media: Use dry chemical, alcohol resistant foam, water spray. DO NOT USE WATER JET. Protective Equipment for Fire Fighting: No Special requirements. 6. ACCIDENTAL RELEASE MEASURES Toxic to aquatic organisms, may cause long term effects in the environment No risk phase required R10 Flammable R34 Causes burns R50 Very toxic to aquatic organisms R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking R67 Vapour may cause drowsiness and dizziness R51/51 Toxic to aquatic organisms, may cause long-term effects in the aquatic environment. COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: CA 013 Substance: MSDS DATE 13/07/2020 SELDEN SELFREEZ CHEW GUM REMOVER Colourless. Physical Form Use of the Material Chewing gum and sticky substance remover for easy removal from carpets and floors. Method of Use JR&CO users must wear PPE as stipulated in COSHH assessment: Safety glasses EN166 and chemical resistant gloves EN374 Spray the aerosol onto the offending sticky substance. Scrape off with a knife or scraper when the white frost hardens it. If substance softens before removed completely, repeat the above directions. Quantity Used Generally small depending upon the size of the amount of gum. R12 0 Extremely flammable R12 0 Extremely flammable R12 – Extremely flammable

Precautionary statements

S2, S3/9/49 NB The regulatory information given above only indicates the principle regulations specifically applicable to the product described in this material safety data sheet. The users attention is drawn to the possible existence of additional provisions. Refer to all applicable national, international and local regulations or provisions. P280 - Wear eye or face protection. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTRE, doctor or physician. 3. INFORMATION ON INGREDIENTS Ingredient(s) EC number CAS REACH number Remove all sources of ignition and, if possible, ventilate the area Environmental Precautions: Try to prevent the material from entering drains or water courses. Spillages: Small spillages – up to 1L, may be cleaned up with a mop or absorbent cloth. Medium spillages – up to 5L may be absorbed into sand, earth or other inert material and transferred to a suitable container for subsequent disposal. Large spillages – contain with sand, earth or other inert material. Do not pump or release to drain. Do not contaminate watercourses or group. If necessary pump to a safe place. Consult your local Water Authority, Environmental Protection Agency, local council or an expert for advice on disposal. 7. HANDLING AND STORAGE Handling Precautions: Wear suitable gloves if long or repeated exposure to the product is anticipated. A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after use. A2 Do not spray on a naked flame or any incandescent material. S23 Do not breathe vapour/spray S51 Use only in well-ventilated areas S2 Keep out of the reach of children PRESSURISED CONTAINER: Increase in temperature to greater than 50C will cause internal pressure to rise potentially causing bursting/explosion. Can a Safer No practical commercial alternatives exist and physical methods cannot be used. Alternative Be Used Operator Persons Exposed, Low risk of skin or eye contact by dispensing the aerosol directly Method of Exposure onto the gum deposit. and Risk Level Accidental hand contact with the material is unlikely and will be minimised by the use of gloves. Inhalation of the vapour during is restricted by the relatively short periods for which the spray is used. The workplaces are large, and well ventilated. The risk is low. Flammability risk is minimised by keeping the workplace free from sources of ignition (e.g. no smoking). Indirectly Areas where the material is used are cordoned off or work is carried out with the building empty. Product to be stored in secure container and kept in secure flammable liquids/ COSHH storage cabinet Control Measures Used Minimum quantities used consistent with effective performance. Product to be used in short bursts only. Contact time kept to a minimum Product us applied directly to affected areas Mandatory use of chemical resistant gloves EN374 and safety goggles PPE Used Engineering Measures: Provide adequate general and local exhaust ventilation. Hand Protection: Use protective gloves. Eye Protection: Wear approved safety goggles EN166. Other Protection: General workwear only. Hygiene Measures: DO NOT SMOKE IN WORK AREA First Aid INHALATION: Move the exposed person to fresh air at once. Keep the Arrangements affected person warm and at rest. Get prompt medical attention. For breathing difficulties oxygen may be necessary. INGESTION: Rinse mouth thoroughly. Provide rest, warmth and fresh air. SKIN CONTACT: Rinse with water. Get medical attention if any discomfort continues. EYE CONTACT: Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15minutes. Get medical attention if any discomfort continues. Emergency Extinguishing Media: Use powder, dry chemicals, sand, dolomite etc. water spray, fog, or Arrangements mist. Special Fire Fighting Procedures: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Containers close to fire should be removed or cooled with water. User water to keep fire exposed containers cool and disperse vapours. Name Of Assessor: Rebecca Elliott Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: SELDEN SELFREEZ CHEW GUM REMOVER A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after use. A2 Do not spray on a naked flame or any incandescent material. S23 Do not breathe vapour/spray S51 Use only in well-ventilated areas S2 Keep out of the reach of children PRESSURISED CONTAINER: Increase in temperature to greater than 50C will cause internal pressure to rise potentially causing bursting/explosion. 3. INFORMATION ON INGREDIENTS Ingredient Name EC No. CAS No. % A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after use. A2 Do not spray on a naked flame or any incandescent material. S23 Do not breathe vapour/spray S51 Use only in well-ventilated areas S2 Keep out of the reach of children PRESSURISED CONTAINER: Increase in temperature to greater than 50C will cause internal pressure to rise potentially causing bursting/explosion. STATUTORY INSTRUMENTS Control of Substances Hazardous to Health, Chemicals (Hazard Information and Packaging) Regulations. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40., Introduction to Local Exhaust Ventilation HS(G)37., CHIP for everyone HSG(108).

