11. Pro 110 ULV Insecticide(PCP15330)

Hazard statements (CLP)

H227, H303, H304, H313, H315, H320, H331

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Classification Flammable Liquids – Category 4; H227 Aspiration Hazard – Category 1; H304 Acute Inhalation Toxicity – Category 3; H331 Acute Oral Toxicity – Category 5; H303 Acute Dermal Toxicity – Category 5; H313 Skin irritation – Category 2; H315 Eye irritation – Category 2B; H320

Signal word

DANGER

Hazard statements

Combustible liquid H227 May be fatal if swallowed and enters airways H304 Toxic if inhaled H331 May be harmful in contact with skin H313 Causes skin irritation H315 Causes eye irritation H320

Prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear NIOSH/MSHA approved respirator, safety goggles, chemical resistant gloves and coveralls. Avoid breathing vapours and mists. Use only outdoors or in a well-ventilated area. Wash skin and eyes thoroughly after handling. Do not eat, drink or smoke when using this product.

Response

In case of fire: Use Foam, Carbon Dioxide, Dry Chemical or Water to extinguish. IF SWALLOWED: Immediately call doctor. Do NOT induce vomiting. Give 1 to 2 glasses of water (200 to 500mL) to dilute material. Rinse mouth. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing of vomitus. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a doctor for medical advice. Restore breathing if required. IF ON SKIN: Wash skin thoroughly with soap and water. Call a doctor if you feel unwell. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists, get medical attention. Hold eyelids open during flushing. Flush eyes with running water for 20 minutes.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up. Storage temperature Min 0°C Max 50°C

Disposal

Dispose of waste product in accordance with Local, Provincial or Federal government regulations. Dispose of empty container with household garbage.

2.3 Other hazards

This product is toxic to fish and wildlife. Do Not contaminate local water supplies or environments.

2.1 Classification of the substance or mixture

Flammable Liquids – Category 4; H227 Aspiration Hazard – Category 1; H304 Acute Inhalation Toxicity – Category 3; H331 Acute Oral Toxicity – Category 5; H303 Acute Dermal Toxicity – Category 5; H313 Skin irritation – Category 2; H315 Eye irritation – Category 2B; H320 Label Elements Signal Word: DANGER Hazard Statement(s): Combustible liquid H227 May be fatal if swallowed and enters airways H304 Toxic if inhaled H331 May be harmful in contact with skin H313 Causes skin irritation H315 Causes eye irritation H320 Precautionary Statement(s): Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear NIOSH/MSHA approved respirator, safety goggles, chemical resistant gloves and coveralls. Avoid breathing vapours and mists. Use only outdoors or in a well-ventilated area. Wash skin and eyes thoroughly after handling. Do not eat, drink or smoke when using this product. Response: In case of fire: Use Foam, Carbon Dioxide, Dry Chemical or Water to extinguish. IF SWALLOWED: Immediately call doctor. Do NOT induce vomiting. Give 1 to 2 glasses of water (200 to 500mL) to dilute material. Rinse mouth. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing of vomitus. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a doctor for medical advice. Restore breathing if required. IF ON SKIN: Wash skin thoroughly with soap and water. Call a doctor if you feel unwell. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists, get medical attention. Hold eyelids open during flushing. Flush eyes with running water for 20 minutes. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Storage temperature Min: 0°C Max: 50°C Disposal: Dispose of waste product in accordance with Local, Provincial or Federal government regulations. Dispose of empty container with household garbage. Other Hazards This product is toxic to fish and wildlife. Do Not contaminate local water supplies or environments. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Concentration Common name / Synonyms Petroleum Distillates 64742-47-8 75% – 85% Petroleum Distillates 3,4-methylenedioxy-6- 51-03-6 10.0% Piperonyl Butoxide propylbenzyl n-butyl (PBO) diethyleneglycol ether Pyrethrins 8003-34-7 1.0% Pyrethrins SECTION 4. FIRST-AID MEASURES Inhalation Move victim to fresh air and restore breathing if required. Obtain Medical Advice. Skin Contact Wash skin thoroughly with soap and water. If irritation persist seek Medical Attention. Eye Contact Flush eyes with running water fro 20 minutes. Hold eyelids open during flushing. If irritation persists, seek Medical Attention. Ingestion Give 1 to 2 glasses of water (200 to 500 mL) to dilute material. Do not induce vomiting. Obtain Medial Advice. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing of vomitus. Never give anything by mouth to an unconscious person. Most Important Acute Effects of Overexposure: Symptoms and May cause temporary irritation to the eyes, nose throat and respiratory tract. Effects, Acute and Prolonged exposure to vapours can cause headache, dizziness, nausea and nervous Delayed system depression. Effects of Chronic Exposure: Prolonged exposure may cause defatting and drying of the skin, possibly progressing to dermatitis. Immediate Medical None Known Attention and Special Treatment SECTION 5. FIRE-FIGHTING MEASURES Extinguishing Media Suitable Foam, Carbon Dioxide, Dry Chemical or Water. Wear self-contained Breathing Extinguishing Media Apparatus and impervious clothing. Unsuitable None Known. Extinguishing Media Specific Hazards Container may explode under intense heat. Vapour is heavier than air, may travel Arising from the along the ground to ignition sources and then flash back. Materials to Avoid: Acidic or Product alkaline conditions may cause product to decompose. Hazardous Decomposition Products: Carbon Monoxide and Carbon Dioxide. Special Protective Fire-fighters must wear Self-contained Breathing Apparatus and impervious clothing. Equipment and Minimize the amount of water used and dike the area for runoff. Precautions for Fire- Eliminate all ignition sources. Fighters SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions,