MasterCat 4239 R

SECTION 2: Hazards identification

OSHA Hazards i o

2.1 Classification of the substance or mixture

No classified e

Signal word

No signal word. 2

Hazard statements

No known significant effects or critical hazards. / 2

Precautionary statements

2

Prevention

Not applicable. /

Response

Not applicable. 2

Storage

Not applicable. 0

Disposal

Not applicable. 2 1 Considerations / 2 Methods The generation of waste should be avoided or minimized wherever possible. Disposal of this 0 product, solutions and any byproducts should comply with the requirements of environmental protection and waste 2 disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a 1 licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the 13-27 requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. R 14. Transport Information e v DOT Classification IMDG IATA i

2.3 Other hazards

None known P 3. r Composition and Information of Ingredients i Substance/mixture: n Mixture t There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, D are classified as hazardous to health or the environment and hence require reporting in this section. a t Occupational exposure limits, if available, are listed in Section 8. e 4. First Aid Measures 2 Description of necessary first aid measures / Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for 2 and remove any contact lenses. Get medical attention if irritation occurs. 2 Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention / if symptoms occur. . 2 Skin contact: Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. 0 Ingestion: Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable or breathing. If material has been swallowed and the exposed person is conscious, give small quantities of 2 water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention 1 if symptoms occur. 13-23 Most important symptoms/effects, acute and delayed

Potential Acute Health Effects

Eye contact: No known significant effects or critical hazards. Inhalation: No known significant effects or critical hazards. R Skin contact: No known significant effects or critical hazards. e Ingestion: No known significant effects or critical hazards. v i Over-exposure signs/symptoms s Eye contact: No known significant effects or critical hazards. i Inhalation: No known significant effects or critical hazards. o Skin contact: No known significant effects or critical hazards. n Ingestion: No known significant effects or critical hazards. D Indication of immediate medical attention and special treatment needed, if necessary a t Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities e have been ingested or inhaled. Specific treatments: No specific treatments. 2 Protection of first aiders: No action shall be taken involving any personal risk or without suitable training. / 2 See toxicological information (Section 11). 2 / 5. Fire-Fighting Measures 2 Extinguishing media 0 2 Suitable extinguishing media: Use an extinguishing agent suitable for surrounding fire. Unsuitable extinguishing media: 1 None known. P Specific hazards arising from the chemical: No specific fire or explosion hazard. r Hazardous thermal decomposition products: Decomposition products may include the following materials: i Halogenated compounds; metal oxide/oxides. n t Special protective actions for fire-fighters: No special protection is required. D Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self- a contained breathing apparatus (SCBA) with a full face-piece operated in t positive pressure mode. e 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures 2 / For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through 2 spilled material. Put on appropriate personal protective equipment. 2 For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information / in Section 8 on suitable and unsuitable materials. See also the information in “For non- 2 emergency personnel.” 0 Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 2 and sewers. Inform the relevant authorities if the product has caused environmental 1 pollution (sewers, waterways, soil or air). 13-24 Methods and materials for containment and cleaning up Spill: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container R for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. e Note: see Section 1 for emergency contact information and Section 13 for waste disposal. v i 7. Handling and Storage s i Precautions for safe handling o Protective measures: Put on appropriate personal protective equipment (see Section 8). n Advice on general D Eating, drinking and smoking should be prohibited in areas where this material is handled, stored a occupational hygiene: and processed. Workers should wash hands and face before eating, drinking and smoking. See t also Section 8 for additional information on hygiene measures. e Conditions for safe Store in accordance with local regulations. Store in original container protected from direct storage, including sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 2 any incompatibilities: 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers / that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store 2 in unlabeled containers. Use appropriate containment to avoid environmental contamination. 2 / 8. Exposure Controls / Personal Protection 2 0 Control parameters 2 Occupational exposure limits: None 1 Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne P contaminants. r Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. i n Individual protection measures t Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, D smoking and using the lavatory and at the end of the working period. Appropriate techniques a should be used to remove potentially contaminated clothing. Wash contaminated clothing t before reusing. Ensure that eyewash stations and safety showers are close to the workstation e location. Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases, or dusts. If contact 2 is possible, the following protection should be worn, unless the assessment indicates a higher / degree of protection: safety glasses with side-shields. Skin protection: 2 Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn 2 at all times when handling chemical products if a risk assessment indicates this is necessary. / Body protection: Personal protective equipment for the body should be selected based on the task being 2 performed and the risks involved and should be approved by a specialist before handling this 0 product. 2 Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on 1 the task being performed and the risks involved and should be approved by a specialist before handling this product. 13-25 Respiratory protection: Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. 9. Physical and Chemical Properties R e Physical state: Liquid Lower and upper explosive Not available v (flammable) limits: i Color: Colorless to light yellow Vapor Pressure: Not available Odor: s None Vapor Density: Odor threshold: 1 [Air=1] Not available Relative Density: 1.33 to 1.35 i pH: 4 - 5 Solubility: Easily soluble in the following materials: o cold water and hot water n Melting Point: -7° C (19.4° F) Solubility in Water: Not available Boiling Point: 110° C (230° F) D Partition coefficient: Not available n-octanol/water a Flash Point: Not applicable Auto-ignition temperature: Not available t Burning time: Not applicable Decomposition temperature: Not available Burning rate: e Not applicable SADT: Evaporation Rate: Not available Viscosity: Not available Flammability Not available 2 (solid,gas): / 2 10. Stability and Reactivity / Reactivity: 2 No specific test data related to reactivity available for this product or its ingredients. 0 Chemical stability: The product is stable. Possibility of hazardous reactions: 2 Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid: No specific data. 1 Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials and metals. P Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should r not be produced. i n 11. Eye contact: No known significant effects or critical hazards. Inhalation: No known significant effects or critical hazards. R Skin contact: No known significant effects or critical hazards. e Ingestion: No known significant effects or critical hazards. v i Symptoms related to the physical, chemical and toxicological characteristics: s Eye contact: No known significant effects or critical hazards. i Inhalation: No known significant effects or critical hazards. o Skin contact: No known significant effects or critical hazards. n Ingestion: No known significant effects or critical hazards. D Delayed and immediate effects and also chronic effects from short and long term exposure: a Short term exposure: t Potential immediate effects: No known significant effects or critical hazards. e Potential delayed effects: No known significant effects or critical hazards. Long term exposure: 2 Potential immediate effects: No known significant effects or critical hazards. / Potential delayed effects: No known significant effects or critical hazards. 2 Potential chronic health effects: 2 General: No known significant effects or critical hazards. / Carcinogenicity: No known significant effects or critical hazards. 2 Mutagenicity: No known significant effects or critical hazards.