Signal word

Danger Contains alkyl alcohol ethoxylate (C9-11 Pareth-6).

2.1 Classification of the substance or mixture

Notes Weight number percent alkyl alcohol ethoxylate Polymer* 68439-46-3 [4] Acute Tox. 4 3-10 (H302) Eye Dam. 1 (H318) tetrasodium ethylene diamine 200-573-9 64-02-8 01-2119486762-27 Acute Tox. 4 1-3 tetraacetate (H302) Acute Tox. 4 (H332) STOT RE 2 (H373) Eye Dam. 1 (H318) alkyldimethylbenzylammoniumchloride 270-325-2 68424-85-1 No data available Skin Corr. 1B 1-3 (H314) Acute Tox. 4 (H302) Acute Tox. 4 (H312) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) * Polymer. Workplace exposure limit(s), if available, are listed in subsection 8.1. [1] Exempted ionic mixture. See Regulation No known effects or symptoms in normal use Eye Contact: Causes severe Irritation. Skin Contact: May produce an allergic reaction Inhalation: No known effects or symptoms in normal use Ingestion: No known effects or symptoms in normal use PROPAN-2-OL 200-661-7 67-63-0 10-15% C;R34;Xn, R20/21/22 2-BUTOXYETHANOL 203-905-0 111-76-2 1-3% Xn;R20/21/22 Xi;R36/38 4. FIRST AID MEASURES Inhalation If spray/mist has been inhaled, proceed as follows. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Ingestion Do not induce vomiting. Give plenty of water to drink. Get medical attention if any discomfort continues. Skin contact Wash with plenty of water. Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 5. FIRE FIGHTING MEASURES Extinguishing media Extinguish with the following media: Extinguish with foam, carbon dioxide, dry powder or water fog. Special hazards arising from the substance or mixture Thermal decomposition or combustion products may include the following substances: Irritating gases or vapours. May explode when heated or when exposed to flames or sparks. Advice for firefighters Keep containers cool by spraying with water to reduce explosion risks. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with eyes Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the Environmental Agency or other appropriate regulatory body. Methods and material for containment and cleaning up Small Spillages Flush away spillage with plenty of water. Large Spillages Contain and absorb spillage with sand, earth or other non-combustible material. Collect and place in suitable waste disposal containers and seal securely 7. HANDLING AND STORAGE Precautions for safe handling Eliminate all sources of ignition Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame 8. PERSONAL PROTECTION/EXPOSURE CONTROLS Engineering measures - This product must not be handled in a confined space without adequate ventilation. Respiratory protection not required. No specific hand protection noted, but protection for the skin is advisable to prevent removal of natural oils from skin. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Liquid COLOUR Clear Blue ODOUR Faint Alcoholic. SOLUBILITY Soluble in water 10. STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product. Chemical stability No particular stability concerns. Conditions to avoid Avoid heat, flames and other sources of ignition. Incompatible materials Materials To Avoid. No specific material or group of materials is likely to react with the product to produce a hazardous situation Hazardous decomposition products No known hazardous decomposition products. packaging & labelling of dangerous substances & GHS/CLP- Associated Eye Irrit. 