FILLER CARTRIDGE

Hazard statements (CLP)

H302, H373

Code

Statements

H302

Harmful if swallowed

2.1 Classification of the substance or mixture

Not classified as dangerous according to the criteria of

2.2 Label elements

Not classified as dangerous according to the criteria of

Additional information

EUH208

Contains

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3 1). May produce an allergic reaction.

2.3 Other hazards

No other hazards known 3.1. Substances Not applicable 3.2, Mixtures Name CAS No gi aeed . REACH Registration No EC No Conc. (C)

EU Classification

CLP |Note

Remarks

lethanediol 107-21-1 c<2.5% lAcute Tox. 4; H302 f1)(2)(6}(10) Constituent (01-2119456816-28 203-473-3 ISTOT RE 2; H373 Created by: Brandweerinformatiecentrum voor gevaarlijke staffen vzw (BIG) Publication date 2011-07-13 § Technische Schoolstraat 43 A, B-2440 Geel Date of revision 2020-03-16 g http://www. big.be BIG vzw 2 & Reason for revision: 15 % {1} For H-statements in full: see heading 16 {2} Substance with a Community workplace exposure limit {6} Enumerated in Annex VI DNEL Long-term local effects inhalation 35 mg/m? Long-term systemic effects dermal 106 mg/kg bw/day DNEL/DMEL - General population ethanediol Effect level (DNEL/DMEL) Type [Value DNEL Long-term local effects inhalation 7 mg/m? Long-term systemic effects dermal 53 mg/kg bw/day PNEC ethanediol Compartments Value Fresh water 10 mg/l Marine water 1 mg/l lAqua (intermittent releases) 10 mg/l Fresh water sediment 37 mg/kg sediment dw Marine water sediment 3.7 mg/kg sediment dw ISTP 199.5 mg/l Sail 1.53 mg/kg soil dw 8.1.5 Control banding If applicable and available it will be listed below. 8.2, Exposure controls The information in this section is a general description If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure scenarios that correspond to your identified use. 8.2.1 Appropriate engineering controls Keep away from naked flames/heat. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. 8.2.2 Individual protection measures, such as personal protective equipment Observe strict hygiene. Do not eat, drink or smoke during work. a) Respiratory protection: Respiratory protection not required in normal conditions. b) Hand protection: Protective gloves against chemicals (EN 374). Materials Measured Thickness Protection index breakthrough time nitrile rubber c) Eye protection: Eye protection not required in normal conditions. d)} Skin protection: Reason for revision: 15 Publication date 2011-07-13 Date of revision 2020-03-16 Protective clothing (EN 14605 or EN 13034). 8.2.3 Environmental exposure controls: See headings 6.2, 6.3 and 13 ECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical form Paste Viscosity Thixotropic Odour Characteristic odour Odour threshold INo data available in the literature Colour White Particle size INot applicable (liquid) Explosion limits INo data available in the literature Flammability Not classified as flammable Log Kow Not applicable (mixture) Dynamic viscosity INo data available in the literature Kinematic viscosity INo data available in the literature Melting point INo data available in the literature Boiling point 100 °C Evaporation rate INo data available in the literature Relative vapour density INo data available in the literature Vapour pressure INo data available in the literature Solubility Water; miscible Relative density 0.51 Decomposition temperature INo data available in the literature Auto-ignition temperature INo data available in the literature Flash point 200 °C Explosive properties INo chemical group associated with explosive properties Oxidising properties INo chemical group associated with oxidising properties pH 7; 20°C

Further information

Absolute density [505 kg/m? ] SECTION 10: Stability and reactivity 10.1. Reactivity Heating increases the fire hazard. Neutral reaction. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid

