Avitex - wet wipes for disinfection

Hazard statements (CLP)

H225, H228, H319

Code

Statements

H225

Highly Flammable liquid and vapour

Product definition

Mixture This product is classified and labeled in accordance with

Hazard statements

H228 Flammable solid

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. 2.3 Other threats Other hazards not reflected in the classification: None known. Substance does not meet the PBT or vPvB criteria in accordance with Annex XIII. 3.2 Mixtures The chemical name of the No WE

2.1 Classification of the substance or mixture

ingredient No CAS Regulation (EC) Concentration / No.

Storage

Keep container tightly closed in a dry, well-ventilated place. Store in appropriately labelled containers Keep away from sources of ignition, heat and direct sunlight. 7.3 Specific end use (s) No data available. 8.1 Control parameters Occupational exposure limits National limit values ETHANOL - NDS:1900 mg/ m³ NDSCh Recommended monitoring procedures Procedures for monitoring the concentrations of hazardous components in the air and procedures for controlling air cleanliness in the workplace should be used - if they are available and justified at the workplace - in accordance with the relevant national or European Standards, taking into account the conditions prevailing at the place of exposure and appropriate measurement methodology adapted to the conditions work. The mode, type and frequency of tests and measurements should meet the requirements of the Ministry of Health Regulation of February 2, 2011 (Journal of Laws 2011, No. 33, item 166, as amended). DNEL and PNEC values for ingredients: Ethanol DNEL value for workers under dermal long-term systemic exposure: 343 mg / kg bw / day DNEL value for workers under long-term systemic exposure by inhalation: 950 mg / m3 DNEL value for workers under exposure conditions acute systemic effects by inhalation: 1900 mg / m3 DNEL value for consumers under dermal long-term systemic exposure: 206 mg / kg bw / day. DNEL value for consumers under long-term systemic exposure by inhalation: 114 mg / m3. DNEL value for consumers under exposure conditions acute systemic effects by inhalation: 950 mg / m3 DNEL value for consumers under long-term systemic exposure by ingestion: 87 mg / kg bw / day. PNEC values: fresh water: 0,96 mg/l sea water: 0,79 mg/l fresh water sediment: 3,6 mg/kg dry mass sea water sediment: 2,9 mg/kg dry mass soil: 0,63 mg/kg dry mass sewage treatment plant: 580 mg/l periodic release: 2,75 mg/l 8.2 Exposure Control Observe the general principles of safety and hygiene. Do not eat, drink or smoke while working. Wash your hands thoroughly before breaks and after finishing work. Avoid contact with eyes. Take off contaminated clothing and wash before reuse. Ensure adequate ventilation at the workplace. If during the work processes there is a risk of employees being exposed to caustic agents or inflammation of clothing on the employee - no more than 20 m in a horizontal line from the positions where these processes are carried out, emergency showers (safety showers) for washing the whole body and separate showers for washing the eyes. Hand/Body protection: Protective gloves. Eye/Face protection: Safety glasses recommended if there is a risk of eye contamination. Respiratory protection: not required if properly ventilated. The personal protective equipment used must meet the requirements of Regulation 2016/425 / EU. The employer is obliged to provide protection measures appropriate to the activities performed and meeting all quality requirements, including their maintenance and cleaning. Environmental exposure control. Avoid release to the environment, do not discharge large quantities to the sewage system. Possible emissions from ventilation systems and process equipment should be checked to determine their compliance with the requirements of environmental law. 9.1 Information on basic physical and chemical properties Appearance Physical state: Paper wipes soaked with a disinfectant Color: by product range Odour: alcoholic pH: not marked Melting Point/freezing point: No data available Initial boiling point and boiling range: No data available Flash point: 27ºC Evaporation Rate: No data available Flamability (solid, gas): no data available Burning time: no data available Combustion speed: No data available Flamability limits or: no data available Explosiveness: Upper/lower Vapour pressure: no data available Vapour density: no data available Relative density: no data available Auto-ignition temperature: 425ºC (ethanol) Solvent content: <60% Explosive properties: Not applicable Oxidation properties: not classified as oxidising. 9.2 Other Information No additional information available. 10.1 Reactivity: Reactive product. Does not undergo hazardous polymerization. Product vapors may form explosive mixtures with air. See also section 10.3 -10.5. 10.2 Chemical stability: The product is stable under normal conditions. 10.3 Possibility of hazardous reactions: The product may react with light metals and give off hydrogen. 10.4 Conditions to avoid: Avoid direct sunlight, sources of ignition and heat. 10.5 Incompatible materials: Strong oxidizers, acids, light metals. 10.6 Hazardous decomposition products : Not known. 