2 (H319) Aquatic Chronic 3 (H412) with the Material Eye Irrit. 2 (H319) Aquatic Chronic 3 (H412) Notes Weight number (1999/45/EC) percent propan-2-ol 200-661-7 67-63-0 01-2119457558- Flam. Liq. 2 (H225) F;R11 1-3 25 STOT SE 3 (H336) Xi;R36 Eye Irrit. 2 (H319) R67 tetrapotassium pyrophosphate 230-785-7 7320-34-5 01-2119489369- Eye Irrit. 2 (H319) Xi;R36 1-3 18 alkyl alcohol ethoxylate Polymer* 68439-46-3 [4] Acute Tox. 4 Xn;R22 1-3 (H302) Eye Dam. Xi;R41 1 (H318) alkyldimethylbenzylammoniumc 270-325-2 68424-85-1 No data available Skin Corr. 1B Xn;R21/22 0.1-1 hloride (H314) Acute Tox. 4 C;R34 N;R50 (H302) Acute Tox. 4 (H312) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) * Polymer. Workplace exposure limit(s), if available, are listed in subsection 8.1. [1] Exempted ionic mixture. See Regulation Following European dangerous preparations directive (1999/45/EC) this preparation is classified as dangerous Flammable Eye Contact: None. Skin Contact: None. Inhalation: None. Ingestion: None. Range BUTANE 203-448-7 106-97-8 30-60% F;R12 4. FIRST AID MEASURES INHALATION: Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. For breathing difficulties oxygen may be necessary. INGESTION: Rinse mouth thoroughly. Provide rest, warmth and fresh air. SKIN CONTACT: Rinse with water. Get medical attention if any discomfort continues. EYE CONTACT: Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15minutes. Get medical attention if any discomfort continues. 5. FIRE FIGHTING MEASURES Extinguishing Media: Use powder, dry chemicals, sand, dolomite etc. water spray, fog or mist. Special Fire Fighting Procedures: Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. Unusual Fire & Explosion Hazards: Aerosol cans may explode in a fire. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate, if leakage cannot be stopped and evacuate area. Environmental Precautions: Any spillages needs to be contained and not allowed to enter water courses. 7. HANDLING AND STORAGE Usage Precaution: Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Usage Description: Aerosol cans must not be exposed to direct sunlight or temperatures above 50®C. 8. PERSONAL PROTECTION/EXPOSURE CONTROLS Name Std TWA – 8hrs STEL – 15min Notes BUTANE WEL 600 ppm1450 mg/m3 750 ppm1810 mg/m3 WEL = Workplace Exposure Limits Provide adequate general and local exhaust ventilation. Protective equipment needed: protective gloves EN374and approved safety googles. Hygiene measures DO NOT SMOKE IN WORK AREA! 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Aerosol. COLOUR Colourless. ODOUR Almost Odourless. SOLUBILITY 100% Product Name: SELDEN SELFREEZ CHEW GUM RMVR 10. STABILITY AND REACTIVITY Stability: Stable under normal temperature conditions, avoid shocks and physical damage. Conditions to avoid: Avoid heat, flames and other sources of ignition. Hazardous Decomposition Products: Fire creates vapours/gases/fumes of Carbon Monoxide (CO), Carbon Dioxide (CO2).

UN Number

Non-dangerous goods 15. REGULATORY INFORMATION: EU regulations: Non-dangerous goods 14.2 UN proper shipping name: Non-dangerous goods 14.3 Transport hazard class(es): Non-dangerous goods Class: - 14.4 Packing group: Non-dangerous goods

