PGP

SECTION 2: Hazards identification

29 CFR 1910.1200) Identification

Potential health effects

Potential health health effects Routes Routes of of of of exposure exposure Inhalation. Ingestion. Skin contact. Eye contact. Eyes Accidental exposure will cause a moderate but transient irritation. Skin Moderately irritating to skin with prolonged exposure. Inhalation Irritating to mucous membranes. Ingestion Irritating to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Environmental effects

Potential environmental environmental effects Considering the limited amount applied during use and the size of the container, the risk of adverse effects is considered small. 3. 3. 3. 3. Composition Composition Composition / / / / Information Information Information on on on on Ingredients Ingredients Components CAS CAS # # # # Percent 2-AMINOETHANOL 141-43-5 3-7 SODIUM HYDROXIDE 1310-73-2 1-5 4. 4. 4. 4. First First First Aid Aid Aid Measures Measures First First aid aid aid procedures procedures Eye Eye contact contact After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention if symptoms persist. Skin Skin contact contact Wash affected area with mild soap and water. Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation Move to fresh air. Rinse nose and mouth with water. Call a physician if symptoms develop or persist. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Never give liquid to an unconscious person. Get medical attention if any discomfort continues. 5. 5. 5. 5. Fire Fire Fire Fighting Fighting Fighting Measures Measures Environmental Environmental precautions Environmental effects Based on ecotoxicity and fate data for the individual ingredients in this specific formulation, and for related consumer household cleaning products formulations, this product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment at relevant environmental concentrations. This product is intended for dispersive use and should not be disposed of directly into the environment. 13.

Precautionary statements

Prevent further leakage or spillage if safe to do so. Do not contaminate water. Extinguishing media media Suitable Suitable extinguishing Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media Protection Protection of of of of firefighters firefighters Protective Protective equipment equipment equipment and and Wear full protective clothing, including helmet, self-contained positive pressure or pressure precautions for for for firefighters firefighters demand breathing apparatus, protective clothing and face mask. 6. 6. 6. 6. Accidental Accidental Accidental Release Release Release Measures Measures Personal Personal precautions Keep unnecessary personnel away. Wear suitable protective clothing. Environmental Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Clean-up Clean-up methods methods methods and and and materials materials In case of spills, beware of slippery floors and surfaces. Use a non-combustible material like and and containment containment containment measures measures vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. 7. 7. 7. 7. Handling Handling Handling and and and Storage

Storage

Handling Use personal protective equipment as required. Avoid contact with skin. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of reach of children. Store in a cool and well-ventilated place. Keep from freezing. 8. 8. 8. 8. Exposure Exposure Exposure Controls Controls Controls / / / / Personal Personal Personal Protection Protection Occupational Occupational exposure exposure exposure limits limits US. US. ACGIH ACGIH ACGIH Threshold Threshold Threshold Limit Limit Limit Values Values Components Type Value 2-AMINOETHANOL STEL 6 ppm (141-43-5) TWA 3 ppm SODIUM HYDROXIDE TWA 2 mg/m3 (1310-73-2) US. US. OSHA OSHA OSHA Table Table Table Z-1 Z-1 Z-1 Limits Limits Limits for for for Air Air Air Contaminants Contaminants Contaminants (29 (29 (29 CFR CFR CFR 1910.1000) 1910.1000) Components Type Value 2-AMINOETHANOL PEL 3 ppm (141-43-5) 6 mg/m3 SODIUM HYDROXIDE PEL 2 mg/m3 (1310-73-2) Engineering Engineering controls controls Provide adequate ventilation. Provide easy access to water supply and eye wash facilities. Personal Personal protective protective protective equipment equipment Eye Eye / / / / face face face protection protection Not normally needed. If contact is likely, safety glasses with side shields are recommended. Skin Skin protection protection Not normally needed. If prolonged or repeated contact is likely, protective gloves are recommended. Recommended gloves include rubber or neoprene. Respiratory Respiratory protection protection Not normally needed. General General hygiene hygiene Handle in accordance with good industrial hygiene and safety practice. considerations 9. 9. 9. 9. Physical Physical Physical & & & & Chemical Chemical Chemical Properties Properties Color Cloudy. Odor Scented Odor Odor threshold threshold Not available. Physical Physical state state Liquid. pH pH pH pH 13 Melting Melting point point Not available. Freezing Freezing point point Not available. Boiling Boiling point point Not available. Flash Flash point point 180 °F (82.2 °C) Evaporation Evaporation rate rate Not available. Vapor Vapor pressure pressure Not available. Specific Specific gravity gravity 1.03 - 1.06 Solubility Solubility (water) (water) Miscible Partition Partition coefficient coefficient Not available (n-octanol/water) VOC 10.02 % estimated Percent Percent volatile volatile 68.69 % estimated 10. 10. Chemical Chemical Chemical Stability Stability Stability & & & & Reactivity Reactivity Reactivity Information Information Chemical Chemical stability stability This is a stable material. Conditions Conditions to to to to avoid avoid Avoid contact with acids. Hazardous Hazardous decomposition decomposition No hazardous decomposition products are known. products Hazardous Hazardous polymerization polymerization Will not occur. 11. 11. Toxicological

