Filter-Ox

Hazard statements (CLP)

H350, H372

Code

Statements

H350

May cause cancer

SECTION 2: Hazards identification

OSHA 21. Classification of the substance or mixture GHS US classification Carcinogenicity, Category 1A May cause cancer Specific target organ toxicity — Repeated exposure, Causes damage to organs through prolonged or repeated exposure Category 1 22

2.2 Label elements

GHS US labelling

Signal word

Danger

Hazard statements

May cause cancer. Causes damage to organs through prolonged or repeated exposure. see section 16 SECTION 4: First-aid measures 41. Description of first aid measures First-aid measures general IF exposed or concerned: Get medical advice/attention First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact Wash skin with plenty of water. First-aid measures after eye contact Rinse eyes with water as a precaution First-aid measures after ingestion Call a poison center or a doctor if you feel unwell. 42. Mostimportant symptoms and effects (acute and delayed) No additional information available 43. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 51. Suitable (and unsuitable) extinguishing media Stitable extinguishing media Water spray. Dry powder. Foam 52. Specific hazards arising from the chemical Hazardous decomposition products in case of Toxic fumes may be released fire 53. Special protective equipment and precautions for fire-fighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Do not handle until all safety precautions have been read and understood. Eliminate every possible source of ignition. Prevent unauthorised access. 6.1.1. For non-emergency personnel Emergency procedures Only qualified personnel equipped with suitable protective equipment may intervene. Do not breathe dustffume/gas/mist/vapours/spray. 6.1.2. For emergency responders Protective equipment Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection” 62. Environmental precautions Avoid release to the environment. Notify authorities if product enters sewers or public waters. 63. Methods and material for containment and cleaning up Methods for cleaning up Mechanically recover the product. Notify authorities if product enters sewers or public waters.

Precautionary statements

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mistivapours/spray. Wash hands, forearms and face thoroughly after handiing Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concemed: Get medical advice/attention Get medical advice/attention if you feel unwell. Store locked up. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 238

Other hazards which do not result in classification

No additional information available 24.

Ingredient(s) with unknown acute toxicity

Not applicable SECTION 3: Compo: il Substances Not applicable 32, Mixtures 04/01/2020 EN (English) Page 1 Name

Product definition

Respirable crystalline siica (CASNo) 14808-60-7 | 50— 80 Manganese dioxide (CASNo) 1313139 | 5-10 Silicic acid, sodium salt (CASNo) 1344-098 | 1-5

Further information

Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 74, Precautions for safe handling Additional hazards when processed Avoid dust formation 04/01/2020 EN (English) 217 Precautions for safe handling Ensure good ventilation of the work station. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Take all necessary technical measures to avoid or minimize the release of the product on the workplace. Limit quantities of product at the minimum necessary for handiing and limit the number of exposed workers. Provide local exhaust or general room ventilation. Wear personal protective equipment. Floors, walls and other surfaces in the hazard area must be cleaned regularly. Do not breathe dust/fume/gas/mistivapours/spray. Hygiene measures Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Aways wash hands after handling the product 72 Cor ns for safe storage, including any incompatil ities Technical measures Minimise generation of dust Storage conditions Store locked up. Store in a well-ventilated place. Keep cool. Heat and ignition sources Keep away from sources of ignition - No smoking. Storage area Protect from moisture. Protect from sunlight. Store away from heat. Special rules on packaging Store in a closed container. rols/personal protectiol Control parameters Filter-Ox No additional information available Respirable crystalline silica (14808-60-7) USA - ACGIH - Occupational Exposure Limits Local name Silica crystaline - quartz ACGIH TWA (mg/m?) 0.025 mg/m* Remark (ACGIH) (respirable dust) Regulatory reference ACGIH 2019 USA No additional information available Stability and reactivi 1041. Reacti The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 04/01/2020 EN (English) i 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 104. Conditions to avoid Avoid creating or spreading dust. Direct sunlight. Extremely high or low temperatures. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking 10.5. Incompatible materials No additional information available 106. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under fire conditions, hazardous fumes will be present LI Information on toxicological effects Acute toxicity (oral) Not classified Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified Manganese dioxide ( 1313-13-9) ATE US (oral) 500 mg/kg bodyweight ATE US (gases) 4500 ppmv/4h ATE US (vapours) 11 mglidh ATE US (dust,mist) 1.5 mg/li4h Skin corrosion/iritation Not classified Serious eye damagefiritation Not classified Respiratory or skin sensitisation Not classified Germ cell mutagenicity Not classified Carcinogenicity May cause cancer. Respirable crystalline silica ( 14808-60-7) IARC group | 1- carcinogenic to humans Reproductive toxicity Not classified STOT-single exposure Not classified STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure. Respirable crystalline silica ( 14808-60-7) STOT-repeated exposure I Causes damage to organs through prolonged or repeated exposure. Manganese dioxide ( 1313-13-9) STOT-repeated exposure [ May cause damage to organs through prolonged of repeated exposure Aspiration hazard Not classified Viscosity, kinematic No data available Ecology - general The product is not considered hamful to aquatic organisms nor to cause long-term adverse effects in the environment 122. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 04/01/2020 EN (English) 57 12.4. Mobi in soil No additional information available

2.1 Classification of the substance or mixture

GHS US classification Carcinogenicity, Category 1A May cause cancer. Specific target organ toxicity — Repeated exposure, Causes damage to organs through prolonged or repeated exposure. Category 1 22.