PBT Substances

Persistent, Bioaccumulative and Toxic • PNEC - Predicted No Effect Concentration • REACH number - REACH registration number, without supplier specific part - Persistent, Bioaccumulative and Toxic • PNEC - Predicted No Effect Concentration • REACH number - REACH registration number, without supplier specific part

vPvB Substances

very Persistent and very Bioaccumulative • ATE - Acute Toxicity Estimate COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: Substance: CA 009 SPRINT HARD SURFACE CLEANER MSDS DATE 13/07/2020 Physical Form Clear Green Liquid Use of the For cleaning unpolished floors and all other hard surfaces. Material Method of Use Do not carry out any cleaning activity without prior washing hands and selecting the appropriate PPE stipulated in this assessment. Although no formal PPE requirement as per COSHH, JR&Co policy stipulate that gloves and suitable clothing to protect skin contact must be worn for all cleaning tasks. JR&Co also requires operatives to wear glasses when diluting product By mop and bucket or trigger spray. The liquid is pumped into the spray or bucket via a pelican pump at a dose rate specified in the standard procedure. Add 4 pumps into 5 litres of water – half a small mop bucket/small bucket. Quantity Used Add 8 pumps into 10 litres of water - half a Kentucky mop/flat mop bucket. Add 2 pumps into Trigger bottle ¾ filled with water -750 ml of diluted material. Associated with the Material No other hazards known The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No - very Persistent and very Bioaccumulative • ATE - Acute Toxicity Estimate COSHH & ENVIRONMENT ASSESSMENT FORM Assessment: CA 012 Substance: Brasso Metal Polish MSDS DATE 13/07/2020 Viscous liquid Physical Form Use of the Material Designed to remove tarnish from brass, copper, chrome and stainless steel. Method of Use Apply with the soft cloth. Polish off with a dry soft cloth before polish has completely dried. Use a small amount and apply onto a dry cloth. Quantity Used Associated The main hazard associated with Brasso Liquid is the flammability of the with the Material product. The flash point is 35.5 deg C. Eyes –may cause eye irritation. Avoid eye contact. Skin – may cause skin irritation. Not expected to be a skin sensitizer. Avoid skin contact. Inhalation –None expected during normal conditions of use. Ingestion –Health injuries are not known or expected under normal use. Chronic effects –the finished product is not expected to have chronic health effects. Signs & symptoms –may include redness, oedema, drying, defatting, and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea, and vomiting. Components of this product have been identified as having potential environmental concerns. Can a Safer No practical commercial alternatives exist and physical methods cannot be Alternative Be Used used. Operator Persons Exposed, Low risk, low amount used, squirted downward and used Method of Exposure with damp cloth and gloves. and Risk Level Indirectly Used in specific areas. Areas thoroughly cleaned. Control Measures Minimum quantities used consistent with effective performance. Training in Used correct use, handling and storage PPE Used Operators use as resistant gloves EN 166 and uniform. Masks and Safety glasses are not considered necessary for the risks involved First Aid SKIN CONTACT Arrangements Consult a physician if necessary. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. EYE CONTACT Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Seek immediate medical attention/advice. INHALATION Move to fresh air. Consult a physician. If breathing is irregular 9or stopped. Administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. INGESTION Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do not induce vomiting. Emergency In unlikely event that a concentrated from spilled, immediately dilute with Arrangements fresh water and mop. Dispose of in foul water drain. As pelican pumps are used there is reduced risk of spillage. Diluted spillages mop up and contain the spillage with cloths if necessary. Was out all clothes and dry. Clean all buckets and mops afterwards. If necessary absorb with sand type product and dispose of safely as commercial waste Name of Assessor: Rebecca Elliott Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: Brasso

Environmental hazards

None No other hazards known The product does not meet the criteria for PBT or vPvB in accordance with Regulation Non-dangerous goods 14.6 Special precautions for user: Non-dangerous goods 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers. 15. REGULATORY INFORMATION: 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations: Toxic to Aquatic organisms, may cause long term effect in the aquatic environment 3. INFORMATION ON INGREDIENTS % Ingredient Name EINECS No. CAS No.