TOXICOLOGICAL INFORMATION

Toxicological Information Toxicological Toxicological data data Components Test Test Results Results SODIUM HYDROXIDE (1310-73-2) Acute Other LD50 Mouse: 40 mg/kg 2-AMINOETHANOL (141-43-5) Acute Dermal LD50 Rabbit: 1025 mg/kg Acute Oral LD50 Guinea pig: 620 mg/kg Acute Oral LD50 Mouse: 700 mg/kg Acute Oral LD50 Rat: 10.2 g/kg Acute Other LD50 Mouse: 50 mg/kg Acute Other LD50 Rat: 67 mg/kg Sensitization Not available. Acute Acute effects effects This chemical may cause skin/eye irritation. Local Local effects effects Irritating to respiratory system. Irritating to eyes and skin.

Potential chronic health

Chronic effects Hazardous by OSHA criteria. 12. 12. Ecological

ECOLOGICAL INFORMATION

Ecological Information

Disposal

Considerations Considerations Waste Waste codes codes D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel] Disposal instructions instructions This material and its container must be disposed of as hazardous waste. Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. 14. 14. Transport Transport Transport Information Information DOT Basic Basic shipping shipping shipping requirements: requirements: Proper Proper shipping shipping shipping name name Corrosive liquid, basic, inorganic, n.o.s. (2-AMINOETHANOL, SODIUM HYDROXIDE), LTD QTY [may be shipped as CONSUMER COMMODITY ORM-D through 12/31/2013]

Hazard categories

Hazard class 8 UN UN UN UN number number 3266 Packing Packing group group II Hazard class 8 UN UN UN UN number number 3266 Packing Packing group group II IATA Basic Basic shipping shipping shipping requirements: requirements: Proper Proper shipping shipping shipping name name Corrosive liquid, basic, inorganic, n.o.s., (2-AMINOETHANOL, SODIUM HYDROXIDE), LTD QTY Hazard class 8 UN UN UN UN number number 3266 Packing Packing group group II Notes DO NOT SHIP BY AIR. Does not meet packaging requirements for air shipments. 15. 15. Regulatory Regulatory Regulatory Information Information US US US US federal federal federal regulations regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US US US US EPCRA EPCRA EPCRA (SARA (SARA (SARA Title Title Title III) III) III) Section Section 313 313 - - - - Toxic Toxic Toxic Chemical: Chemical: Chemical: De De De De minimis minimis minimis concentration concentration 2-PHENOXYETHANOL (CAS 122-99-6) 1.0 % N230 US US US US EPCRA EPCRA EPCRA (SARA (SARA (SARA Title Title Title III) III) III) Section Section 313 313 - - - - Toxic Toxic Toxic Chemical: Chemical: Chemical: Listed Listed Listed substance

Additional information

Additional information: ERG ERG number number 154 IMDG Basic Basic shipping shipping shipping requirements: requirements: Proper Proper shipping shipping shipping name name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.(2-AMINOETHANOL, SODIUM HYDROXIDE), LTD QTY