Japan

PPG Japan Ltd.

Revision date : 2018-04-20

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GHS08 GHS06 GHS02
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

5-<7 -872

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

3-<5 -118

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

0.5-<1 -118

EC/CAS

26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

0.2-<0.5 -118

EC/CAS

2426-08-6

Name of the chemical

1-Butoxy-2,3-epoxypropan

Concentration

0.1-<0.2 -392

EC/CAS

2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

0.1-<0.2 -118

General Information

Version

8.01

Revision date

2018-04-20

Product name

Japan

1.2.1 Relevant identified uses

Industrial applications

supplier name

PPG Japan Ltd.

Emergency telephone

81-561-35-5154

Icons in SDS

GHS02 GHS06 GHS08 M004 M008 M009 M010 M011 M013 M017

Company Information

company name

PPG Japan Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H311, H315, H317, H319, H334, H336, H341, H351, H360, H370, H372, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

GHS Classification FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 GERM CELL MUTAGENICITY - Category 2 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Fertility) - Category 1A TOXIC TO REPRODUCTION (Unborn child) - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (central nervous system (CNS), respiratory system) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bones, central nervous system (CNS), kidneys, respiratory system) - Category 1 AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 3

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor. Toxic in contact with skin or if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility or the unborn child. Suspected of causing genetic defects. Suspected of causing cancer. Causes damage to organs. (central nervous system (CNS), respiratory system) May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs through prolonged or repeated exposure. (bones, central nervous system (CNS), kidneys, respiratory system) Toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Wear respiratory protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Call a POISON CENTER or physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Take off immediately all contaminated clothing and wash it before reuse. Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs Get medical attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Prolonged or repeated contact may dry skin and cause irritation.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 GERM CELL MUTAGENICITY - Category 2 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Fertility) - Category 1A TOXIC TO REPRODUCTION (Unborn child) - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (central nervous system (CNS), respiratory system) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bones, central nervous system (CNS), kidneys, respiratory system) - Category 1 AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 3

SDS Library

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Up-to-date – Your SDS get updated to latest versions.
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Employee access – Tablets, Smartphones, or link from Corporate Intranet
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Safety – One-click access to first aid information.
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Labels – Generate Secondary Container Labels with just one click.