Chemical name/Classification

Hazard statements (CLP)

H225, H304, H312, H315, H317, H318, H319, H335, H336, H351, H360D, H361d, H362, H373, H400, H410

Code

Statements

H225

Highly Flammable liquid and vapour

Hazard pictograms

PPE PPE PPE PPE

2.2 Label elements

CEN Standard CEN Standard CEN Standard CEN Standard

Remarks

Replace when there is a taste or smell of the Filter mask for gases and contaminant inside the face mask. If the EN 405 2001+A1 2009 vapours contaminant comes with warnings it is Mandatory recommended to use isolation equipment. respiratory tract protection C.- Specific protection for the hands The Breakthrough Time indicated by the EN 374-1:2003 manufacturer must exceed the period during which NON-disposable chemical EN 374-3 2003/AC 2006 the product is being used. Do not use protective protective gloves EN 420 2003+A1 2009 creams after the product has come into contact Mandatory hand with skin. protection D.- Ocular and facial protection SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue) EN 166:2001 EN 167:2001 Clean daily and disinfect periodically according to EN 168:2001 Face mask the manufacturer´s instructions. Use if there is a EN 172 1994/A1 2000 risk of splashing. Mandatory face EN 172 1994/A2 2001 protection EN ISO 4007:2012 EN 1149-1,2,3 EN 13034 2005+A1 2009 Disposable clothing for EN ISO 13982- protection against chemical 1 2004/A1 2010 For professional use only. Clean periodically Mandatory complete risks, with antistatic and EN ISO 6529:2001 according to the manufacturer´s instructions. body protection fireproof properties EN ISO 6530:2005 EN ISO 13688:2013 EN 464:1994 Safety footwear for EN 13287:2008 protection against chemical EN ISO 20345:2011 Replace boots at any sign of deterioration. risk, with antistatic and heat EN 13832-1:2006 Mandatory foot resistant properties EN ISO 20344:2011 protection Emergency measure Standards Emergency measure Standards ANSI Z358-1 DIN 12 899 ISO 3864-1:2002 Emergency shower Eyewash stations 9.1 Appearance: Decomposition temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Risk of combustion Avoid direct impact Not applicable Acids Water Combustive materials Combustible materials Others Not applicable Avoid direct impact Not applicable SECTION 11: TOXICOLOGICAL INFORMATION (continue) 11.1 Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A.- Ingestion: - Acute toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea and vomiting. B- Inhalation: - Acute toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for inhalation. For more information see section 3. C- Contact with the skin and the eyes: - Contact with the skin: Produces skin inflammation. - Contact with the eyes: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for skin contact. For more information see section 3. D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous with carcinogenic effects. For more information see section 3. - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: Suspected of damaging the unborn child. E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensibilizising effects. For more information see section 3. - Cutaneous: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous with sensibilizising effects. For more information see section 3. F- Specific target organ toxicity (STOT)-time exposure: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for inhalation. For more information see section 3. G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Exposure in high concentrations can cause a breakdown in the central nervous system causing headache, dizziness, vertigo, nausea, vomiting, confusion, and in serious cases, loss of concentration. - Skin: Based on available data, the classification criteria are not met, however, it does contain substances which are classified as dangerous due to repetitive exposure. For more information see section 3. H- Aspiration hazard: The consumption of a considerable dose can cause pulmonary damage.

Further information

Non-applicable Specific toxicology information on the substances: Identification Acute toxicity Genus Toluene LD50 oral 5580 mg/kg Rat CAS: 108-88-3 LD50 dermal 12124 mg/kg Rat EC: 203-625-9 LC50 inhalation 28,1 mg/L (4 h) Rat Alkanes, C14-17, chloro LD50 oral >2000 mg/kg CAS: 85535-85-9 LD50 dermal >2000 mg/kg EC: 287-477-0 LC50 inhalation Non-applicable N-methyl-2-pyrrolidone LD50 oral 3598 mg/kg Rat CAS: 872-50-4 LD50 dermal 7000 mg/kg Rat EC: 212-828-1 LC50 inhalation Non-applicable SECTION 11: TOXICOLOGICAL INFORMATION (continue) Identification Acute toxicity Genus Butanone oxime LD50 oral 2100 mg/kg Rat CAS: 96-29-7 LD50 dermal 1100 mg/kg Rat EC: 202-496-6 LC50 inhalation Legislation related to safety data sheets: This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) Nº

