GEON JKF100L CHOC. BROW N 5553

SECTION 2: Hazards identification

OSHA identification mixture This has not ben evaluated as a whole for health effects. Al ingredients are bound in a PVC polymer matrix and potential for hazardous exposure as shipped is minimal. PVC resin is manufactured from Vinyl Chlori de M onomer (VCM ). PVC resin manufacturers take special efforts to strip residual VCM from their resins. Residual VCM in the resin is typicaly below 8.5 ppm. However, VCM is a known carcinogen. The end -user (fabricator) should take necessary

Precautionary statements

mechanical ventilation, local exhaust, respiratory protection, etc.) to protect employes from exposure to any vapors or dusts that may be released during heating or fabrication. Se Sections 8 and 11 for special precautions.After handling, always wash han ds thoroughly with soap and water.

2.2 Label elements

None known.

2.3 Other hazards

None known. POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Page 2 of 15 Revision Date: 02/02/2015 Print Date 02/21/2015 Section 3. Com position/inform ation on ingredients Substance/m ixture : M ixture Chem ical nam e : M ixture eans Other m of identification VC10001817 CAS num ber/other identifiers Ingredient nam e % CAS num ber Quartz 0.1 - 1 14808 -60 -7 concentration Any shown as a range is to protect confidentiality or is due to batch variation. There are no aditional ingredients present which, within the curent knowledge of the supplier and in the concentrations aplicable, are classified as hazardous to health or the environm ent and hence require reporting in this section. Ocupational exposure lim its, if available, are listed in Section 4. First aid m easures Description of necessary first aid easures m Eye contact Immediately flush eyes with plenty of water, ocasionaly lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical atention. Inhalation Remove victim to fresh air and kep a t rest a in position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest ocurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid give to mouth -to -mou th resuscitation. Get medical atention. If unconscious, place in recovery position and get medical atention immediately. M aintain an open airway. Loosen tight clothing such as a colar, tie, belt or waistband. Skin contact Flush contaminated skin w ith of plenty water. Remove contaminated clothing and shoes. W ash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical atention. W ash clothing before reuse. Clean shoes thor oughly before reuse. Ingestion : W ash out mouth with water. Remove dentures if any. Remove victim POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Page 3 of 15 Revision Date: 02/02/2015 Print Date 02/21/2015 to fresh air and kep at rest in a position comfortable for breathing. If material has ben swalowed and the exposed person conscious, is give smal quan tities of water to drink. the Stop if exposed person fels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting ocurs, the head should be kept low so that vomit does not enter the lungs. Get medical atention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical atention immediately. M aintain an open airway. Loosen tight clothing such as a colar, tie, belt or waistband. M ost im portant sym ptom s/effects, acute and delayed

Potential Acute Health Effects

Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Over -exposure signs/sym ptom s Eye contact No specific data. Inhalation No specific data. Skin contact No specific data. Ingestion No specific data. Indication of im ediate m edical attention and special treatm ent neded, if necessary Notes to physician Treat symptomaticaly. Contact poison treatment specialist immediately if large quantities have ben ingested or inhaled. Specific treatm ents No specific treatment. Protection of first -aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self -contained breathing apparatus. It may be dangerous to the person providi ng aid give to mouth -to -mouth resuscitation. W ash contaminated clothing thoroughly with water before removing it, or wear gloves. Se

TOXICOLOGICAL INFORMATION

Section 11) Section 5. Fire -fighting m easures POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Page 4 of 15 Revision Date: 02/02/2015 Print Date 02/21/2015 Extinguishing m edia Suitable extinguishing m edia In case of fire, use water spray (fog), foam, dry chemical or CO . Unsuitable extinguishing m edia None known. Specific arising from the No specific fire or explosion hazard. chem ical Hazardous therm al : M ay emit Hydrogen Chloride (HCl). decom position products Decomposition products may include the folowing materials: carbon dioxide carbon monoxide halogenated compounds Special protective actions for fire - Promptly isolate the scene by removing all persons from the vicinity fighters of the incident if there is a fire. No action shal be taken involving any personal risk or without suitable training. Special protective equipm ent for Fire -fighters shou ld wear appropriate protective equipment and self - fire -fighters contained breathing apparatus (SCBA) with a full face -piece operated in positive presure mode. Acidental release m easures Personal precautions, protective equipm ent and em ergency procedures For non -em ergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Kep unnecessary and unprotected personnel from entering. Do not touch or walk through spiled material. Provid e adequate ventilation. W ear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. ergency For em responders If specialised clothing is required to with the spilage, deal take note of any information in Section 8 on suitable and unsuitable materials. Se also the information in "For non -emergency personnel". Environm ental precautions Avoid dispersal of spiled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental polution (sewers, waterways, soil or air). M ethods and m aterials for containm ent and cleaning up al Sm spill : M ove containers from spil ar ea. Avoid dust generation. Do not dry swep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Page 5 of 15 Revision Date 02/02/2015 Print Date 02/21/2015 Large spill : M ove containers from spil area. Approac h release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not swep. dry Vacuum dust with equipment fited with a HEPA filter and place in a closed, labeled waste container. Dispose of via a lic ensed waste disposal contractor. Note: se Section 1 for emergency contact information and for waste disposal. Handling and storage Precautions for safe handling Protective m easures Put on appropriate personal protective equipment (se Section 8). Avoid exposure - obtain special instructions before use. Do not handle until al safety precautions have ben read and understood. Do not get in eyes or on skin or clothing. Do not ingest. I f during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Kep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in us e. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general ocupational Eating, drinking and smoking should be prohibited in areas where this hygiene material is handled, stored and processed. W orkers shou ld wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Se also Section 8 for additional information on hygiene measures. Conditions for safe storage, Store in accordance with local regulations. Store in original container including any incom patibilities protected from direct sunlight in a dry, cool and wel -ventilated area, away from incompatible materials (se Section 10) and food and drink. Store in a wel -ventil ated place. Kep container tightly closed and sealed until ready for use. Containers that have ben opened must be carefuly resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmen tal contamination. Exposure controls/personal protection Control param eters Ocupational exposure lim its Ingredient nam e Exposure lim its POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Page 6 of 15 Revision Date 02/02/2015 Print Date 02/21/2015 Quartz OSHA PEL 1989 (1989 -03 -01) Calculated as Quartz PEL: Permissible Exposure Level 0.1 mg/m3 Form: Respirable dust OSHA - PEL Z3 (1997 -09 -03) Time W eighted Average (TW A) Form: Respirable Tim e W eighted Average (TW A) 10 mg/m3 Form: Respirable Tim e W eighted Average (TW A) 30 mg/m3 Form: Total dust NIOSH REL (1994 -06 -01) Time W eighted Average (TW A) 0.05 mg/m3 Form: Respirable dust ACGIH TLV (2005 -12 -09) TLV -TW A: Threshold Limit Value - Time weighted average PEL: Permissible Exposure Level 0.025 mg/m3 Form: Respirable fraction Apropriate enginering controls If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other enginering controls to kep worker exposure to airborne contaminants below any recommended or statutory limits. Environm ental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or enginering modifications to the process equip ment wil be necessary to reduce emissions to acceptable levels. Individual protection m Hygiene m easures W ash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentialy contaminated clothing. W contaminated ash clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necesary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the folowing protection should be worn, unless the as sessment indicates a higher degre of protection: safety glasses with side -shields. Skin protection Hand protection Chemical -resistant, impervious gloves complying with an approved standard should be worn at al times when handling chemical product s if a risk asessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are stil retaining their protective properties. It should be noted that the time to breakthrough for any g love material may be POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Revision Date 02/02/2015 Page 7 of 15 Print Date 02/21/2015 different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection Personal protective equipment for the body s hould be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected b ased on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved sta ndard if a risk asesment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chem ical properties Apearance Physical state solid [Pelets.] Color BROW N Odor Not available. Odor threshold Not available. pH Not available. M elting point Not available. Boiling point Not available. Auto -ignition tem perature Not available. Decom position tem perature Not available. SADT Not available. Viscosity Dynam ic: Not available. POLYONE CORPORATION SAFETY DATA SHET JKF10L CHOC. BROW N 53 GEON Version Num ber 1 .6 Revision Date 02/02/2015 Page 8 of 15 Print Date 02/21/2015 Kinem atic: Not available. Section 10. Stability and reactivity