11.1 Information on toxicological effects Toxicity of components: Ethanol Acute toxicity LC50 (inhalation , rat) 20000 pp m/10h LC50 (inhalation , mouse) 39 mg/ m3/ 4h LD50 (oral, rat) 7060 mg/kg, LD50 (oral, mouse) 3450 mg/kg LD50 (oral, rabbit) 6300 mg/kg Mixture toxicity. Acute toxicity Based on available data, the classification criteria are not met. Irritant/corrosive effect: Based on available data, the classification criteria are not met. Serious eye damage / eye irritation: Causes serious eye irritation. Respiratory or skin sensitization: Based on available data, the classification criteria are not met. Mutagenicity: Based on available data, the classification criteria are not met.. Carcinogenic Properties : Based on available data, the classification criteria are not met. Harmful to reproduction: Based on available data, the classification criteria are not met. Specific target organ toxicity - single exposure: Based on available data, the classification criteria are not met. Specific target organ toxicity - repeated exposure: Based on available data, the classification criteria are not met. Threat caused by aspiration: Contact with eyes may result in irritation. May irritate mucous membranes. Inhalation of vapors in high concentrations may cause narcosis. When using the product correctly and complying with generally applicable regulations hygiene, no cases of harmful effects on health are known. 12.1 Toxicity: Toxicity of components Ethanol Toxicity to fish: LC50> 12900-15300mg/ l/96h/(Oncorhynchus mykiss) Toxicity to bacteria: EC5034900 mg/ l/5-30 min. Mixture toxicity. The product is not classified as hazardous to the environment. 12.2 Persistence and degradability: Ethyl alcohol - biodegradable 12.3 Bioaccumulative potential: Ethanol – Bioaccumulation is not expected. 12.4 Mobility in soil: no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects: The product is not classified as hazardous to the ozone layer. The possibility of other harmful effects of the individual components of the mixture on the environment (e.g. the ability to disturb endocrine economy, impact on global warming) should be considered. 13.1 Waste disposal methods Recommendations for the mixture: Waste management (recycling) has priority over waste disposal. The product may be incinerated taking into account local regulations regarding waste incineration. Waste code 070699 - product residue / unused product: - WASTES FROM ORGANIC CHEMICAL PROCESSES; waste from production, preparation, Marketing and use of fats, oils, soaps, detergents, and disinfectants cosmetics; wastes not otherwise specified. Recommendations for used packaging: recovery / recycling / liquidation of packaging waste carried out in accordance with applicable regulations. Only completely emptied packaging can be recycled. EU legal acts European Parliament and Council Directives 2008/98 / EC, as amended and 94/62 / EC as amended and 94/62 / EC as amended. National legal acts: Journal of Laws 2013, item 21 as amended.; Journal of Laws 2013, item 888 as amended. ADR, RID, ADN, IMO/IMDG, ICAO/IATA 14.1 UN Number (ONZ Number) UN 3175 14.2 Correct UN shipping name: SOLID MATERIALS, CONTAINING LIQUID MATERIALS FLAMMABLE, I. N.O. (ETHANOL) 14.3 Transport hazard Class (es): 14.4 Packing Group: II Classification code: F1 Limited quantity (LQ): 1kg / 30kg Transport categories: 2 Hazard Number: 40 Tunnel restriction code; E 14.5 Environmental Hazards: The mixture does not pose a threat to the environment according to transport regulations. 14.6 Special precautions for users: Take away ignition sources. 14.7 Transport in bulk in accordance with annex II to MARPOL 73/78 15.1 Safety, health and environmental legislation specific to the substance or mixture Polish law acts: Act of 25 February 2011 on chemical substances and their mixtures (Journal of Laws of 2011, No. 63, item 322, as amended). Regulation of the Minister of Family, Labor and Social Policy of June 12, 2018 regarding the highest allowable concentrations and intensities of factors harmful to health in the work environment (Journal of Laws 2018, item 1286, as amended). The Waste Act of December 14, 2012 (Journal of Laws 2013, item 21, as amended). Act of 13 June 2013 on the management of packaging and packaging waste (Journal of Laws 2013, item 888, as amended). Regulation of the Minister of Climate of 2 January 2020 on the waste catalog (Journal of Laws 2020, item 10). Regulation of the Minister of Health of February 2, 2011 on tests and measurements of factors harmful to health in the work environment (Journal of Laws of 2011, No. 33, item 166, as amended). UE law acts: European Agreement concerning the International Transport of Dangerous Goods by road (ADR), (OJ Z 2002) No 194, item 1629 and 2003R. No 207, item 213 and 214), Ordinance (EC) No 1907/2006 of the European Parliament and of the Council of December 18th 2006 in REACH case). Ordinance of the European Parliament and Council Regulation (EC) No 1272/2008 of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45 / EC and amending Reg (EC) No 1907/2006 (Official Journal of the European Union L335 / first dated. 31.12. 2008) 2015/830 / EU Commission Regulation of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the registration, evaluation, authorization and restriction of chemicals (REACH). 2008/98 / EC Directive of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain directives together with amendmens. 94/62 / EC Directive of the European Parliament and of the Council of December 20, 1994 on packaging and packaging waste, as amended. 2016/425 / EU Regulation of the European Parliament and of the Council of 9 March 2016 on personal protective equipment and repealing Council Directive 89/686 / EEC. Act of 9 October 2015 on biocidal products (Journal of Laws of 2015, item 1926). 528/2012 / EC Regulation of the European Parliament and of the Council of 22 May 2012 on the making available on the market and use of biocidal products. 15.2 Chemical Safety Assessment. Not applicable