Contains

PROPAN-2-OL and 2-BUTOXYETHANOL, The ingredients are present in with the Material non-hazardous concentrations. This product does not contain any PBT or vPvB substances. Can a Safer No practical commercial alternative exists and physical methods cannot be Alternative Be Used used. Operator Persons Exposed, Low risk, small amount used, squirted downward and Method of Exposure sprayed onto cloth. and Risk Level Protection for the skin is advisable to prevent removal of natural oils from skin. Prolonged or excessively repeated skin contact could lead to removal of natural oils from skin. Inhalation unlikely. Prolonged eye contact may lead to the product affecting the natural lubrication provided by the mucous membranes. Indirectly Used in specific areas. Areas thoroughly cleaned. Control Measures Minimum quantities used consistent with effective performance. Used PPE Used Chemical resistant rubber gloves EN 374 and suitable clothing to protect skin contact First Aid INHALATION If spray/mist has been inhaled, proceed as follows. Move Arrangements affected person to fresh air and keep warm and at rest in a position comfortable for breathing. INGESTION Do not induce vomiting. Give plenty of water to drink. Get medical attention if any discomfort continues SKIN CONTACT Wash with plenty of water. EYE CONTACT Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least Emergency Store at moderate temperatures in dry, well-ventilated area. Keep in original Arrangements container. Store away from: Oxidising material. Discharge used solutions to drain. Small amounts (less than 5 Litres) of unwanted product may be flushed with water to sewer. Larger volumes must be sent for disposal by approved waste contractor. Consign empty container to normal waste. Notes A096 EV Issue 6, revision date 03/09/2014 JR&Co COSHH last review: 13/07/2020 Name Of Assessor: Rebecca Elliott Approved By: Virginia Schuldt 1. IDENTIFICATION OF PRODUCT Product Name: Cleanline Glass and Stainless Steel Cleaner

2.2 Label elements

packaging of substances & mixtures Chemical Safety Assessment No chemical safety assessment has been carried out as not applicable as this product is a mixture. ! !

Remarks

route (mg/kg time organs affected bw/d) propan-2-ol No data available tetrapotassium No data pyrophosphate available alkyl alcohol ethoxylate No data available alkyldimethylbenzylam No data moniumchloride available Ingredient(s) Affected organ(s) propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available Ingredient(s) Affected organ(s) propan-2-ol No data available tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available alkyldimethylbenzylammoniumchloride No data available propan-2-ol 0.05 OECD 107 No bioaccumulation expected tetrapotassium pyrophosphate -2 Method not given No bioaccumulation expected alkyl alcohol ethoxylate 3.11 - 4.19 Method not given High potential for bioaccumulation alkyldimethylbenzylammoniumchloride 0.5 - 1.58 Method not given No bioaccumulation expected Ingredient(s) Value Species Method Evaluation propan-2-ol No data available tetrapotassium No data pyrophosphate available alkyl alcohol ethoxylate < 500 Method not High potential for given bioaccumulation alkyldimethylbenzylam 0.5 Method not No bioaccumulation expected moniumchloride given 12.4 Mobility in soil Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation coefficient type Log Koc Log Koc(des) propan-2-ol No data available Potential for mobility in soil, soluble in water tetrapotassium pyrophosphate No data available alkyl alcohol ethoxylate No data available Potential for mobility in soil, soluble in water alkyldimethylbenzylammoniumchloride No data available - RID/ADR : Proper Shipping Name Turpentine Substitute, Class 3, Subsidiary Risk N/A, Packing Group III, ADR/RID Labels 3 (if not LQ), HIN 30, CEFIC Tremcard No Limited Quantity LQ7 5L inner packaging, 30Kg gross weight / combined packaging 20Kg gross weight / Tray, Special Provisions: none ICAO/IATA : Proper Shipping Name Turpentine Substitute, Class 3, Subsidiary Risk N/A, Packing Group III, Maximum Quantity LTD QTY packaging instruction Y309 5,0L inner packaging (plastic) Max. 10L/packaging. Single packaging is not allowed PAX packaging instruction 309 10L inner packaging (plastic) max 60L/packaging Single packaging’s and combination packaging are allowed. CAO packaging instruction 30 Combination packaging 10L inner packaging (plastic) max. 220L /packaging. Single packagings and combination packagings are allowed. 15. REGULATORY INFORMATION:

Other hazards

No other adverse effects known. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste from residues / unused products: European Waste Catalogue: The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging material is suitable for energy recovery or recycling in line with local legislation. Empty packaging Recommendation: Dispose of observing national or local regulations. Suitable cleaning agents: Water, if necessary with cleaning agent. 14. TRANSPORT INFORMATION Land transport, Sea transport (IMDG), Air transport (ICAO-TI / IATA-DGR) Negligible ecotoxicity 13. DISPOSAL CONSIDERATIONS Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION This product does not require a classification for transport. 15. REGULATORY INFORMATION: Specific regulations: Not applicable Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

67/548/EEC

F R12 Associated Extremely flammable with the Material F R12 Extremely flammable