1 Glass Cleaner

Hazard statements (CLP)

H227, H302, H315, H319, H333, H336

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

GHS CLASSIFICATIONS Health Eye Irritation, Category 2A Acute Toxicity (Oral), Category 4 Skin Irritation, Category 2 Physical Combustible Liquid, Category 4

2.2 Label elements

Exclamation mark

Hazard statements

H319: Causes serious eye irritation. H315: Causes skin irritation. H302: Harmful if swallowed. H333: May be harmful if inhaled. H336: May cause drowsiness or dizziness. H227: Combustible liquid.

Prevention

P280: Wear protective gloves/protective clothing/eye protection/face protection. P261: Avoid breathing fume, gas, mist, vapors, or spray. P273: Avoid release to the environment. P102: Keep out of reach of children. P264: Wash hands thoroughly after handling. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Response

P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P310: Immediately call a POISON CENTER or doctor/physician. 5 P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P330: Rinse mouth. P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower] P332+P313 If skin irritation occurs Get medical advice/attention P362: Take off contaminated clothing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P370+P378 In case of fire Use dry chemical, foam or water mist to extinguish

Storage

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents/container according to all local, state and Federal regulations. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Blue liquid IMMEDIATE CONCERNS: Eye & Skin irritant

Potential health effects

EYES: Irritating, and may injure eye tissue if not removed promptly. SKIN: Contact may cause moderate to severe irritation. SKIN ABSORPTION: Harmful if absorbed through skin. INGESTION: Harmful if swallowed. INHALATION: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches) REPRODUCTIVE TOXICITY

Teratogenic Effects

No listed substance CARCINOGENICITY: Not Established MUTAGENICITY: No listed substance

Principle Routes of Exposure

Eye, skin, ingestion, Inhalation TARGET ORGAN STATEMENT: Blood, kidney, liver, Central nervous system CANCER STATEMENT: None WARNING CAUTION LABELS: Irritant