TOXICOLOGICAL INFORMATION

t D Information on toxicological effects a t Acute toxicity: There is no data available. e Irritation/Corrosion: Skin: There is no data available. Eyes: There is no data available. 2 Respiratory: There is no data available. Sensitization: / Skin: There is no data available. 2 Respiratory: There is no data available. 2 Mutagenicity: There is no data available. / Carcinogenicity: There is no data available. 2 Reproductive toxicity: There is no data available. 0

Teratogenic Effects

There is no data available. 2 Specific target organ toxicity (single exposure): There is no data available. 1 Specific target organ toxicity (repeated exposure): There is no data available. No known significant effects or critical hazards. 0 Developmental effects: No known significant effects or critical hazards. 2 Fertility effects: No known significant effects or critical hazards. 1 P Numerical measures of toxicity r Acute toxicity estimates: There is no data available. i n 12.

Aspiration hazard

There is no data available. 13-26 Information on the likely routes of exposure: Routes of entry anticipated: Oral, Dermal, Inhalation.

ECOLOGICAL INFORMATION

t D Toxicity a Product/ingredient name Result Species Exposure t Product Chronic EC 6999 mg/L Daphnia – Daphnia magna - e Chronic LC50 3623 mg/L Fish – Fathead minnow - Persistence and degradability: There is no data available. 2 Bioaccumulation potential: There is no data available. / Mobility in soil: Soil/water partition coefficient (Koc): -2.49

Other hazards

No known significant effects or critical hazards. 2 13.

UN Number

Not regulated s UN proper - shipping name i Transport hazard class(es) - o Packing Group - n

Environmental hazards

No. Yes. No.

Additional information

D - a Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright t and secure. Ensure that persons transporting the product know what to do in the event of e an accident or spillage. 2 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available. / 2 15. Regulatory Information 2 / US Federal regulations: 2 TSCA 8(a) CDR Exempt/Partial exemption: Not determined. 0 United States Inventory (TSCA 8b): All components are listed or exempted. 2 Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs): Not listed 1 Clean Air Act Section 602 Class I Substances: Not listed P Clean Air Act Section 602 Class II Substances: Not listed r DEA List I Chemicals (Precursor Chemicals): Not listed DEA List II Chemicals (Essential Chemicals): Not listed i n SARA 302/304 t