Normal value of STP microorganisms

Hazard statements (CLP)

H302, H317, H373, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

ECOLOGICAL INFORMATION

environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering None. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Normal value of STP microorganisms. 0,11 mg/kg 3,16 mg/kg Note: Upper limit is not included into the range. pH. places in which people eat. Not available.

2.1 Classification of the substance or mixture

TWA STEL: Short-term exposure limit Health - Derived no-effect level - DNEL / DMEL. The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. Melting point / freezing point. This product is dangerous for the environment and the aquatic organisms. In the long term, it may even have negative effects on aquatic Substances subject to authorisarion (Annex XIV REACH). Not available. - TWA: Time-weighted average exposure limit Initial boiling point. Effects on consumers. Not available. Effects on workers. 7.2. Conditions for safe storage, including any incompatibilities. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = environment. None. The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC (and subsequent - VOC: Volatile organic Compounds The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC (and subsequent

Principle Routes of Exposure

Acute Chronic Acute Chronic Dangerous for the Environment(N) Boiling range. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Not available. amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC Acute local Acute Chronic Acute Information not available. R52/53 Chronic localChronic SECTION 10. Stability and reactivity. The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Flash point. amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation

Hazard pictograms

Upper inflammability limit. None. mg/m3 Xi Not available. EC50 (48h) - for Crustacea. EYES: Remove contact lenses, if present Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem 2. Directive 67/548/EEC and following amendments and adjustments Skin. 119 mg/l Daphnia magna VND 0.05 VND 15 Lower explosive limit. EC50 (72h) - for Algae / Aquatic Plants. Not available. 1,95 mg/l Desmodesmus subspicatus 3.

R-phrase(s)

persists, seek medical advice Upper explosive limit. 43-52/53 SECTION 8. Exposure controls/personal protection. Substances subject to the Stockholm Convention: Not available. mg/kg/day SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash 4. Regulation (EC)

2.2 Label elements

Vapour density Not available. LC50 (96h) - for Fish. 6. Regulation (EC)

Further information

IRRITANT Information not available. Health - Derived no-effect level - DNEL / DMEL Information not available. Effects on consumers. Effects on workers 12.3. Bioaccumulative potential. SECTION 5. Firefighting measures. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Note for users: R43 MAY CAUSE SENSITISATION BY SKIN CONTACT.

Environmental hazards

systemic local systemic local 5.1. Extinguishing media. ENVIRONMENT. suitability and thoroughness of provided information according to each specific use of the product. Acute Tox. 4 systemic Acute toxicity, category 4 systemic Inhalation. VND 3,5 10.1. Reactivity. 12.4. Mobility in soil. SUITABLE EXTINGUISHING EQUIPMENT This document must not be regarded as a guarantee on any specific product property. STOT RE 2 VND 3,5 Specific target organ toxicity - repeated exposure, category 2 S24 AVOID CONTACT WITH SKIN. mg/m3 The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. There are no particular risks of reaction with other substances in normal conditions of use. Information not available. Skin Sens. 1 mg/m3 Skin sensitization, category 1 The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health S37 Skin. WEAR SUITABLE GLOVES. VND 1.25 UNSUITABLE EXTINGUISHING EQUIPMENT Aquatic Chronic 2 VND 1,25 Hazardous to the aquatic environment, chronic toxicity, category 2 and safety laws and regulations. The producer is relieved from any liability arising from improper uses. None in particular. S60 H302 THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE. Harmful if swallowed. mg/kg 10.2. Chemical stability. EPY 8.2.2 - SDS 1003

Results of PBT and vPvB assessment

Provide appointed staff with adequate training on how to use chemical products. mg/kg The product is stable in normal conditions of use and storage. H373 May cause damage to organs through prolonged or repeated exposure. 5.2. Special hazards arising from the substance or mixture. Legend:

Contains

H317 bisphenol-A-epoxy acrylate May cause an allergic skin reaction. bisphenol-A-epoxy acrylate On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. Changes to previous review: Toxic to aquatic life with long lasting effects. H411 10.3. Possibility of hazardous reactions. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following sections were modified: VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified.

Other hazards

Do not breathe combustion products. No hazardous reactions are foreseeable in normal conditions of use and storage. 01 / 02 / 03 / 08 / 09 / 11 / 16.

2.3 Other hazards

Text of risk (R) phrases mentioned in section 2-3 of the sheet: 8.2. Exposure controls. 5.3. Advice for firefighters. 10.4. Conditions to avoid. Information not available. GENERAL INFORMATION R22 HARMFUL IF SWALLOWED. None in particular. However the usual precautions used for chemical products should be respected. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is R43 MAY CAUSE SENSITISATION BY SKIN CONTACT. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. well aired through effective local aspiration. R48/22 HARMFUL: DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE IF SWALLOWED. 10.5. Incompatible materials. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC Personal protective equipment must be CE marked, showing that it complies with applicable standards. R51/53 water used for extinction and the remains of the fire according to applicable regulations. Information not available. Provide an emergency shower with face and eye wash station.