ECOLOGICAL INFORMATION

The experimental information related to the eco-toxicological properties of the product itself is not available 12.1 Toxicity: Identification Acute toxicity Specie Genus Toluene LC50 13 mg/L (96 h) Carassius auratus Fish CAS: 108-88-3 EC50 11,5 mg/L (48 h) Daphnia magna Crustacean EC: 203-625-9 EC50 125 mg/L (48 h) Scenedesmus subspicatus Algae Alkanes, C14-17, chloro LC50 0,1 - 1 mg/L (96 h) Fish CAS: 85535-85-9 EC50 0,1 - 1 mg/L Crustacean EC: 287-477-0 EC50 0,1 - 1 mg/L Algae Butanone oxime LC50 843 mg/L (96 h) Pimephales promelas Fish CAS: 96-29-7 EC50 750 mg/L (48 h) Daphnia magna Crustacean EC: 202-496-6 EC50 83 mg/L (72 h) Scenedesmus subspicatus Algae N-methyl-2-pyrrolidone LC50 832 mg/L (96 h) Lepomis macrochirus Fish CAS: 872-50-4 EC50 4897 mg/L (48 h) Daphnia magna Crustacean EC: 212-828-1 EC50 500 mg/L (72 h) Scenedesmus subspicatus Algae 12.2 Persistence and degradability: Identification Degradability Biodegradability Toluene BOD5 2.5 g O2/g Concentration 100 mg/L CAS: 108-88-3 COD Non-applicable Period 14 days EC: 203-625-9 BOD5/COD Non-applicable % Biodegradable 100 % Butanone oxime BOD5 Non-applicable Concentration 100 mg/L CAS: 96-29-7 COD Non-applicable Period 28 days EC: 202-496-6 BOD5/COD Non-applicable % Biodegradable 24 % N-methyl-2-pyrrolidone BOD5 1.09 g O2/g Concentration 100 mg/L CAS: 872-50-4 COD 1.6 g O2/g Period 28 days EC: 212-828-1 BOD5/COD 0.68 % Biodegradable 73 % 12.3 Bioaccumulative potential: Identification Bioaccumulation potential Toluene BCF 13 CAS: 108-88-3 Pow Log 2,73 EC: 203-625-9 Potential Low Butanone oxime BCF 5 CAS: 96-29-7 Pow Log 0,59 EC: 202-496-6 Potential Low N-methyl-2-pyrrolidone BCF 0,23 CAS: 872-50-4 Pow Log -0,46 EC: 212-828-1 Potential Low 12.4 Mobility in soil: Identification Absorption/desorption Volatility Toluene Koc 178 Henry 6,728E+2 Pa·m³/mol CAS: 108-88-3 Conclusion Moderate Dry soil Yes EC: 203-625-9 Surface tension 27930 N/m (25 ºC) Moist soil Yes SECTION 12: ECOLOGICAL INFORMATION (continue) Identification Absorption/desorption Volatility Butanone oxime Koc 3 Henry CAS: 96-29-7 Conclusion Very High Dry soil EC: 202-496-6 Surface tension 25700 N/m (25 ºC) Moist soil EC: 212-828-1 Surface tension 40070 N/m (25 ºC) Moist soil Code Waste class (Regulation (EU) No Description 1357/2014) 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances Dangerous

UN Number

UN1263 14.2 UN proper shipping name: PAINT 14.3 Transport hazard class(es): 3 Labels: 3 14.4 Packing group: II 14.5 Dangerous for the No UN1263 14.2 UN proper shipping name: PAINT 14.3 Transport hazard class(es): 3 Labels: 3 14.4 Packing group: II 14.5 Dangerous for the No

Environmental hazards

14.6 Special precautions for user Special regulations: 163, 367, 640D, 650 Tunnel restriction code: D/E Physico-Chemical properties: see section 9 Limited quantities: 5 L 14.7 Transport in bulk according Non-applicable to Annex II of MARPOL 73/78 and the IBC Code: 14.6 Special precautions for user Special regulations: 163, 944 EmS Codes: F-E, S-E Physico-Chemical properties: see section 9 Limited quantities: 5 L 14.7 Transport in bulk according Non-applicable to Annex II of MARPOL 73/78 and the IBC Code: 14.1 UN1263 14.2 PAINT 14.3 14.4 14.5 14.6 14.7 Non-applicable