Precautionary statements

Keep away from naked flames/heat. 10.5. Incompatible materials No data available. 10.6. Hazardous decomposition products Upon combustion: CO and CO2 are formed. SECTION 11: Toxicological information 11.1. Information on toxicological effects 11.1.1 Test results Acute toxicity FILLER CARTRIDGE No (test})data on the mixture available Judgement is based on the relevant ingredients Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 ethanediol Route of exposure [Parameter |Method Value Exposure time Species Value Remark determination Oral category 4 Annex VI Oral LDsO BASF-internal 7712 mg/kg bw Rat (male / Experimental value standards female) Dermal LDSO Developmental > 3500 mg/kg bw Mouse {male / Experimental value toxicity study female) Inhalation {mist) LC50 Teratogenicity study | > 2.5 mg/l air 6h Rat (male / Experimental value female) In the light of practical experience, the classification for this substance is more stringent than the one based on test results of the used test organisms Conclusion Not classified for acute toxicity Corrosion/irritation FILLER CARTRIDGE No (test)data on the mixture available Judgement is based on the relevant ingredients ethanediol Route of exposure /Result Method Exposure time Time point Species Value Remark determination Eye Not irritating BASF-internal 1; 24 hours Rabbit Experimental standards value Skin Not irritating BASF-internal 8 days Rabbit Experimental standards value Conclusion Not classified as irritating to the skin Not classified as irritating to the eyes Not classified as irritating to the respiratory system Respiratory or skin sensitisation FILLER CARTRIDGE No (test})data on the mixture available Judgement is based on the relevant ingredients ethanediol Route of exposure |Result Method Exposure time Observation time |Species Value determination |Remark point Skin Not sensitizing Guinea pig Experimental value maximisation test (female} Conclusion Not classified as sensitizing fer inhalation Not classified as sensitizing fer skin Specific target organ to: FILLER CARTRIDGE No (test}data on the mixture available Judgement is based on the relevant ingredients ethanediol Route of exposure {Parameter |Method Value Organ Effect Exposure time Species Value determination Oral (diet) NOEL Equivalentto |150 mg/kg Kidney No effect 16 weeks {daily} Rat (male} Experimental OECD 408 bw/day value Oral (diet) Dose level |Equivalentto [500 mg/kg Kidney Histopatholog [16 weeks {daily} Rat (male} Experimental OECD 408 bw/day ical changes value Dermal NOAEL OECD 410 > 2200 mg/kg No effect 4 weeks (daily, 5 days | Dog (male) Experimental bw |/ week) value Conclusion Not classified for subchronic toxicity Mutagenicity (in vitro) FILLER CARTRIDGE No (test)data on the mixture available Judgement is based on the relevant ingredients ethanediol Result Method Test substrate Effect Value determination [Remark Negative OECD 471 Bacteria (S.typhimurium) No effect Experimental value Mutagenicity (in vivo) FILLER CARTRIDGE Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 No (test)data on the mixture available Judgement is based on the relevant ingredients ethanediol Result Method Exposure time Test substrate Organ Value determination Negative Chromosome Rat {male / female) Experimental value aberration assay Conclusion Not classified for mutagenic or genotoxic toxicity Carcinogenicity FILLER CARTRIDGE No (test)data on the mixture available Judgement is based on the relevant ingredients ethanediol Route of Parameter Method Value Exposure time Species Effect Organ \Value lexposure determination Oral NOAEL Carcinogenic 1000 mg/kg 24 month(s) Rat (male / Experimental toxicity study bw/day female) value Conclusion Not classified for carcinogenicity Reproductive toxicity FILLER CARTRIDGE No (test)data on the mixture available Judgement is based on the relevant ingredients ethanediol Parameter Method Value Exposure time Species Effect Organ \Value determination Developmental toxicity | NOAEC Developmenta |150 mg/m? | 6 days (gestation, Rat No effect Experimental I toxicity study Jair daily) - 15 days value (gestation, daily) Effects on fertility NOAEL 3generation |> 1000 Rat(male/ |No effect Experimental study mg/kg female) value bw/day Conclusion Not classified for reprotoxic or developmental toxicity Toxicity other effects FILLER CARTRIDGE No (test)data on the mixture available Chronic effects from short and long-term exposure FILLER CARTRIDGE Skin rash/inflammation. ECTION 12: Ecological informati 12.1. Toxicity FILLER CARTRIDGE No (test}data on the mixture available Judgement of the mixture is based on the relevant ingredients Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 ethanediol Parameter Method Value Duration Species Test design |Fresh/salt Value determination water Acute toxicity fishes LCsO EPA 600/4- 172860 me/l |96h Pimephales Static Fresh water Experimental value 90/027 promelas system Acute toxicity crustacea EC50 OECD 202 |>100mg/l [48h Daphnia magna_ | Static Fresh water | Experimental value system Toxicity algae and other EC5O EPA 600/9- |6500meg/l- |96h Pseudekirchneri Experimental value; aquatic plants 78-018 13000 mg/l ella subcapitata Grewth rate Long-term toxicity fish NOEC EPA 600/4- |15380me/l_ |7 day(s) Pimephales Experimental value 90/027 promelas Long-term toxicity aquatic NOEC EPA 600/4- |8590 mg/l 7 day(s) Ceriodaphnia sp. Fresh water Experimental value crustacea 90/027 Toxicity aquatic micro- £C20 ISO 8192 > 1995 mg/| [30 minutes | Activated sludge | Static Fresh water | Read-across organisms system ECS DIN 38412-8 |> 10000 meg/||16h Pseudomonas Experimental value putida Conclusion Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008 12.2. Persistence and degradability ethanediol Biodegradation water Method Value Duration Value determination OECD 301A 90% - 100 % 10 day{s) Experimental value Phototransformation air {DT50 air) Method Value Conc. OH-radicals Value determination SRC AOP v1.92 46.3 day(s) 500000 /cm? Calculated value Conclusion Water Contains readily biodegradable componentis) 12.3. Bioaccumulative potential FILLER CARTRIDGE Log Kow Method Remark Value Temperature Value determination Not applicable {mixture} ethanediol Log Kow Method Remark Value Temperature Value determination 71.36 Calculated Conclusion Does not contain bioaccumulative component(s) 12.4. Mobility in soil ethanediol (log) Koc Parameter Method Value \Value determination log Koc SRC PCKOCWIN v1.66 (e] Calculated value Volatility (Henry's Law constant H} Value Method [Temperature Remark Value determination 10.1327 Pa.m?/mol ISRC HENRYWIN v3.10 25°C Calculated value Percent distribution Method Fraction air Fraction biota Fraction Fraction soil Fraction water [Value determination sediment Other 0.03 % jo % 0% 100 % Calculated value Conclusion Contains component(s} with potential for mobility in the soil 12.5. Results of PBT and vPvB assessment Does not contain component(s) that meet{s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006. 12.6. Other adverse effects FILLER CARTRIDGE Greenhouse gases None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014) Ozone-depleting potential {ODP) Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 Not classified as dangerous for the ozone layer (Regulation {EC} No 1005/2009) Groundwater Groundwater pollutant ethanediol Groundwater Groundwater pollutant SECTION 13: Disposal considerations The information in this section is a general description If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure scenarios that correspond to your identified use. 13.1. Waste treatment methods 13.1.1 Provisions relating to waste European Union Can be considered as non hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997. Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC). 08 04 10 (wastes from MFSU of adhesives and sealants (including waterproofing products): waste adhesives and sealants other than those mentioned in 08 04 09). Depending on branch of industry and production process, also other waste codes may be applicable. 13.1.2 Disposal methods Remove waste in accordance with local and/or national regulations. Dispose of the small quantities as household waste. Do not discharge into drains or the environment. Dispose of at authorized waste collection point. 13.1.3 Packaging/Container No data available SECTION 14: Transport information Road (ADR), Rail (RID), Inland waterways (ADN), Sea (IMDG/IMSBC), Air (ICAO-TI/IATA-DGR) 14.1. UN number [Transport [Not subject ] 14.2. UN preper shipping name 14.3. Transport hazard class{es) Hazard identification number Class Classification code 14.4. Packing group Packing group Labels 14.5. Environmental hazards [Environmentally hazardous substance mark Ino 1 5 .6. Special precautions for user Special provisions Limited quantities 14.7. Transport in bulk according to Annex || of Marpol and the IBC Code [annex ILof MARPOL 73/78 [Not applicable, based on available data ] SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture European legislation: VOC content Directive 2010/75/EU VOC content Remark 2.24% 11.3 g/l Indicative occupational exposure limit values (Directive 98/24/EC, 2000/39/EC and 2009/161/EU) ethanediol Product name Skin resorption Ethylene glycol Skin REACH Annex XVII- Restriction Contains component(s) subject to restrictions of Annex XVII of Regulation {EC} No 1907/2006: restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles. Designation of the substance, of the group of | Conditions of restriction substances or of the mixture ethane diol Liquid substances or mixtures fulfilling the 1. Shall not be used in criteria for any of the following hazard classes | — ornamental articles intended to produce light or colour effects by means of different or categories set out in AnnexI to Regulation | phases, for example in ornamental lamps and ashtrays, (EC) No 1272/2008: — tricks and jokes, Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 (a) hazard classes 2.1 to 2.4, 