Physical hazards

Combustible material

2.1 Classification of the substance or mixture

Health: Eye Irritation, Category 2A Acute Toxicity (Oral), Category 4 Skin Irritation, Category 2 Physical: Combustible Liquid, Category 4 GHS LABEL Exclamation mark SIGNAL WORD: WARNING HAZARD STATEMENTS H319: Causes serious eye irritation. H315: Causes skin irritation. H302: Harmful if swallowed. H333: May be harmful if inhaled. H336: May cause drowsiness or dizziness. H227: Combustible liquid. PRECAUTIONARY STATEMENT(S) Prevention: P280: Wear protective gloves/protective clothing/eye protection/face protection. P261: Avoid breathing fume, gas, mist, vapors, or spray. P273: Avoid release to the environment. P102: Keep out of reach of children. P264: Wash hands thoroughly after handling. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Response: P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310: Immediately call a POISON CENTER or doctor/physician. 5 P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P330: Rinse mouth. P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P332+P313: If skin irritation occurs: Get medical advice/attention. P362: Take off contaminated clothing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P370+P378: In case of fire: Use dry chemical, foam or water mist to extinguish. Storage: P403+P233: Store in a well-ventilated place. Keep container tightly closed. Disposal: P501: Dispose of contents/container according to all local, state and Federal regulations. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Blue liquid IMMEDIATE CONCERNS: Eye & Skin irritant POTENTIAL HEALTH EFFECTS EYES: Irritating, and may injure eye tissue if not removed promptly. SKIN: Contact may cause moderate to severe irritation. SKIN ABSORPTION: Harmful if absorbed through skin. INGESTION: Harmful if swallowed. INHALATION: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches) REPRODUCTIVE TOXICITY TERATOGENIC EFFECTS: No listed substance CARCINOGENICITY: Not Established MUTAGENICITY: No listed substance ROUTES OF ENTRY: Eye, skin, ingestion, Inhalation. TARGET ORGAN STATEMENT: Blood, kidney, liver, Central nervous system CANCER STATEMENT: None WARNING CAUTION LABELS: Irritant PHYSICAL HAZARDS: Combustible material. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% CAS Ethylene glycol butyl ether 45 - 50 111-76-2 Sodium Lauryl Sulfate 0 - 5 151-21-3 Sodium Xylene Sulfonate 0 - 5 1300-72-7 Dye < 0.2 N/A Water 45 - 55 7732-18-5 4. FIRST AID MEASURES EYES: Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Seek medical attention immediately. SKIN: Remove contaminated clothing. Immediately flush with water followed by washing with mild soap. Seek medical attention. INGESTION: Get immediate medical attention. Do not induce vomiting unless instructed to do so by poison center or physician. INHALATION: Remove victim to fresh air and monitor. Seek medical advise if irritation persists. 6 SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Severe burning sensation, tearing, redness, swelling. SKIN: Contact causes skin irritation. INGESTION: Irritation of mouth, throat, along with stomach upset, vomiting. INHALATION: Irritation of nose, throat and lungs with coughing, sneezing, possible difficulty breathing. ACUTE TOXICITY: Severely irritating to eyes. Causes moderate to severe skin irritation. Harmful if swallowed. CHRONIC EFFECTS: Not Established NOTES TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE FIGHTING MEASURES FLAMMABLE CLASS: IIIA (140-200F) GENERAL HAZARD: Combustible Liquid EXTINGUISHING MEDIA: Use Dry chemical, carbon dioxide, or water spray when fighting fires involving this material. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide from combustion EXPLOSION HAZARDS: Fire exposed containers may burst due to increased pressure from heat. FIRE FIGHTING PROCEDURES: Use an extinguishing agent suitable for surrounding fire. FIRE FIGHTING EQUIPMENT: No special requirements. SENSITIVE TO STATIC DISCHARGE: None HAZARDOUS DECOMPOSITION PRODUCTS: Not Established 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Avoid runoff into storm sewers and ditches which lead to waterways. LARGE SPILL: Avoid walking in material. Prevent product from entering into stream, soil, storm sewer or other bodies of water. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Avoid discharges into open waterways. LAND SPILL: Avoid discharge to soil. AIR SPILL: NA = Not Applicable GENERAL PROCEDURES: Isolate spill or leak area immediately. Keep unauthorized personnel away. Do not touch or walk through spilled material. Prevent entry into waterways, sewers, or confined areas. Absorb with dry earth, sand or other non- combustible material and transfer to containers. RELEASE NOTES: Eliminate all ignition sources. Ventilate area well. SPECIAL PROTECTIVE EQUIPMENT: Eye protection, rubber gloves, rubber boots to protect feet. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Close container after use. HANDLING: Avoid contact with skin and eyes. Wash hands before eating, drinking, smoking or using toilet facilities. STORAGE: Store in closed container away from heat, spark or open flame. STORAGE TEMPERATURE: (40°F) Minimum to (110°F) Maximum STORAGE PRESSURE: Store at ambient atmospheric pressure. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 7 EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV Supplier OEL Chemical Name ppm mg/m3 ppm mg/m3 ppm mg/m3 TWA 50 240 20 97 NL Ethylene glycol butyl ether STEL NL ENGINEERING CONTROLS: Use in well ventilated area. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Chemical splash googles and full face-shield. SKIN: Rubber or other chemical resistant gloves. RESPIRATORY: A respirator is not needed under normal and intended conditions of product use. WORK HYGIENIC PRACTICES: Wash with soap and water after handling. Do not eat, drink or smoke while using product. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Solvent, characteristic ODOR THRESHOLD: Not Established COLOR: Blue pH: 11.0 to 12.0 PERCENT VOLATILE: >90 FLASH POINT AND METHOD: 67.22°C (153°F) Tag Closed Cup (TCC) FLAMMABLE LIMITS: 4.0 to 10.6 AUTOIGNITION TEMPERATURE: Not Established VAPOR PRESSURE: ~ 1.2 kPa at 25°C (77°F) VAPOR DENSITY: ~ 4 Air = 1 BOILING POINT: 212o F; 100o C FREEZING POINT: 32o F; 0o C THERMAL DECOMPOSITION: Not Available SOLUBILITY IN WATER: Complete EVAPORATION RATE: (Water =1) <1.0 DENSITY: 8.12 at 20°C (68°F) SPECIFIC GRAVITY: ~ 0.973 grams/ml. VISCOSITY: Water thin. (VOC): 48.600 % by weight 10. STABILITY AND REACTIVITY REACTIVITY: Stable HAZARDOUS POLYMERIZATION: Will not occur. STABILITY: Stable under normal storage and use conditions. CONDITIONS TO AVOID: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Under normal conditions of storage and use, hazardous decomposition products should not be produced. INCOMPATIBLE MATERIALS: Strong acids, oxidizers. 8 11. TOXICOLOGICAL INFORMATION ACUTE ORAL LD50 DERMAL LD50 INHALATION Chemical Name (rat) (rabbit) LC50 (rat) 1300 mg/kg > 2000 mg/kg Ethylene glycol butyl ether > 3.1 mg/l (rat) (rabbit) 1200 mg/kg > 2000 to 20000 > 3900 mg/m3 Sodium Lauryl Sulfate (rat) mg/kg (rabbit) (rat) EYES: Causes eye irritation. DERMAL LD50: > 2000 mg/kg guinea pig SKIN ABSORPTION: Not Established ORAL LD50: ~ 1300 mg/kg Male and Female rats. INHALATION LC50: Not Established EYE EFFECTS: Severe eye irritant. SKIN EFFECTS: Moderate skin irritant. CARCINOGENICITY NTP Chemical Name OSHA IARC Status Status Group 3 - Not classifiable as No listed Ethylene glycol butyl ether No listed to its substance carcinogenicity to Humans IARC: 3-Group 3: Not classifiable as to its carcinogenicity to humans. IRRITATION: Irritant CORROSIVITY: No data available. Contact Env. Dept. SENSITIZATION: No products were found. NEUROTOXICITY: Central nervous system effects marked by dizziness, headache, nausea, unconciousness. GENETIC EFFECTS: No known significant effects or critical hazards. REPRODUCTIVE EFFECTS: No known significant effects or critical hazards. TARGET ORGANS: May cause damage to blood, Kidney, liver with prolonged or repeated exposure to high concentrations of vapors. MUTAGENICITY: No known significant effects or critical hazards. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Not Established ECOTOXICOLOGICAL INFORMATION: Not Available