SILAN

Hazard statements (CLP)

H315, H319, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification according to GHS Irritating to eyes, inhalation and skin.

Classification according to GHS

HAZARDOUS Hazardous: H315 Irritating to skin. H319 Irritating to eyes. H335 May be irritating to inhalation

Prevention

P261 Avoid breathe smoke/gas/burning liquid P302+P352 IN CASE OF SKIN CONTACT: Wash with plenty of water with soup. P305+P351+P338 IN CASE OF EYE CONTACT: Rinse water carefully for few minutes. If applicant and possible, take out contact lenses. Continue rinsing. P321 Provide required treatment

Storage

P405 Store locked-up 3. COMPONENTS Name CAS No. WE No. Stare in labeled, well locked container, in cool, dry, well-ventilated storage area. Keep away from heat and ignition. No not store in contact with oxidation materials and with acids. 8. EXPOSURE CONTROL/INDIVIDUAL PROTECTION Use appreciate ventilation, local and general, that provide concentration in air bellow specified level (min. 10 times air exchange per hour). Recommended to place shower at working space to rinse eyes. Individual protection actions should be design and perform to avoid hazardous and other inconvenience at normal use, that protects from chemicals. Individual protection: Respiratory protection: Necessary – at major concentration Eye protection: Necessary - such as goggles Hands protection: Necessary – gloves, protect against chemicals (CE mark) Body protection: Necessary - protective clothing Protective and hygienic measures: Change contaminated clothing. Rinse hands and face after usage. Use skin protective cream. 9. PHYSICAL/CHEMICAL PROPERTIES Physical form, color: transparent liquid Boiling point: 255 0C Ignition temperature: 92 0C Solubility in water: insoluble Density: 1,045 g/ml (20 0C) 10. STABILITY AND REACTIVITY Stability: Product stable under normal conditions of use and storage. Materials and conditions that must be avoided: Avoid oxidants and acids.

R-phrase(s)

Conc. % (weight) Silane methacrylate 2530-85-0 209-785-8 Xi 36-38 100 % Full text of R-phrases and symbols can be found in the section 16. of MSDS. 4. EMERGENCY FIRST AID PROCEDURES After inhalation: Provide access to fresh air, or resuscitation, heat. After eye contact: Rinse eye with open eyelid for few minutes and consult a doctor. After skin contact: Immediately flush with water and soap and rinse well. After ingestion: Immediately contact your doctor. 5. FIRE FIGHTING MEASURES Adequate fire-fighting measures: carbon dioxide, fire-fighting foam, water. Major fire threat by stream of water or alcohol resistant foam. Fire-fighting measures, which must not be used for safety reasons: Massive stream of water. Special risks: Fire can produce: carbon oxide and carbon dioxide. Special protective equipment for fire-fighters: In case of fire, substances harmful to health can be produced. Put on protective gastight clothing and breathing apparatus complete with a full face mask. 6. UNINTENDED RELEASE INTO THE ENVIRONMENT Individual precautions: Avoid contact with eyes and skin. Provide for the exchange of air (ventilation). Proceed in accordance with the principles of safety and health at work with chemicals. Use personal protective equipment as stated in paragraph 8. Precautions concerning environment protection: In the event of a failure, do not allow discharges into the environment. Secure the product before it enters the sewers, groundwater, soil. 7. HANDLING AND STORAGE Provide efficient air circulation (ventilation). Proceed in accordance with the principles of good practice and in compliance with health and safety. While use of the device do not eat, drink or smoke, avoid contact with the liquid, inhalation, use personal protective equipment (as defined in section 8), work in well-ventilated room.

TOXICOLOGICAL INFORMATION

High toxicity: Oral: LD50 – 22600 µL/kg (rat), Skin: LD50 >20 mL/kg (rbt), Irritating to skin: mild – 500 mg/24H (rbt), Irritating to eyes: mild- 500 mg/24H (rbt), Skin contact: Irritating to skin and mucosa Eye contact: Irritant

Further information

None of the ingredients of the product is classified as carcinogenic, mutagenic or reprotoxic. 12. ECOLOGICAL INFORMATION Harmful to water class 1 (self-determination): limited harmful to water. Do not allow to access the drinking water sources, soil and water treatment as concentrated. Do not allow to access to environment without permission from authorities. 13. DISPOSAL CONSIDERATIONS Dispose of in compliance with governmental regulation or return to the producer. 14. TRANSPORT INFORMATION The product is not subject to regulations for hazardous materials. Transport by road (ADR/RID) – NA Maritime transport (IMDG) – NA Air transport (ICAO/IATA) – NA 15. REGULATION Product has to be labeled. H315 Irritating for skin. H319 Irritating for eyes. H335 May cause severe inhalation irritant. HAZARDOUS