2.6 and 2.7,2.8 | — games for one or more participants, or any article intended to be used as such, even with types A and B, 2.9, 2.10, 2.12, 2.13 categories _| ornamental aspects, Land 2, 2.14 categories 1 and 2, 2.15 types A] 2. Articles not complying with paragraph 1 shall not be placed on the market. to; 3. Shall not be placed on the market if they contain a colouring agent, unless required for (b) hazard classes 3.1 to 3.6, 3.7 adverse fiscal reasons, or perfume, or both, if they: effects on sexual function and fertility or on | — can be used as fuel in decorative oil lamps for supply to the general public, and, development, 3.8 effects other than narcotic | — present an aspiration hazard and are labelled with H304, effects, 3.9 and 3.10; 4, Decorative oil lamps for supply to the general public shall not be placed on the market (c) hazard class 4.1; unless they conform to the European Standard on Decorative oil lamps (EN 14059} adopted (d) hazard class 5.1. by the European Committee for Standardisation (CEN). 5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following requirements are met: a} lamp oils, labelled with H304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: Keep lamps filled with this liquid out of the reach of children”; and, by 1 December 2010, “Just a sip of lamp oil — or even sucking the wick of lamps — may lead to life- threatening lung damage”; b) grill lighter fluids, labelled with H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: “Just a sip of grill lighter may lead to life threatening lung damage”; ¢) lamp oils and grill lighters, labelled with H304, intended for supply to the general public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010. 6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel for decorative lamps, labelled H304, intended for supply to the general public. 7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled H304 to the competent authority in the Member State concerned. Member States shall make those data available to the Commission." National legislation Belgium FILLER CARTRIDGE No data available ethanediol Réserption peau Ethyléneglycol (en aérosol}; D; La mention “D” signifie que la résorption de l’agent, via la peau, les muqueuses ou les yeux, constitue une partie importante de l’exposition totale. Cette résorption peut se faire tant par contact direct que par présence de |’agent dans lair. National legislation The Netherlands FILLER CARTRIDGE |Waterbezwaarlijkheid IB (5); Algemene Beoordelingsmethociek (ABM) ethanediol [Huidopname (wettelijk) [Ethaan-1,2-diol (damp); H National legislation France FILLER CARTRIDGE No data available ethanediol Risque de pénétration Ethyléneglycol (vapeur); PP lpercutanée National legislation Germany FILLER CARTRIDGE WGK 1; Classification water polluting according to external literature source ethanediol [TA-Luft 5.2.5 JTRGSSOO - Risiko der Ethandiol; Y; Risiko der Fruchtschadigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des biclogischen Fruchtschadigung Grenzwertes nicht beflirchtet zu werden Hautresorptive Stoffe Ethandiol; H; Hautresorptiv National legislation United Kingdom FILLER CARTRIDGE No data available ethanediol Skin absorption Ethane-1,2-diol particulate; Sk Ethane-1,2-diol vapour; Sk Other relevant data FILLER CARTRIDGE No data available ethanediol [riv ~ Carcinogen Ethylene glycol; A4 15.2. Chemical safety assessment No chemical safety assessment has been conducted for the mixture. Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16 Full text of any H-statements referred to under heading 3: H302 Harmful if swallowed. H373 May cause damage to organs (kidneys) through prolonged or repeated exposure if swallowed. {*) INTERNAL CLASSIFICATION BY BIG ADI Acceptable daily intake AOEL Acceptable operator exposure level CLP (EU-GHS} Classification, labelling and packaging (Globally Harmonised System in Europe} DMEL Derived Minimal Effect Level DNEL Derived No Effect Level ECSO Effect Concentration 50 % ErC50 EC50 in terms of reduction of growth rate LCso Lethal Concentration 50 % LDSO Lethal Dose 50 % NOAEL No Observed Adverse Effect Level NOEC No Observed Effect Concentration OECD Organisation for Economic Co-operation and Development PBT. Persistent, Bioaccumulative & Taxic PNEC Predicted No Effect Concentration STP Sludge Treatment Process vPVB very Persistent & very Bioaccumulative The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions may be used. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to take all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances. BIG does not guarantee the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third parties. This safety data sheet is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is failing the general conditions of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction are limited. Consult the mentioned agreement/conditions for details. Reason for revision: 15 Publication date: 2011-07-13 Date of revision: 2020-03-16