Phenol synthetic, technical

Hazard statements (CLP)

H301, H311, H314, H331, H341, H373

Code

Statements

H301

Toxic if swallowed

2.1 Classification of the substance or mixture

Directive 67/548/EEC: 2.1.1 Classification according to the criteria of Regulation (EC) No 1272/2008 (CLP Regulation) (Annex VI, table 3.1): for physical-chemical properties:  Not classified. for health hazards:  Acute toxicity - oral: Acute Tox. Category 3; H301: Toxic if swallowed.  Acute toxicity - dermal: Acute Tox. Category 3; H311: Toxic in contact with skin.  Acute toxicity - inhalation: Acute Tox. Category 3; H331: Toxic if inhaled.  Skin corrosion/irritation: Skin Corr. Category 1B; H314: Causes severe skin burns and eye damage.  Germ cell mutagenicity: Muta. Category 2; H341: Suspected of causing genetic defects.  Specific target organ toxicity – repeated: STOT Rep. Exp. Category 2; H373: May cause damage to organs through prolonged or repeated exposure. for environmental hazards:  Not classified.

EU Classification

DSD/DPD criteria of Annex I of Directive 67/548/EEC and as reported in Regulation (EC) No 1272/2008 (Annex VI, table 3.2): for physical-chemical properties:  Not classified. for health hazards:  T; R23/24/25 Toxic; Toxic by inhalation, in contact with skin and if swallowed.  Xn; R48/20/21/22 Harmful; Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.  C; R34 Corrosive; Causes burns.  Muta. Cat. 3; R68 Possible risk of irreversible effects. for environmental hazards:  Not classified.

2.2 Label elements

2.2.1 Labelling according to the GHS criteria of Regulation (EC) No 1272/2008 (CLP Regulation):

Signal word

Danger

Hazard pictograms

GHS05: GHS06:skullandcrossbones GHS08: Corrosion

Hazard statements

H301: Toxic if swallowed. H311: Toxic in contact with skin. H314 Causes severe skin burns and eye damage H331 Toxic if inhaled. H341: Suspected of causing genetic defects H373: May cause damage to organs through prolonged or repeated exposure. T – toxic. C-corrosive.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash hands and open skin areas thoroughly after handling. P270: Do no eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. 

Response

P301+P330+P331 IF SWALLOWED rinse mouth. Do NOTinduce vomiting. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see information on this label). P322: Specific measures (see information on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. 

Storage

P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. 

Disposal

P501: Dispose of contents/container in accordance with local/ regional/ national/ international regulation. 2.2.2 Labelling according to the DSD/DPD criteria of Annex I of Directive 67/548/EEC and as reported in Regulation (EC) No 1272/2008 (CLP Regulation):

R-phrase(s)

R23/24/25 - toxic by inhalation, in contact with skin and if swallowed. R34 - causes burns. R48/20/21/22 - harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. R68 - possible risk of irreversible effects.

S-phrase(s)

S1/2 - keep locked up and out of reach of children. S24/25 - avoid contact with skin and eyes. S26 - in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of water. S36/37/39 - wear suitable protective clothing, gloves and eye/face protection. S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Other physicochemical hazards

Fire and Explosion Hazards:  Combustible.  When heated, vapours may form explosive mixtures with air: indoors, outdoors and sewers explosion hazard.  Containers may explode when heated.  Fire may produce irritating, corrosive and/or toxic gases.  Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Chemical Hazards:  Reacts with oxidants causing fire and explosion hazard.  Contact with metals may evolve flammable hydrogen gas.

Health hazards

Toxic. Inhalation, ingestion or skin contact with the substance may cause severe injury or death.  Effects of contact or inhalation may be delayed. Eye and Skin Contact:  Easily absorbed. Serious skin burns. Numbness. Convulsion. Collapse. Coma. Death.  Eye Contact: Pain. Redness. Permanent loss of vision. Severe deep burns.  Contact with molten substance may cause severe burns to skin and eyes. Inhalation:  Sore throat. Burning sensation. Cough. Dizziness.Headache.Nausea. Vomiting. Shortness of breath. Labouredbreathing.Unconsciousness. Symptoms may bedelayed. Ingestion:  Corrosive. Abdominal pain. Convulsions. Diarrhoea. Shock or collapse. Sore throat. Smoky, greenish-dark urine.