Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
50-100%
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10<25%
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
2,5<10%
General Information
Revision date
2017-03-30
Product name
primopoly Hardener
Emergency telephone
Giftinformationszentrum Universitätsklinikum Mainz
Icons in SDS
Company Information
company name
primotec - Joachim Mosch e.K
e-mail address of the competent person responsible for the Safety Data Sheet
primotec@primogroup.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories
Acute toxicity: Acute Tox. 4 Skin corrosion/irritation: Skin Irrit. 2 Serious eye damage/eye irritation: Eye Irrit. 2 Respiratory or skin sensitisation: Resp. Sens. 1 Respiratory or skin sensitisation: Skin Sens. 1 Carcinogenicity: Carc. 2 Specific target organ toxicity - single exposure: STOT SE 3 Specific target organ toxicity - repeated exposure: STOT RE 2
Hazard statements
Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer by inhalation. H335 May cause respiratory irritation. H373 May cause damage to organs (...) through prolonged or repeated exposure if inhaled.
2.2 Label elements
Regulation (EC) No. 1272/2008
Hazardous Ingredients
diphenylmethanediisocyante, isomeres and homolgues 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate
Signal word
Danger
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 In case of inadequate ventilation wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulation.
Special rules for supplemental label elements for certain mixtures
EUH204 Contains isocyanates. May produce an allergic reaction.
2.3 Other hazards
Sensitisation to the respiratory tract
