RD Encapsulant (Part B Hardener)

Hazard statements (CLP)

H315, H317, H320, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

Contains

10% Diphenylmethane diisocyanate (MDI) in various isomeric forms - According to Regulation 2012 OSHA Hazard Communication Standard: 29 CFR Part 1910.1200

2.1 Classification of the substance or mixture

Acute Toxicity 4 (inhalation - mist) Serious eye damage / eye irritation 2B Skin corrosion / irritation 2 Skin sensitization 1B Respiratory sensitization 1 Carcinogenicity 2 Specific target organ toxicity Single exposure - 3 (irritation to respiratory system) Repeated exposure - 2 (by inhalation)

Signal word

Danger

Hazard statements

H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves, protective clothing, eye protection, face protection P271 Use only outdoors or in a well ventilated area. P260 Do not breathe dust/gas/mist/vapors. P201 Obtain special instructions before use. P261 Avoid breathing mist. P202 Do not handle until all safety precautions have been read and understood. P284 Wear respiratory protection if ventilation is inadequate. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash thoroughly with plenty of soap and water after handling.

Response

P312 Call a POISON CENTER or physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. If present and easy to remove, remove contact lenses. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+311 If exposed or concerned: Call a POISON CENTER or physician. P314 Get medical advice/attention if you feel unwell. P303+P352 IF ON SKIN or hair: Wash with plenty of soap and water. P333+P311 If skin irritation or rash occurs: Call a POISON CENTER or physician. P362+P364 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P311 If eye irritation persists: Call a POISON CENTER or physician. P403+P233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

Disposal) P501 Dispose of contents/containers to hazardous or special waste collection point.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. ANIMAL TESTS AND OTHER RESEARCH INDICATE THAT SKIN CONTACT WITH MDI MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. According to Regulation 2012 OSHA Hazard Communication Standard: 29 CFR Part 1910.1200 Emergency overview DANGER: CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. AVOID CONTACT WITH SKIN AND EYES. SKIN OR EYE CONTACT MAY CAUSE IRRITATION.